ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The spontaneous decomposition of the compounds MoOF2(S2CNR2)2, where R = Et or n-Pr yields salts containing the new cation [MoO(S2CNR2)3]+ and the dimeric anion [Mo2O4F6]2− The structure of the ethyl derivative has been determined by x-ray diffraction techniques. It crystallizes in space group C2/c with a = 27.3 56(4) Å, b = 17.292(3) Å, c = 12.716(3) A,β = 103.76(3)°. All atoms, including the thirty hydrogen atoms, were used in a least-squares procedure with convergence to a conventional R factor of 0.045. The i.r. and far i.r. spectra are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01753071
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