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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 1597-1606 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Time-resolved four wave mixing (4WM) signals of conjugated polymers are calculated using a density matrix approach and the Hartree–Fock approximation. The influence of the Coulomb interaction as well as size effects on the nonlinear optical response are examined. For the Hückel model (no Coulomb interaction), quantum beats due to the coherent excitation of several band states are found for small sizes, and photon echo-like behavior is obtained for infinite size. The Coulomb interaction changes the nature of the response and gives rise to a broad delayed signal whose temporal profile is determined by the dephasing time.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 59 (1986), S. 859-863 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Amorphous rare-earth transition metal alloys of composition (Gd1−xFex)1−yAuy with x=0.74, 0.77, and 0≤y≤0.40 were prepared by evaporation onto rotating glass substrates. The magnetic and magneto-optic properties have been investigated in the temperature range 4.2≤T≤TC revealing a decrease of the compensation and Curie temperature, the uniaxial anisotropy, and the Faraday and Kerr rotation with increasing gold content. The temperature behavior can be interpreted in terms of a mean-field analysis indicating a pronounced influence of the gold on the iron moment and the exchange constants. The temperature dependence of the Faraday rotation can be described in terms of the sublattice magnetizations inferred from the fit of the mean-field theory to the measured saturation magnetization.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 61 (1987), S. 3331-3333 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: GdTbCo films were rf diode sputtered from a composite target varying the argon pressure PAr and the substrate bias voltage Vb. Both the uniaxial magnetic anisotropy constant Ku and the aging behavior of the films depend strongly on the preparation parameters. The absolute maximum of Ku was obtained at Vb=−150 V. However, at this bias voltage nearly the highest oxidation rate of unprotected 100-nm-thick films was observed. Films of highest stability are obtained without any bias voltage. The oxidation rate is correlated with the Ar concentration in the films. It was argued recently that the anisotropy of sputtered films could depend on argon incorporation. Our results seem to rule out this mechanism since GdTbCo films prepared at zero bias show a relative Ku maximum in dependence on PAr where the argon concentration is near its absolute minimum. The magneto-optic Kerr rotation θK of the films can only be correlated with the Co concentration for zero bias films. Some additional variation depending on the bias voltage has been observed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Alimentary pharmacology & therapeutics 7 (1993), S. 0 
    ISSN: 1365-2036
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1365-2036
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: The effects of the H+, K+-ATPase inhibitor BY 1023/SK&F 96022 on pentagastrin-stimulated acid secretion have been studied in healthy male volunteers (n= 12). The gastric acid response to submaximal pentagastrin-stimulation (0.6 μg/h/kg b.w.) was dose-dependently inhibited. A single dose of 5 mg decreased acid output by 22% while after 60 mg and 80 mg secretion was almost completely abolished.A good dose linearity was observed for AUC (0, 〉) and Cmax over the dose range from 5 to 80 mg. Elimination half-life, total clearance and volume of distribution of the parent compound were independent of the dose.The drug was well tolerated up to the highest dose of 80 mg. No clinically relevant influence was found on either laboratory screen or cardiovascular parameters.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Mathematical programming 49 (1990), S. 281-283 
    ISSN: 1436-4646
    Keywords: Linear duality ; polar duality ; closed sets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract A topological characterization is given for closed sets in ℚ n under the restriction of (cone) polar duality to ℚ n .
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 24 (1994), S. 1201-1205 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Holes in cation exchange membranes of alkali chloride cells can have a number of different causes. They do not represent a source of great danger during operation of a membrane electrolyser as long as their number is limited or their combined diameter does not exceed a certain size. Of the different methods for detection of holes in membranes, two procedures are described in detail: the cell voltage test and the leak test with measurement of the gas flow through the holes. The cell voltage test is performed with low time consumption during start-up of an electrolyser. It mainly shows the large membrane holes in a cell. In contrast to this, with the leak test all holes in a membrane are detected. However, the procedure is time consuming and is possible only with a totally drained electrolyser. It is recommended to perform these tests immediately after installing new membranes and then from time to time in order to avoid damage to the cells or to the plant chlorine system.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 23 (1993), S. 103-107 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract During the operation of an industrial-scale membrane electrolysis plant over a number of years, a record was kept of the formation of the byproduct oxygen in the anode gas and chlorate in the anolyte parallel to the decline of the current efficiencies of the main products. It was found that the current efficiencies of the byproducts increase linearly with the declining current efficiencies of the main products, chlorine and caustic soda. Of the two types of anode used, one exhibited considerably more oxygen formation than the other. The high-oxygen anode was associated with distinctly lower chlorate formation than the low-oxygen anode. The increasing oxygen contents and chlorate formation rates associated with falling caustic current efficiency are reported for both types of anode. If hydrochloric acid is used to destroy the chlorate, the amount of acid must be increased as the caustic current efficiency falls. The amounts of hydrochloric acid required for the two types of anode are calculated as examples for 96% and 93% caustic current efficiency.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1437-3262
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract Manganese nodules from the Kane Gap (a deep sea channel connecting the Sierra Leone and Gambia Basins off West Africa) were investigated chemically and dated by10Be along cross-sections. Comparing the nodule structure with the stratigraphy of the related sediments, the following conclusions are drawn concerning the sedimentation processes during the last 4 to 6×106 years: The growth of the nodules started about 4 to 4.5 Ma before present during or near to the end of a period of erosion on a fossil-free, probably Miocene sediment. During the first phase of only a few hundred thousandyears, the nodules grew very quickly (7 to 〉18 mm/Ma). Fe-rich hydrogenetic material formed the internal sections of the nodules during this time. Slowing down of the bottom currents, resulting in deposition of thin sediment covers for short intervals, caused the character of the nodules to change to a more diagenetic composition. The growth rates were reduced to about 1 to 2 mm/Ma. The time of slowing is roughly 3 to 4 Ma BP. Probable uncertainties of the dating and growth rates resulting from supposed changes of the10Be supply to the nodules due to variations of the near bottom environment are discussed.
    Abstract: Résumé Le «Kana Gap» est un chenal sous-marin qui relie les bassins de Sierra Leone et de Gambie, au large de l'Afrique occidentale. Des nodules de manganèse, recueillis le long de profils transversaux dans ce chenal, ont fait l'objet d'une étude chimique et d'une détermination d'âge10Be. La comparaison entre la structure des nodules et la stratigraphie des sédiments sous-jacents permet de tirer les conclusions suivantes relatives au processus sédimentaire au cours des 4 à 6 derniers Ma. La croissance des nodules a commencé il y a environ 4 à 4,5 Ma pendant ou juste après un épisode d'érosion sous-marine sur des sédiments non fossilifères, probablement miocènes. Au cours d'une première phase d'une durée de quelques centaines de milliers d'années, la croissance a été très rapide (7 à 〉 18 mm par Ma) avec formation de la partie centrale du nodule, constituée de matière hydrogénée riche en Fe. Ensuite, après ralentissement des courants de fond et dépôt probable d'une mince couche de sédiment, le caractère des nodules a évolué vers une composition plus diagénétique, avec réduction du taux de croissance à 1 à 2 mm par Ma. Le moment de ce changement de régime doit se situer entre 3 et 4 Ma. Des changements dans les conditions de milieu sur le fond de la mer pourraient avoir provoqué une variation de la quantité de10Be apportée aux nodules, d'où résulterait une incertitude sur l'estimation des âges et du taux de croissance; cette question est discutée par les auteurs.
    Notes: Zusammenfassung An Manganknollen aus der Kane-Lücke, dem Verbindungskanal zwischen Sierra Leone Becken und Gambia Becken (vor W-Afrika) wurden entlang Querprofilen durch mehrere Knollen chemische Untersuchungen und10Be Altersbestimmungen durchgeführt. Durch Vergleich des Aufbaus der Knollen mit der Stratigraphie des unterlagernden Sediments werden Rückschlüsse auf Veränderungen des Sedimentationsgeschehens während der letzten 4–6×106 Jahre gezogen. Hiernach begann das Wachstum der Knollen vor maximal 4.5×106 Jahren während oder gegen Ende einer Erosionsphase auf fossilfreiem, vermutlich miozänem Sediment. Während der ersten Phase wuchsen die Knollen über wenige 100000 Jahre sehr schnell (7 bis〉18 mm/106 Jahre). Hierbei schied sich Fe-reiche Knollensubstanz hydrogener Zusammensetzung ab. Nach Verringerung der Strömung und vermutlich zeitweiser Bildung von dünnen Sedimentschleiern änderte sich der Charakter der Knollen zu mehr diagnetischer Zusammensetzung bei wesentlich reduziertem Wachstum (ca. 1 bis 2 mm/106 Jahre). Der Zeitpunkt der Umstellung ist nur sehr grob zu ermitteln, er dürfte etwa zwischen 3 und 4×106 Jahren vor heute liegen. Eventuelle Unsicherheiten bei der Datierung und den Wachstumsraten, die möglicherweise aus milieubedingten Änderungen in der10Be Versorgung der Knollen resultieren, werden diskutiert.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1573-0581
    Keywords: volcanology ; hotspot ; Pacific ; Macdonald ; petrology ; Austral Islands
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The southeastern extension of the Austral Islands volcanic chain terminates near 29°S, 140°W at the active Macdonald Seamount. The ‘hotspot’ region near Macdonald consists of at least five other volcanic edifices each more than 500 m high, included in an area about 50–100 km in diameter. On the basis of the sea-floor topography, the southeastern limit of the hotspot area is located about 20 km east of the base of Macdonald, where it is defined by the 3950 m isobath. At the edge of the hotspot area, there is a marked deepening of the seafloor from c.3900 m down to 4000–4300 m. The deeper sea-floor is faulted and heavily sedimented. The Macdonald volcano itself stands 3760 m above the surrounding seafloor, and has a basal diameter of 45 km. Its summit in January 1987 was 39 m below sea level, and it seems likely that Macdonald will emerge at the surface in the near future. Recent (March and November 1986) phreatic explosions on Macdonald Seamount erupted fragments of ultramafic and mafic plutonic blocks together with basic lapilli (volcaniclastic sand). The plutonic blocks have been variably altered and metamorphosed, and in some cases show signs of mineralisation (disseminated sulphides). The blocks presumably come from deeper levels in the volcanic system. The volcanics so far dredged from Macdonald consist of olivine and clinopyroxene cumulus-enriched basalts, evolved basalts, and mugearite. On the basis of incompatible element variations, simple crystal fractionation seems to be controlling the chemical evolution of Macdonald magmas.
    Type of Medium: Electronic Resource
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