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  • Chemistry  (4)
  • 77K fluorescence  (1)
  • Holographic grating  (1)
  • 1
    ISSN: 1432-1939
    Schlagwort(e): Photoinhibition ; Crassulacean acid metabolism (CAM) ; 77K fluorescence ; Quantum yield ; Stress physiology
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Summary Diurnal measurements of low temperature (77K) fluorescence at 690 nm (PS II) from north, south, east, and west facing cladode surfaces of Opuntia basilaris in Death Valley, California were made on six occasions during 1985. The absolute levels of F o(instantaneous fluorescence) and F m(maximum fluorescence), as well as the ratio F v/F m(variable fluorescence, F m-F o, over maximum fluorescence), were greater in the north face relative to the other faces. Diurnal decreases in F o, F mand F v/F mwere found concomitant with increases in incident photon flux area density (PFD). F v/F mwas fairly low throughout the year, indicative of photoinhibition, but became somewhat elevated after a spring rain. In early fall the quantum yield of the south face was considerably depressed relative to that of the north face, and corresponding differences were observed in F v/F m. A decrease in PFD during growth of glasshouse plants led to an increase in chlorophyll concentration, F oand F m, but not F v/F m. Although there was some variability in the quantum yield of well watered glasshouse cladodes, a correlation was found between quantum yield and the light and CO2 saturated rate of photosynthesis. When O. basilaris was water stressed under glasshouse conditions, reductions in quantum yield, F m, and F v/F mwere observed. Reductions in F v/F malways indicated a reduced quantum yield, although the converse was not necessarily so in well watered glasshouse plants. The results of this study indicate that O. basilaris is likely to experience photoinhibition throughout much of its life in Death Valley.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Advanced Materials for Optics and Electronics 1 (1992), S. 293-297 
    ISSN: 1057-9257
    Schlagwort(e): Liquid crystals ; Spiropyran ; Holographic grating ; Optical data storage ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: The application of liquid crystalline siloxanes consisting of pentamethylhydrocyclosiloxane cores with attached cholesteryl-, biphenyl- and photochromic spiropyran-based mesogens as reversible optical data storage materials is demonstrated by grating formation with an argon ion laser beam operating in the UV and visible regions. Erasure of the gratings with heat or visible radiation was possible.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 23 (1983), S. 784-788 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Experimental studies of fiber wet-spinning and solution processing of films of molecular composites are presented. The rigid rod polymer was poly (p-phenylenebenzobisthiazole) (PPBT) and the flexible polymers were poly (2,5(6′)-benzimidazole) (ABPBI) and poly (2,5(6′)-benzothiazole) (ABPBT). Effects of the flexible polymer molecular entanglements in solution on the processing are discussed. These fibers and films have very high modulus and strength, which improve upon heat treatment. The uniaxial modulus of highly oriented molecular composites follows the linear rule of mixtures.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 61 (1996), S. 1163-1171 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: An investigation was made of the optical and waveguiding properties of thin films fabricated from solutions of chitosan-acetic acid (chitosan/HAc) and chitosan/HAc doped with rare-earth metal ions (Er+++ or Nd+++). For all three films, the refractive indices were approximately 1.5 and there was nearly no absorption in the range of 300 to 2700 nm. The optical loss in a waveguides was less than 0.5 dB/cm. Morphological observations disclosed that all the films possessed a dense and homogeneous amorphous structure with smooth surfaces. Extrinsic scattering, especially the scattering caused by surface impurities, was the dominating factor affecting the optical loss value. It is also interesting to note that for all the films, doped with rare-earth metal ions or not, the morphological characteristics were alike and the optical properties were similar. Doping rare-earth metal ions into chitosan thin films did not seriously influence optical waveguiding. This paper reports, we believe, the first study of chitosan films for optical applications. The experimental results demonstrate that chitosan and its derivatives are potential candidates for optical materials. © 1996 John Wiley & Sons, Inc.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 31 (1993), S. 1975-1982 
    ISSN: 0887-6266
    Schlagwort(e): poly(p-phenylene) oligomer ; p-sexiphenyl ; molecular dynamics ; thermal expansion ; rigid-rod polymers ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: We have studied the conformation and coefficient of thermal expansion in the poly(p-phenylene) oligomer p-sexiphenyl (C36H26) by molecular dynamics simulations. Studies of the backbone phenyl-phenyl torsion angle in a simulated p-sexiphenyl crystal at room temperature indicate the presence of torsional librations of approximately ±20°. Further analysis of the phenyl-phenyl backbone torsion angle in less closely packed regions of the simulated crystal (crystal ends) indicate the presence of 180° phenyl ring flips, in agreement with solid-state deuterium NMR data on poly(p-phenylene oligomers). The linear coefficient of thermal expansion was also calculated and found to be negative, in qualitative agreement with experimental data on rigid-rod compounds. © 1993 John Wiley & Sons, Inc.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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