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  • Analytical Chemistry and Spectroscopy  (1)
  • Standard reference material  (1)
  • 1
    ISSN: 1432-0517
    Keywords: Key words Experimental design ; Analysis of variance (ANOVA) ; Determination of uncertainties ; Human serum ; Cholesterol ; Standard reference material
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract  Repeated subsampling or a hierarchical design of experiments combined with an analysis of variance (ANOVA) is demonstrated to be a useful tool in the determination of uncertainty components in amount-of-substance measurements. With the reference material of human serum as investigated here for total cholesterol, besides several in-laboratory sources of uncertainty, a vial-to-vial effect which can be regarded as an off-laboratory source was found to be significant. This knowledge might be essential when the material is used for calibration and for the self-assessment of a laboratory.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal of Chemometrics 3 (1989), S. 537-540 
    ISSN: 0886-9383
    Keywords: Cluster analysis ; Display ; Interlaboratory test ; Ultrametrics ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ultrametric inter-object distances found by hierarchical clustering may be used to generate and appropriate constellation of points in a plane. A configuration of points which reproduce the ultrametric distances in a low-dimensional space as closely as possible can be found by Torgerson's method of multidimensional scaling. The resulting display supports the cognition of clusters very well, and for this purpose it seems to be superior to, for instance, the frequently applied principal components display. In certain situations dedrograms are expected to become simpler to interpret when such complementary ‘cluster display’ is also consulted. An example from analytical chemistry is presented.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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