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  • 1
    ISSN: 1434-601X
    Keywords: 14.60.Cd ; 25.70.Cd ; 25.70.Ef
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We present the results obtained from systematic studies of positron creation for a series of heavy-collision systems, with united chargeZ u =Z 1 +Z 2 ranging fromZ u =164 (Pb + Pb) toZ u =184 (U+U) at bombarding energies close to the Coulomb barrier, using the Orangeβ-spectrometer at GSI. For each collision system studied, the dominating continuous distributions due to quasiatomic and nuclear positron emission are determined accurately. This is essential in obtaining the characteristics of the still unexplained monoenergetic positron lines which appear in the energy range between 200 keV and 400 keV. Our results are compared with coupled-channels calculations for quasi-atomic positron creation. The latter describe quite well the global features of the measured spectra, but overestimate systematically their absolute values. From the comparison, a common normalization factor of about 0.75 can be established for the calculated spectra. In particular, the dependence onZ u of the measured emission probabilities was found to follow a power law (∝Z u 195±1), in fair agreement with the theoretical prediction.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-601X
    Keywords: 14.60.Cd ; 25.70.Cd ; 25.70.Ef
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We present the results obtained from a series of ρ+ρ−-coincidence measurements in heavy-ion collisions using the double-Orangeβ-spectrometer at GSI. The collision systems U+U, U+Pb, and U+Ta were investigated at bombarding energies close to and slightly above (U+Ta) the Coulomb barrier. For all systems studied, very narrow (FWHM−20 keV) ρ+ρ− lines were observed in the sum-energy spectra, with kinetic energies ranging from ∼555 keV to ∼810 keV, superimposed on a continuous distribution mainly due to uncorrelated ρ+ρ− emission. Particularly in the U+Ta system, a pronounced sum-energy line appears at ∼634 keV, predominantly in deep-inelastic collisions. In some cases (e.g. U+Pb) the line characteristics is consistent with a two-body decay mode of an emitter which moves with the c.m. velocity of the colliding ions. However, other lines, and in particular the 634 keV line (U+Ta), exhibit a rather isotropical opening-angle distribution whereas their energy is unequally shared between positrons and electrons, thus being in clear disagreement with this scenario. In general, the data preclude an emission from the separated (moving) nuclei, and, in the latter cases, provide evidence that the e+e−-pair decay occurs in the vicinity of the Coulomb field of a third heavy (positively charged) partner having only a small transverse velocity (|v|⊥〈0.02c)
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 328 (1987), S. 129-145 
    ISSN: 1434-601X
    Keywords: 14.60.Cd ; 25.70.Cd ; 25.70.Ef
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Positron lines were observed in heavy ion-atom collisions at bombarding energies close to the Coulomb barrier in subcritical systems with the sum of the atomic numbers of the colliding nucleiZ u =Z 1+Z 2 being smaller thanZ u =172. Each collision system, studied,208Pb +208Pb(Zu=164),238U+181Ta(Zu=165), and238Au(Zu=171), exhibits the emission of two positron lines withZ u -independent c.m. energies of ∼ 258 keV and ∼ 340 keV, and with widths of about 30 keV, superimposed on continuous positron spectra from nuclear pair decay and pair emission induced by the time changing Coulomb field of the collision. The production cross section of thee +-lines rises with a high power ofZ u (ocZ u 22), which is comparable to theZ u 20-dependence for the collision induced positrons.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 16 (1933), S. 1201-1208 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 16 (1933), S. 54-69 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 16 (1933), S. 468-478 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 16 (1933), S. 375-382 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurde gezeigt, dass bei der Fällung der Schwermetallferro-cyanide aus verdünnter Lösung (Konzentration der Metallsalze und des Ferrocyanids 0,01- bis 0,005-m.) charakteristische Maxima der Viskosität auftreten, deren Lage angenähert stöchiometrischen Verhältnissen der reagierenden Ionen entspricht, wobei aber der Permutit-charakter der Niederschläge eine Rolle spielt.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dinucleoside monophosphates bearing usual protecting groups at the exocyclic amino functions of the heterocyclic bases, the 5′-hydroxy group, the phosphate moiety and the O-6-position of the guanine ring have been analysed by FAB mass specrometry in the negative ion mode. These non-charged key intermediates for oligodeoxynucleotide synthesis exhibit very simple spectra in the mass range of m/z 400-1500 using tetra-ethylene glycol as matrix. Most of the observed ions could easily be assigned. Apart from deprotonated molecular ions sequence specific ions arising from C-O-P bond cleavage and ions derived from loss of protecting groups were observed. The simplicity of spectra interpretation makes FAB mass spectrometry to a rapid and valuable tool for unambiguous identification of dimeric synthons for oligonucleotide synthesis.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 3 (1980), S. 415-416 
    ISSN: 0935-6304
    Keywords: Gas chromatography/mass spectrometry ; Volatile sulfur compounds from waste water ; Adsorption of air samples on tenax GC ; Mechanism of corrosion of concrete ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 24 (1993), S. 131-141 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Arc-PVD-Coating of Cemented Carbides and Analysis of their Functional Behaviour in Interrupted Cut MachiningInterrupted machining of quenched and tempered steel demands the application of tools with high resistance against mechanically and tribologically induced wear. These demands can not be fully satisfied by uncoated carbides. Also CVD-coatings give only some improvement due to a certain embrittlement of the substrate during the coating process. PVD-coatings deposited at low temperatures without affection of the substrate lower the influence of the relevant wear mechanisms preferably at moderate cutting speeds.The combination of tough substrates with structural and compositional optimized coatings results in a multiplication of tool life within the whole range of low and medium cutting speeds. Coatings with homogenious structure, compressive residual stresses and high content of metalloides ensure excellent resistance against wear.Titanium-carbonitride deposited on carbide was found to be superiour compared with other carbonitride, nitride and carbide coatings within the system Ti—Zr—C—N due to excellent tribological properties. It was optimal suited for the interrupted cut application.
    Notes: Die Zerspanung von höherfesten Stahlwerkstoffen in unterbrochenen Schnitten stellt an die Werkzeuge hohe mechanische und tribologische Anforderungen, denen unbeschichtete Hartmetalle in vielen Fällen nicht gerecht werden können. Während sich bei der Zerspanung von höherfestem Stahl in stark unterbrochenen Schnitten durch die CVD-Beschichtung von Hartmetallen auf-grund prozeßbedingter Versprödungseffekte kaum Leistungssteigerungen erzielen lassen, können PVD-Hartstoffbeschichtungen, die bei substratschonend niedrigen Prozeßtemperaturen abgeschieden werden, dem Auftreten der relevanten Schädigungsmechanismen besonders bei niedrigen und mittleren Schnittgeschwindigkeiten entscheidend entgegenwirken.Insbesondere mit zähen Substratsorten sowie mit strukturell und kompositionell optimierten Schichten können Standzeitvervielfachungen im gesamten unteren und mittleren Schnittgeschwindigkeitsbereich erzielt werden. Homogene Schichtstrukturen, hohe Druckeigenspannungen und hohe Metalloidgehalte der Hartstoff-schichten gewährleisten eine hohe Verschleißfestigkeit. Titankarbonitrid zeichnet sich auf Hartmetallen gegenüber anderen karbonitridischen, nitridischen und karbidischen Schichten des Systems Ti—Zr—C—N durch ein besonders günstiges tribologisches Verhalten aus und hat sich als optimaler Beschichtungswerkstoff für unterbrochene Schnitte erwiesen.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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