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  • 66.30. Jt  (2)
  • PACS: 61.72.Vv; 61.72.Cc; 66.30.Jt  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 35 (1984), S. 227-232 
    ISSN: 1432-0630
    Keywords: 66.30. Jt ; 61.70. Tm
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The diffusion of N in the group VI B metals Cr and W has been studied in the previously uninvestigated temperature ranges 300°–550 °C (Cr) and 600°–800 °C (W) using ion-beam techniques. Diffusion couples were created by ion-implantation. The timedependent diffusion profiles were monitored by the use of the Nuclear Resonance Broadening (NRB) technique. The linear Arrhenius plots extracted from the measured diffusivities indicate that the diffusivity of implanted N in Cr and W can be described by the activation energyQ=1.39±0.06 eV and 2.32±0.16 eV and the pre-exponential factorD 0=(7.0±7.2)×10−4cm2/s and 4.3±8.3cm2/s, respectively. The solubilities of N in Cr and W from the implanted distributions were found to deviate from those obtained using conventional metallographical methods.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 34 (1984), S. 49-56 
    ISSN: 1432-0630
    Keywords: 66.30. Jt ; 61.70. Tm
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The diffusion of N in the group VB metals V and Nb has been studied in the previously uninvestigated temperature range 300–500 °C using ion-beam techniques. Diffusion couples were created by ion implantation. The time-dependent diffusion profiles were monitored by the use of the Nuclear Resonance Broadening (NRB) technique. New values for the solubility of N in Nb were obtained. The diffusion rates presented support recent observations of the diffusivity of interstitial impurities in body-centered cubic metals in which positive deviations from Arrhenius behaviour have been seen at high temperatures.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1432-0630
    Keywords: PACS: 61.72.Vv; 61.72.Cc; 66.30.Jt
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract.  Concentration profiles of nitrogen in vacuum-annealed p- and n-type single-crystal (1 0 0) InP implanted with 1×1016 30 keV 15N+ ions cm-2 have been studied by Secondary Ion Mass Spectrometry (SIMS) and Nuclear Resonance Broadening (NRB) techniques. Damage induced by the nitrogen implantation was studied by Rutherford Backscattering Spectrometry (RBS) and channeling. Annealing the samples led to loss and redistribution of nitrogen in the temperature range from 575 to 675 °C. At temperatures from 575 to 600 °C, rapid migration of nitrogen towards the sample surface was observed. The n-type InP material had a very dominant tendency for surface nitrogen build-up, whereas the p-type material had a markedly smaller surface peak in the nitrogen distribution. The surface peak in n-type material is due to sulphur acting partly as a diffusion barrier. SIMS analyses showed sulphur build-up on the surface in the course of annealing. At temperatures from 600 to 675 °C, the nitrogen profiles of n- and p-type InP were similar. A small loss of nitrogen was observed at 625–675 °C. Two different recovery stages were observed at 575–600 °C and at 625–650 °C. The corresponding activation energies for nitrogen loss are 2.9 and 3.0 eV, respectively.
    Type of Medium: Electronic Resource
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