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  • 1985-1989  (19)
Material
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 3061-3071 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This work reports the measurements of rate coefficients for excitation transfer reactions of metastable He(2 3S) atoms, produced in 0.3–4 atm of helium, with various reactants presenting a wide range of characteristics. In all cases studied, three-body reaction channels were identified with most probable values of rate coefficients lying in the range from 0.2 to 6.7×10−31 cm6 s−1, for Ne and N2O, respectively. These are generally more than one order of magnitude smaller than previously reported. The interpretation of this discrepancy in terms of a more reactive intermediate He2(Σ*) complex in dynamic equilibrium with the He(2 3S) population seems to be confirmed, and is analyzed in some detail.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 82 (1985), S. 2274-2279 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This work reports the characterization of late time periods in the decay of metastable He(2 3S) atoms produced in 1–4 atm of helium containing up to 1400 mTorr of N2. Results have been obtained that exploit the large dynamic range and high data acquisition rates available from time resolved spectroscopic studies of preionized stripline discharges. A new value was found for the termolecular reaction of (2 3S) with N2 of 1.5×10−31 cm6 s−1 that is in good agreement with a model of collisionally induced capture. An indirect channel of reaction was also found that seems to explain the anomalously rapid and conflicting termolecular rates that were previously reported.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 82 (1985), S. 4965-4976 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This report belongs to a series concerned with the correlation of photolysis bands observed in electronic transition spectra of simple molecules with their dissociation products. In this work a time-delayed, double resonance application of optical impedance spectroscopy was used for the study of the state selective photolysis of Cs2 excited in the yellow range of visible wavelengths. Two independently tunable dye lasers were synchronously pulsed, the first being used to dissociate the constituents of the sample along the various possible channels and the second, delayed pulse being used to identify the products by exciting them selectively into easily detected Rydberg states. The time between photolysis and detection could be varied, starting from a value too short to permit collisional mixing or radiative cascading of the products. Particular attention was paid to the photolytic production of the fine structure components of the first and second electronically excited state of atomic cesium and to the subsequent processes which tended to degrade the selectivity produced in the initial distributions of product populations among the available states. Data were fit to a quantitative model from which rate coefficients could be extracted for various mixing processes. Reported here is what appears to be a first value for the fine-structure mixing cross section (5 2D5/2→5 2D3/2) of 17 A(ring)2±60%. In addition a delayed process for the selective production of Cs(5 2D) atoms was found to result from the excitation of a state having a lifetime less than 100 ns that is tentatively identified as a molecular state correlated with Cs(5 2D), possibly 5d 3Δu.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 59 (1988), S. 2260-2264 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Eight triaxial Blumleins have been stacked in series at one end while being synchronously commuted at the other end with a single hydrogen thyratron. Significant voltage gain has been maintained in the stack for periods of the order of 20 ns. Having no other switching elements, operation has been possible at repetition rates to 100 Hz. An x-ray diode has been matched to this pulse power source, making possible the emission of an average bremsstrahlung dose of 5.8 R/s from a sequence of 20-ns pulses. In less than 4 min of operation at 100 Hz, a dose of 1 kR could have been delivered to a target sample. When operated at 50-kV charging voltage, spectral measurements show the output to be a true continuum, peaking at intensities in excess of 2×108 keV/keV/shot and containing useful intensities of photons having energies of 150 keV.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 60 (1989), S. 3258-3261 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A technique is described which demonstrates how a frequency modulation spectrometer (FMS) can be used to measure the isomer shift of ferromagnetic absorbers without mechanical tuning. As an example, the isomer shift of an iron sample relative to a 57Co source in a Pd matrix was measured and found to be −(0.1869±0.003) mm/s compared to the literature value of −(0.185±0.02) mm/s.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 58 (1987), S. 2157-2160 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A new method is reported for calibrating bremsstrahlung spectra in the 200–1000-keV range with x-ray activation techniques. This approach is particularly significant for pulsed sources that cannot be characterized with conventional spectroscopy methods.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 2338-2340 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 216-218 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Amorphic diamond films characterized by a high percentage of sp3 bonds have been prepared in an UHV environment with a laser plasma source of carbon ions. Peak power densities in excess of 1011 W/cm2 were found necessary to produce films at growth rates of 0.5 μm/h over areas of 20 cm2 having optical quality sufficient to show bright interference colors.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 53 (1988), S. 187-188 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Diamond-like carbon films have been deposited onto clean, unseeded substrates using a hybrid ion beam technique. In this method the ion fluences available for acceleration were particularly enhanced by the use of laser ablation plumes ejected from highly purified graphite targets. The combination of levels of purity characteristic of ultrahigh vacuum environments, large ratios of ion to neutral concentrations, and high fluences showed considerable merit for the growth of large-area (10 cm2 ) films of optical quality and uniformity at deposition rates approaching 20 μm/h.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 58 (1987), S. 2103-2109 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Described here is the scaling of a repetitively pulsed, flash x-ray source to yield 140-mW average power in 15-ns pulses of radiation near 1 A(ring). Interchangeability of discharge anodes has provided for a significant fraction of the output to be extracted in the K lines of Cu, Mo, Nb, and Ag. In less than 1 min of experimental time, a peak spectral density is radiated that exceeds 1×1018 keV/keV. For some applications this device can offer a tabletop alternative to laser plasma x rays and to synchrotron radiation.
    Type of Medium: Electronic Resource
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