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  • 1
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 2408-2412 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Thermal changes of implanted fluorine distributions in a SiO2 film and a (100)-oriented Si single crystal were investigated by the 19F(p, αγ) 16O reaction and secondary-ion mass spectrometry. Fluorine in the Si accumulates to a damaged region (consistent with a Monte Carlo simulation) after annealing above 700 °C for 30 min. This effect is not observed in the SiO2. Once the fluorine is trapped by the damaged region, nearly 80% of the fluorine stays in the silicon after annealing at 800 °C. In contrast, only 10% of implanted fluorine remains in the SiO2 after annealing at 800 °C. These effects are explained by assuming the difference in the natures of imperfections in these samples. Above 1000 °C, most of the fluorine diffuses out of both systems.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 2700-2711 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We report the thickness and annealing temperature dependence of the structural, morphological, compositional, and electrical properties including ferroelectric characteristics of Pb(Zr0.52Ti0.48)O3 thin films deposited by a sol-gel method. The thickness and annealing temperature of the films were in the range of 0.12–0.36 μm and 520–670 °C, respectively. The crystalline structure and growth behavior of the films have been studied by x-ray diffraction, scanning electron microscopy, and atomic force microscopy. It is demonstrated that the weak ac electric field dependence of the permittivity of the films in terms of the Rayleigh law can be explained. The coercive field obtained from a sweep up and down schedule of the capacitance-voltage curves is asymmetrical and shows different behavior according to the annealing temperature and thickness. We also show that the activation energy coefficient, γ, obtained from frequency dependent polarization-electric field hysteresis loops is related to the annealing temperature and thickness of the films. A low leakage current density (∼100 nA/cm2 at 200 kV/cm) and low annealing temperature (∼520 °C) demonstrate the potential of the deposited films for integrated ferroelectric random access memory and piezoelectric sensor applications. © 1999 American Institute of Physics.
    Materialart: Digitale Medien
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  • 3
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: A fluorinated thermal SiO2, grown after HF surface treatment without de-ionized water rinse, was estimated to contain ∼3×1013 cm−2 of fluorine by the 19F(p,αγ)16O reaction. Secondary-ion mass spectrometry data indicate that the SiF distribution is peaked at the SiO2/Si interface in the fluorinated oxide. The time-dependent change of the absolute amount of fluorine on the HF-treated silicon surface as a function of storage time in air or in vacuum was also investigated by the 19F(p,αγ)16O reaction. The initial number of fluorine atoms on the HF-treated silicon surface was estimated to be ∼1015 cm−2 before substantial desorption took place. Fluorine atoms desorb from the silicon surface much more rapidly if the sample is stored in air than in vacuum. These results were also supported by the x-ray photoelectron spectroscopy measurement.
    Materialart: Digitale Medien
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