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  • 1
    Electronic Resource
    Electronic Resource
    Polymer chain conformation in the melt during steady elongational flow as measured by SANS. Temporary network model (1990)
    s.l. : American Chemical Society
    Macromolecules 23 (1990), S. 2577-2582 
    Details
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ma00211a028
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  • 2
    Electronic Resource
    Electronic Resource
    A high potential ferrous complex and its conversion to an alkylperoxoiron(III) intermediate: A lipoxygenase model
    Amsterdam : Elsevier
    Journal of Inorganic Biochemistry 51 (1993), S. 83 
    Details
    ISSN: 0162-0134
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://linkinghub.elsevier.com/retrieve/pii/0162-0134(93)85119-S
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  • 3
    Electronic Resource
    Electronic Resource
    A Non-staggered Grid, Fractional Step Method for Time-Dependent Incompressible Navier-Stokes Equations in Curvilinear Coordinates
    Amsterdam : Elsevier
    Journal of Computational Physics 114 (1994), S. 18-33 
    Details
    ISSN: 0021-9991
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Computer Science , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1006/jcph.1994.1146
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  • 4
    Electronic Resource
    Electronic Resource
    Scaling functions for the finite-size effect in fractal aggregates (1994)
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 27 (1994), S. 782-790 
    Details
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: An exact scaling function for the finite-sized fractal aggregates sharply bounded by a sphere of radius R has been established by using the convolution square of the shape function of aggregates and the inhomogeneity function, which is introduced to take into account the presence of inhomogeneity in fractal aggregates. The scaling function for an inhomogeneous aggregate is mainly determined by the geometric shape of the aggregate but is also dependent upon the degree of inhomogeneity present in the aggregate. The differences between the scaling function reported in this paper and the commonly used ones, exp (−r/ξ) and exp [−(r/ξ)2], are discussed. The simulating calculations have shown that the use of different scaling functions will not only influence the cross-over behavior between the Guinier regime and the fractal regime, but also make the low-q scattering intensity converge to different values.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1107/S0021889894000762
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  • 5
    Electronic Resource
    Electronic Resource
    EPR properties of mixed-valent μ-oxo and μ-hydroxo dinuclear iron complexes produced by radiolytic reduction at 77 K (1999)
    Springer
    JBIC 4 (1999), S. 292-301 
    Details
    ISSN: 1432-1327
    Keywords: Key words Mixed-valent species ; Dinuclear iron ; EPR ; Radiolytic reduction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract  Radiolytic reduction at 77 K of oxo-/hydroxo-bridged dinuclear iron(III) complexes in frozen solutions forms kinetically stabilized, mixed-valent species in high yields that model the mixed-valent sites of non-heme, diiron proteins. The mixed-valent species trapped at 77 K retain ligation geometry similar to the initial diferric clusters. The shapes of the mixed-valent EPR signals depend strongly on the bridging ligands. Spectra of the Fe(II)OFe(III) species reveal an S=1/2 ground state with small g-anisotropy as characterized by the uniaxial component (g z –g av /2〈0.03) observable at temperatures as high as ∼100 K. In contrast, hydroxo-bridged mixed-valent species are characterized by large g-anisotropy (g z –g av /2〉0.03) and are observable only below 30 K. Annealing at higher temperatures causes structural relaxation and changes in the EPR characteristics. EPR spectral properties allow the oxo- and hydroxo-bridged, mixed-valent diiron centers to be distinguished from each other and can help characterize the structure of mixed-valent centers in proteins.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s007750050315
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  • 6
    Electronic Resource
    Electronic Resource
    A composite multigrid method for calculating unsteady incompressible flows in geometrically complex domains (1995)
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 20 (1995), S. 341-361 
    Details
    ISSN: 0271-2091
    Keywords: Navier-Stokes ; unsteady ; composite multigrid ; incompressible ; non-staggered grid ; semi-implicit ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A time-accurate, finite volume method for solving the three-dimensional, incompressible Navier-Stokes equations on a composite grid with arbitrary subgrid overlapping is presented. The governing equations are written in a non-orthogonal curvilinear co-ordinate system and are discretized on a non-staggered grid. A semi-implicit, fractional step method with approximate factorization is employed for time advancement. Multigrid combined with intergrid iteration is used to solve the pressure Poisson equation. Inter-grid communication is facilitated by an iterative boundary velocity scheme which ensures that the governing equations are well-posed on each subdomain. Mass conservation on each subdomain is preserved by using a mass imbalance correction scheme which is secondorder-accurate. Three test cases are used to demonstrate the method's consistency, accuracy and efficiency.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/fld.1650200502
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  • 7
    Electronic Resource
    Electronic Resource
    Dicumyl peroxide-modified cellulose/LLDPE composites (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 41 (1990), S. 2039-2048 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The present study reports results on the processing and mechanical properties of composites modified by the addition of dicumyl peroxide (DCP). The addition of minute amounts of peroxide to the cellulose/polymer system during processing has been shown to significantly improve the physical properties of composites. SEM micrographs of fracture surfaces of the peroxide modified composites reveal direct grafting of polyethylene onto cellulose fibers. The existence of a critical peroxide concentration indicates that the grafting reactions terminate when cellulose surfaces are no longer accessible. Possible mechanisms involved are discussed.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1990.070410910
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  • 8
    Electronic Resource
    Electronic Resource
    Explicit robust schemes for implementation of a class of principal value-based constitutive models: Symbolic and numeric implementation (1994)
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 37 (1994), S. 1931-1944 
    Details
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The issue of developing effective and robust schemes to implement a class of the Ogden-type hyperelastic constitutive models is addressed. To this end, special purpose functions (running under MACSYMA) are developed for the symbolic derivation, evaluation, and automatic FORTRAN code generation of explicit expressions for the corresponding stress function and material tangent stiffness tensors. These explicit forms are valid over the entire deformation range, since the singularities resulting from repeated principal-stretch values have been theorectically removed. The required computational algorithms are outlined, and the resulting FORTRAN computer code is presented.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/nme.1620371110
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  • 9
    Electronic Resource
    Electronic Resource
    Tensile stress and recoverable strain measurements on polystyrene melts. Interpretation of results in terms of rubberlike elasticity (1987)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 25 (1987), S. 295-310 
    Details
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Extensional tests at constant strain rate \documentclass{article}\pagestyle{empty}\begin{document}$ \dot \varepsilon $\end{document} have been carried out on polystyrene melts with different molecular weight distributions at various temperatures and strain rates. The true tensile stress is found to be well approximated by the sum of two contributions: (1) a neo-Hookean expression involving the recoverable strain and (2) a contribution rapidly reaching a steady-state value. Two experimental parameters can be defined: an elasticity modulus \documentclass{article}\pagestyle{empty}\begin{document}$ G(\dot \varepsilon ) $\end{document} from (1) and a viscosity \documentclass{article}\pagestyle{empty}\begin{document}$ \eta _{\rm v} (\dot \varepsilon ) $\end{document} from (2). It is further shown that time-temperature equivalence applies not only to the stress but also to the recoverable strain and to G and ηv. The dependence of G and ηv on strain rate is then discussed. For high strain rates, G is close to the linear viscoelastic plateau modulus of PS melts and decreases with decreasing strain rate. The value of ηv is found to a good approximation to be equal to three times the shear viscosity taken at a shear rate equivalent to the elongational strain rate.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1987.090250204
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