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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 3142-3154 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Further insight into processing-structure-property relationships have been carried out for existing and candidate carbon-based protective overcoats used in the magnetic recording industry. Specifically, 5 nm thick amorphous diamond-like carbon (a:C) and nitrogenated diamond-like carbon (a:CNx) overcoats were deposited by low deposition rate sputtering onto a thin film disk consisting of either CoCrPt/CrV/NiP/AlMg or CoCrPt/CrV/glass. The wear durability and frictional behavior of these hard disks were ascertained using a recently developed depth sensing reciprocating nanoscratch test. It was determined that the CN0.14/CoCrPt/CrV/glass disk exhibited the most wear resistance, least amount of plastic deformation, and lowest kinetic friction coefficient after the last wear event. Core level x-ray photoelectron spectroscopy (XPS) results of sputter cleaned overcoats indicated that nitrogen up to 14 at. % incorporated into the amorphous network resulted in these improvements near the overcoat/magnetic layer interface, since there was an increase in the number of N-sp3 C bonded sites in a predominantly N-sp2 C bonded matrix. However, nonsputter cleaned overcoats exhibited a more graphitic pyridine-like (nondoping configuration) structure near the surface as evidenced by the increase in C(Double Bond)N versus C–N bonds and the valence band XPS determined appearance of the 2p-π band near the Fermi level (EF). Therefore, XPS sputter cleaning revealed a gradient in the chemical nature of the overcoats through the thickness. In addition, micro-Raman spectroscopy established that a further increase of nitrogen (≥18 at. %) weakened the overcoat structure due to the formation of terminated sites in the amorphous carbon network, since nitrogen failed to connect the sp2 domains within the network. This, in conjunction with an increase in the intensity of the 2p-π band from the valence band XPS spectra and the increase in the G-band position and ID/IG ratio from the Raman spectra, confirmed the increase in the size and number of sp2 bonds in the CN0.18 overcoat. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 81 (2002), S. 1020-1022 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report a composite material consisting of precipitated micron-scale Ta-rich solid solution particles distributed in a bulk metallic glass matrix. The reinforcing ductile particles are precipitated during melting of the master alloy of glass-forming (Zr70Ni10Cu20)82Ta8Al10, by using previously prepared metastable Zr–Ta solid solution binary ingots. Upon cooling from the melt, the matrix undergoes a glass transition to produce an amorphous phase while the particles of precipitated Ta solid solution are distributed in the glass matrix. The resulting material not only shows high strength (∼2.1 GPa), but also has dramatically enhanced plastic strain to failure in uniaxial compression relative to single-phase bulk metallic glasses. The composite also displays limited tensile ductility. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    Journal of Mathematical Physics 26 (1985), S. 854-860 
    ISSN: 1089-7658
    Source: AIP Digital Archive
    Topics: Mathematics , Physics
    Notes: A uniform asymptotic expansion in the variable, determining the location of the observer for the fields scattered by a perfectly conducting parabolic cylinder, is derived. This expansion can be applied to scattering by arbitrary smooth convex surfaces of variable curvature. The accuracy of numerical results is examined.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    Journal of oral rehabilitation 29 (2002), S. 0 
    ISSN: 1365-2842
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: In complete denture wearers the maximum bite force (MBF) is known to be considerably lower than in dentate people. Low MBF might therefore be an indication of poor denture fit but there is limited evidence on this. Therefore, the aim of the present study was to investigate whether MBF can be improved by the replacement of complete dentures for elderly people.Nine edentulous volunteers, average age 74·2 ± 5·5 years and average denture experience 19·4 ± 19·5 years (1–50 years), had replacement dentures made. Functional impressions were taken after border moulding using zinc oxide eugenol paste. After a rehearsal session, MBF was recorded with the old dentures, and with the new dentures immediately at insertion, at 3, 8 days, 2–3 weeks, 1, 2, 3 and 6–10 months post-insertion (p.i.). The MBF was recorded with the central bearing point method using a full-bridge strain gauge with a confirmed linearity from 1 to 1000 N and an accuracy of ±1 N. Data were analysed off-line using the mean of two peak readings per patient per session.The results indicate that MBF tended to be impaired when replacement dentures were first fitted (n.s.). However, this trend reversed during the first month p.i. for patients with a ‘moderate’ lower ridge resorption of Atwood (1963) grade 3 or 4 (n=5). Patients with more severe lower ridge resorption (Atwood grade 5 or 6; n=4) showed a significantly lower MBF over the entire observation period (P=0·05) and took longer to regain bite strength. Only patients with moderate bone resorption exceeded their pre-insertion level of MBF within the observation period of 6–10 months p.i. In contrast to one report of immediate improvement of MBF at insertion of a new or relined denture (Leyka et al., 2000), the present study suggests that, at least for elderly patients with severe bone resorption, delayed improvement of MBF should be expected.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Superlattices and Microstructures 15 (1994), S. 11 
    ISSN: 0749-6036
    Keywords: Bloch oscillations, coherent wavepacket dynamics. Wannier-Stark states,
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 0550-3213
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 104 (1973), S. 15-31 
    ISSN: 1434-4475
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung 2-substituiertep-Naphthochinonesetzen sich mito-Phenylendiamin entweder unter Eliminierung des Substituenten zu Benzo[a]phenazin-5-ol (WegA) oder unter Addition und Oxydation zu 6-substituierten Benzo[a]phenazin-5-olen (WegB) um. Ein Zusammenhang zwischen Reaktionsweg und elektronischer Wirkung der Substituenten (ausgedrückt durch das Redoxpotential der Chinone) sowie weitere die Reaktion beeinflussende Faktoren werden aufgezeigt, Mechanismen für den Ablauf der Reaktion diskutiert.
    Notes: Abstract The reaction of 2-substituted p-naphthoquinones with o-phenylenediamine proceeds either with elimination of the substituent and formation of benzo[a]phenazin-5-ol (path A) or by addition and oxidation to 6-substituted benzo[a]phenazin-5-ols (pathB). The relationship between reaction path and electronic effect of the substituent, expressed by the redox potential of the quinones, and other factors which influence the reaction are indicated, and reaction mechanisms are discussed.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 128 (1997), S. 901-909 
    ISSN: 1434-4475
    Keywords: 2-Dialkylamino-p-benzoquinones ; 2,5-bis-Dialkylamino-p-benzoquinones ; 2-Dialkylamino-8-hydroxydibenzofurandiones-1,4 ; 2-Dialkylamino-5-p-hydroxy-phenoxy-p-benzoquinones ; 8-Hydroxydibenzofurandion-1,4
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary p-Benzoquinone (1) reacts with dialkylamines2a-d to 2-dialkylamino-p-benzoquinones3, 2,5-bis-dialkylamino-p-benzoquinones4, 2-dialkylamino-8-hydroxydibenzofuran-1,4-quinones5, and in pyridine also to 2-dialkylamino-5-p-hydroxy-phenoxy-p-benzoquinones6. A method affording almost exclusively3 has been developed which is also applicable to compounds2e-h.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1434-4475
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The “dihydronaphthodiphenazine” ofKehrmann, which is according toBadger andPettit reported to be “14-o-aminophenyl-13,14-dihydro-5,8,13,14-tetraaza-6,7-benzopentaphene”, is N-(o-aminophenyl)-benzo[a]phenazin-5-amine. This was proved by chemical and spectroscopic investigations. The structures of the derivatives prepared byBadger andPettit are also corrected and the acetylation processes are cleared up.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 81 (1950), S. 878-886 
    ISSN: 1434-4475
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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