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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 19 (1986), S. 2513-2519 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 8270-8272 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Random sequential adsorption of nonoverlapping rectangles of arbitrary orientation onto a continuous plane was investigated by computer simulation. It is shown that the approach to the jamming limit of rectangles with various aspect ratios obeys the scaling law θJ−θ(τ)∼τ−1/3. Furthermore, the adsorption kinetics of rectangles approach those of line segments as the rectangle aspect ratio becomes large.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 2599-2602 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Random sequential adsorption of nonoverlapping rectangles of arbitrary orientation onto a continuous plane was investigated by computer simulation. The approach to the jamming limit was found to obey Feder's law for a wide range of rectangle aspect ratios. The coverage fraction at the jamming limit was found to depend upon the aspect ratio of the adsorbed rectangles, with a maximum in the jamming coverage occurring at aspect ratios ≈2.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 82 (1985), S. 5269-5274 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Large-scale computer simulations of cluster–cluster aggregation of particles undergoing Brownian motion have been performed to investigate the kinetic properties of the coagulation process. It is shown that the mean-field approach of the Smoluchowski equation accurately describes the kinetics if the fractal geometry of the clusters is taken into account. The kinetic rate kernels that enter into that equation are deduced explicitly from the simulations.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 3659-3661 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Precise values for the critical threshold for the three-dimensional "Swiss cheese" continuum percolation model have been calculated using extensive Monte Carlo simulations. These simulations used a growth algorithm and memory blocking scheme similar to what we used previously in three-dimensional lattice percolation. The simulations yield a value for the critical number density nc=0.652 960±0.000 005, which confirms recent work but extends the precision by two significant figures. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 98 (1994), S. 13067-13076 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 7397-7401 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The monomer–monomer surface reaction model with an adsorbate interaction term is studied. An epidemic analysis of the poisoning times (tp) for small square lattices as a function of lattice edge length L and interaction strength α at the point of equal adsorption rates yields a dynamic scaling relation which describes the crossover between log-power-law and exponential behavior in L, and is able to fit the entire dependence of tp upon α and L. The phase transition is further explored by varying adsorption rates and is found to follow second-order kinetics. A mean-field approximation is introduced as a comparison for the numerical results. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 98 (1993), S. 674-677 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The surface reaction model of Ziff, Gulari, and Barshad (ZGB) is investigated on finite systems with "hard'' oxygen boundary conditions. The rate of production of CO2 is calculated as a function of y and system size. When the rate of CO adsorption y is above the first-order transition value y2, the reactive region is found to extend into the system a distance ξ which scales as (y−y2)−0.40 when y→y2.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 23 (1980), S. 241-263 
    ISSN: 1572-9613
    Keywords: Kinetics of polymerization ; kinetics of gelation ; gelation ; polymerization ; condensation polymerization ; Flory-Stockmayer theory ; Smoluchowski's coagulation equation ; coagulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract It is shown that three basic models of the Flory-Stockmayer theory of polymerization may all be described directly by means of a kinetic rate equation of a form first discussed by Smoluchowski, and correspond to the three known classes of solutions to this equation. The kinetics of gelation are discussed from the rate equation; the nature of both the Flory and the Stockmayer gelation theories is shown, and a new model of gelation is proposed. Some new solutions to Smoluchowski's equation are given in an appendix.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 65 (1991), S. 1217-1233 
    ISSN: 1572-9613
    Keywords: Diffusion ; trapping ; random walks
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The flux of particles to a single trap is investigated for two systems: (1) particles in 3D space which jump a fixed step lengthl (the Rayleigh flight) and are adsorbed by a spherical surface, and (2) particles on a lattice, jumping to nearest neighbor sites, with a single adsorbing site. Initially, the particles are uniformly distributed outside the traps. When the jump length goes to zero, both processes go over to regular diffusion, and the first case yields the diffusive flux to a sphere as solved by Smoluchowski. For nonzero step length, the flux for large times is given by a modified form of Smoluchowski's result, with the effective radius replaced byR-cl, wherec=0.29795219 andcl is the Milne extrapolation length for this problem. For the second problem, a similar expression for the flux is found, with the effective trap radius a function of the lattice (sc, bcc, fcc) being considered.
    Type of Medium: Electronic Resource
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