Electronic Resource
Woodbury, NY
:
American Institute of Physics (AIP)
Applied Physics Letters
59 (1991), S. 2817-2819
ISSN:
1077-3118
Source:
AIP Digital Archive
Topics:
Physics
Notes:
Swelling of micrometer thick-films of plasma-polymerized tetrafluoroethylene has been measured for a range of solvents using an optical-interferometric technique. For low gas-phase concentrations of the solvent, the swelling is found to correlate with the ionization potential of the solvent. Photo-thermal deflection spectroscopy of the films shows optical absorption in the infrared, which changes with exposure to different solvents. Both of these results suggest weak electron transfer from the solvent to the polymer as the dominant interaction mechanism.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.106403
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