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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 127 (1996), S. 801-810 
    ISSN: 1434-4475
    Keywords: Vanadyl(IV). Benzylmalonato complex ; IR ; Raman ; ESR ; Electronic spectra ; Thermal behaviour
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Summary The sodium, ammonium, and lead(II) salts of the novel vanadyl(IV) complex bis(benzylmalonato)aquaoxovanadium(IV) have been prepared for the first time. They were characterized by means of electronic, IR, Raman and ESR spectroscopy. The thermal behaviour of the salts was investigated using TG and DTA methods.
    Notes: Zusammenfassung Die Natrium-, Ammonium- und Blei(II)-Salze des neuen Vanadyl(IV)-KomplexesBis(benzylmalonato)aquaoxovanadium(IV)wurden erstmalig dargestellt und mittels Elektronen-, IR-, Raman- und ESR-Spektroskopie characterisiert. Das thermische Verhalten dieser Salze wurde anhand von TG- und DTA-Messungen untersucht.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 124 (1993), S. 355-366 
    ISSN: 1434-4475
    Keywords: Vanadyl(IV) saccharinate ; IR spectra ; Electronic spectra ; Magnetic and thermal behaviour
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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