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  • 1985-1989  (3)
  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 2922-2928 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The shape of the liquid–liquid coexistence curve of five binary liquid mixtures containing methanol (methanol, methanol-d1, methanol-d4) and cyclohexane (cyclohexane, cyclohexane-d12) is studied using a differential refractometer. It is found that all systems have approximately the same critical composition (mole fraction) and approximately the same shape of the coexistence curve in the vicinity of the critical point. However, the critical temperature changes in a characteristic manner. Replacement of hydrogen atoms involved in hydrogen bonding by deuterium leads to an increase of the critical temperature of about 1.2 K for each replaced hydrogen atom. Replacement of hydrogen atoms not involved in hydrogen bonding leads to a decrease of the critical temperature of about 0.3 K for each replaced hydrogen atom. These are average values referring to the systems methanol/cyclohexane, phenol-d6/D2O, deutero-isobutyric acid (COOH)/H2O, and deutero-isobutyric acid (COOD)/D2O. Substitution of H2O by D2O in the four component system benzene, ethanol, water, ammonium sulfate of near tricritical composition increases a characteristic temperature by about 1 K.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Naturwissenschaften 74 (1987), S. 528-535 
    ISSN: 1432-1904
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 264 (1986), S. 159-166 
    ISSN: 1435-1536
    Keywords: Membrane ; mica ; pores ; transport properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The electrochemical properties of the pore wall of track-etched mica membranes are modified (a) by covalent binding of positively and negatively charged groups, and (b) by adsorption of cationic and amonic polyelectrolytes. The electrochemical properties of the pore wall are characterized by measurements of membrane potential, electrical conductivity and streaming potential. By these methods it is possible to change the sign of the surface charge density of the pore wall and to increase its absolute value by a factor of about 30 compared with that of the unmodified pore wall. Changes of electrochemical properties of the pore wall are desirable in studies of negative osmosis and incongruent electrolyte transport in membranes with known pore structure.
    Type of Medium: Electronic Resource
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