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Digitale Medien

Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat (1993)

Ferrer, E. G. ; Etcheverry, S. B. ; Baran, E. J.

Springer

Monatshefte für Chemie 124 (1993), S. 355-366

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Details

ISSN: 1434-4475

Schlagwort(e): Vanadyl(IV) saccharinate ; IR spectra ; Electronic spectra ; Magnetic and thermal behaviour

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Summary The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00814132

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