ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A flow system has been developed to study relative rate coefficients of hydroxyl radicals reacting with alkanes under conditions relating to tropospheric chemistry. Relative Arrhenius parameters have been measured over the temperature range 243-328 K for pairs of alkanes from a list consisting of n-butane, 2-methylpropane, n-pentane, n-hexane, 2,2- and 2,3-dimethylbutane, 2,3,3-trimethylbutane, and 2,3,4-trimethylpentane.The results have been incorporated into a Structure-Activity Relation for hydroxylalkane reactions which leads to the following group rate coefficients for a temperature range of 240-500 K. \documentclass{article}\pagestyle{empty}\begin{document}$$\begin{array}{rcl} k_{{\rm prime}}^0 &=& 3.13 \times 10^{ - 12}\, {\rm exp(} - 904/T)\,{\rm cm}^{\rm 3}\, {\rm molecule}^{ - 1}\, {\rm s}^{ - 1} \\ k_{{\rm sec}}^0 &=& 2.45 \times 10^{ - 12} \,{\rm exp(} - 320/T)\,{\rm cm}^{\rm 3}\, {\rm molecule}^{ - 1}\, {\rm s}^{ - 1} \\ k_{{\rm tert}}^0 &=& 1.88 \times 10^{ - 12} \,{\rm cm}^{\rm 3}\, {\rm molecule}^{ - 1}\, {\rm s}^{ - 1} \end{array}$$\end{document}
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550201203
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