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  • 1
    Electronic Resource
    Electronic Resource
    Rheology-morphology relationships in nylon 6/liquid-crystalline polymer blends (1990)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 7-12 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Extrusion measurements have been carried out on blends of nylon 6 and a liquid-crystalline copolyesteramide (LCP). The flow curves at low temperature show a behavior similar to that of pure LCP with a rapid rise of the viscosity at low shear rates. At high shear rates the viscosity is lower than that for each of the two components. This minimum has been attributed to the lack of interactions between the two phases and to the formation of fibrils of the LCP phase. The SEM analysis shows, indeed, that fibrils of the LCP phase are produced in the convergent flow at the inlet of the capillary at high shear rates. These fibrils are lost during the flow in the long capillary.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760300103
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  • 2
    Electronic Resource
    Electronic Resource
    Rheological behavior of a semirigid liquid crystal polymer (1993)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 944-949 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The rheological behavior of liquid crystal polymers is still far from completely clarified from both experimental and theoretical points of view. In this paper, the shear flow and the non-isothermal elongation flow behavior of a semirigid liquid crystal copolyester is discussed. The viscosity strongly decreases when the test temperature is increased above the crystal-nematic transition temperature; below this temperature the viscosity is very high. The thermal history strongly affects the shear viscosity. The elongational flow behavior depends also on temperature. Above the crystal-nematic transition temperature and the mesophase is easily spinnable, whereas below this temperature, the spinnability is very poor.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760331503
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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