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  • Analytical Chemistry and Spectroscopy  (12)
  • Boundedness  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 9 (1974), S. 555-557 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The fragmentation reaction [C3(H,D)6]+· → [C3(H,D)5]+ + (H, D) has been examined in the metastable decomposition region for two pairs of labelled propenes: CH3CD=CH2,CD3CH=CD2 and CD3CH=CH2, CH3CD=CD2. The results indicate that complete hydrogen scrambling occurs in the propene molecular ion prior to fragmentation. The isotope effect kH/kD is in the range 2·1 to 3·3.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 8 (1988), S. 617-641 
    ISSN: 0271-2091
    Keywords: Higher order ; Boundedness ; Convective transport ; Curvature ; Finite difference ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The paper describes a new approach to approximating the convection term found in typical steady-state transport equations. A polynomial-based discretization scheme is constructed around a technique called ‘curvature compensation’; the resultant curvature-compensated convective transport approximation is essentially third-order accurate in regions of the solution domain where the concept of order is meaningful. In addition, in linear scalar transport problems it preserves the boundedness of solutions. Sharp changes in gradient in the dependent variable are handled particularly well. But above all, the scheme, when used in conjunction with an ADI pentadiagonal solver, is easy to implement with relatively low computational cost, representing an effective algorithm for the simulation of multi-dimensional fluid flows. Two linear test problems, for the case of transport by pure convection, are employed in order to assess the merit of the method.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 19 (1988), S. 517-522 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance CARS measurements of the photoisomeriztion process of bisdimethylaminoheptamethine under different resonance and excitation conditions are presented and compared with model calculations. A Six-level model - a Rulliere-type model extended by one level - is suggested.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 19 (1988), S. 353-357 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance CARS line-shape analysis has been applied to determine the parameters of the excited electronic state potential curves of a cyanine dye and its short-lived photoisomers during the process of photoisomerization. For this very complicated situation other methods for the estimation of these values would fail. The origin shift parameters determined are very small and the homogeneous line width is smaller than the line width of the absorption band.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 21 (1990), S. 835-839 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A theoretical and experimental comparison of coherent anti-Stokes Raman scattering (CARS) and Raman-induced phase conjugation (RIPC) techniques has been carried out. In most cases the RIPC techniques are much more sensitive than CARS to deviations from the phase-matching conditions, from which it follows that for RIPC much higher accuracy of the alignment and optical homogeneity are necessary. In practice, only one RIPC variant with nearly copropagating pump waves and contrapropagating Stokes waves is applicable to obtain complete spectra. A CARS reflection technique is discussed for the investigation of highly absorbing samples.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 17 (1986), S. 425-430 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An extension of the Fleming and Johnson procedure is presented for determining the molecular third-order susceptibility parameters from three characteristic intensities within a CARS line profile (Imax, Imin, Imid). For CARS excitation close to a molecular one-photon resonance, these three intensity values taken from one spectrum do not suffice for the determination of all relevant parameters. A simple procedure is given for overcoming this by combining the information from all the spectra within a concentration series, keeping the frequency of the CARS pump laser fixed. Uncertainty in the measured Imid value is overcome by applying a least-squares fit of the spectra.Results obtained from resonance CARS measurements for Rhodamine 6G in ethanol are given.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 18 (1987), S. 323-326 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance CARS spectra of the short-lived photoisomer of pinacyanol were obtained. From the CARS line frequencies, intensities, line shapes and depolarization ratios it can be concluded that a cis-isomer rather than a twisted configuration is observed.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 20 (1989), S. 183-189 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Model calculations of the absorption and the four quantities representing third-order non-linear susceptibility [the real and imaginary part of the excitation profile and of the resonance background component for resonance coherent anti-Stokes Raman scattering (CARS), R, J, b′ and b″, respectively] were carried out for polyatomic molecules. Comparison with previously acquired experimental data for bisdimethylaminoheptamethine perchlorate shows satisfactory agreement, except for b′ and b″. Some molecular parameters (the shift parameter of the active vibrations and the vibronic relaxation constant) were estimated. It is concluded that the resonance background is more sensitive to the model than the absorption and the excitation profile.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance Raman spectra of the three isoelectronic proton transfer systems 2-(2′-hydroxy-5′-methylphenyl)-benzotriazole (TIN), 2-(2′-hydroxyphenyl)benzothiazole (HBT) and 2-(2′-hydroxyphenyl)benzoxazole (HBO) were measured with excitation in the range of the S0-S1 absorption band of the enol tautomers. In each compound, about 15 modes in the wavenumber range between 120 and 1650 cm-1 show a strong coupling to the electronic transition. In TIN and HBT, combination tones of the strongest mode below 500 cm-1 and the vibrations at higher wavenumbers point to the strong anharmonicity of the low wavenumber motion. The experimental results are analysed by normal-mode calculations, which provide insight into the microscopic elongations in the molecules. The coupling strengths derived from the spectra are used to calculate the envelope of the S0-S1 absorption bands of TIN and HBT, reproducing the measured spectra very well. Theoretical simulations of the combination tone spectra give information on the vibrational modes involved in excited-state proton transfer.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 6 (1977), S. 193-194 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Substantial progress has been made in spontaneous Raman spectroscopy by the use of lasers as a source of excitation radiation. Moreover the development of high-power pulse lasers provided access to a new class of scattering processes-the non-linear Raman effects. The methodical development of the non-linear Raman effects is now at a state whereby in special cases it is possible to obtain better spectra than with the use of spontaneous Raman scattering. This paper describes one of the non-linear Raman effects - inverse Raman scattering - on some samples taken from two groups of technically interesting substances.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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