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  • 1
    Electronic Resource
    Electronic Resource
    Full-automatic broad-band wavelength control of a pulsed dye laser (1981)
    Springer
    Applied physics 24 (1981), S. 331-340 
    Details
    ISSN: 1432-0630
    Keywords: 06.60 ; 42.60 ; 42.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A full-automatic wavelength controled pulsed dye laser has been developed. With the control system, dye laser oscillations of nanosecond pulses are tuned to any wavelength in the visible or scanned in any sweep mode keeping the nearly transform-limited bandwidth of 0.45 GHz. A mechanical tuning of the wavelength is employed, such that the motion of three wavelength selectors is synchronized to give a smooth and precise wavelength control. The basic principle underlying the tuning scheme, various requirements to be met in system construction, and the practical performance of automatic wavelength control are described in this paper.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00899731
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  • 2
    Electronic Resource
    Electronic Resource
    High precision wavelength meter with Fabry-Perot optics (1981)
    Springer
    Applied physics 25 (1981), S. 311-316 
    Details
    ISSN: 1432-0630
    Keywords: 07.40 ; 07.60 ; 42.60 ; 42.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A high precision wavelength meter in the visible is described, which is based on a Fabry-Perot interferometer with several etalons of different resolution. The interference fringe pattern projected on a photo-diode array detector is computationally processed to give a stepwise refinement of the wavelength value to any adjusted accuracy. The present model intends to provide digital and real-time values of high precision wavelength for dye-laser spectroscopy, and to serve as a monitor or as a pilot for wavelength control of a dye-laser source of nanosecond pulses. The model is, therefore, designed with particular emphasis on its short-pulse capability and on-line mode of operation as well as on its high sensitivity and resolution. Some arrangements of essential necessity are involved therein, such as to avoid an errorneous wavelength readout for a noisy incidence of pulsed field. The ultimate accuracy of wavelength measurement is prescribed by the resolving power of the thickest etalon employed. As applied to the pulsed source, the model determines the wavelength to the accuracy of ±one part in 107 for even a single shot nanosecond incidence of a fraction of μJ energy. The design and performance are described in connection to pulsed dye-laser incidence.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00902989
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  • 3
    Electronic Resource
    Electronic Resource
    A prism anamorphic system for Gaussian beam expander (1978)
    Springer
    Applied physics 17 (1978), S. 131-136 
    Details
    ISSN: 1432-0630
    Keywords: 42.10 ; 42.60 ; 42.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Basic properties are given of the prism anamorphic expander of a Gaussian beam composed of a couple of prisms in tandem. Its shorter overall length for a given expansion, relative ease of optical adjustment, a sharp selection of polarization component, and rather small inclusive dispersion make it an excellent beam expander in a specific laser cavity. The design principle is presented of the prism system with a grating for an anastigmatic optical resonator for a dye laser of narrow linewidth and of short pulse duration.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00885244
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  • 4
    Electronic Resource
    Electronic Resource
    Positron annihilation in irradiated and unirradiated polyethylenes (1992)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 30 (1992), S. 517-525 
    Details
    ISSN: 0887-6266
    Keywords: positron annihilation in polyethylene, before and after irradiation ; polyethylene, positron annihilation in, effect of radiation on ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Positron lifetimes were measured for four kinds of polyethylene samples and were resolved into four components. The temperature dependence of the two longlived components was examined in detail. In agreement with other results, the longest lived component could be reasonably assigned to ortho-positronium located in amorphous regions. This component was shown to be sensitive to the defects in high-density polyethylene introducted in the course of its production. Both the intensity and the lifetime of the second longest lived component were structure insensitive, i.e., they did not change even on passing through the melting point. This component has been tentatively assigned to a positronium compound state. The effect of gamma-ray irradiation was also examined. Although the intensity (I4) of the longest lived component was reduced by the irradiation, correlation between I4 and the free radical concentration was poor, and the reduction in I4 caused by the irradiation is considered to be due to structure change and not to chemical reasons.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1992.090300601
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  • 5
    Electronic Resource
    Electronic Resource
    Novolac epoxy resins and positron annihilation (1993)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 49 (1993), S. 1921-1929 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Four kinds of epoxy resins: cresol novolac, tris-hydroxyphenylmethane, tetramethylbiphenol, and bisphenol A, were cured with phenol novolac epoxy resins. Characteristics of these epoxy compounds were studied by the positron annihilation lifetime (PAL) technique. Glass transition temperatures, thermal expansion coefficients, and volume of intermolecularspace holes among polymer chains were obtained from the lifetime, τ3, of the long-lived component of ortho-positronium. It was revealed that, at the glass transition temperature, Tg, the volume of the hole created among polymer chains expanded 1.4 times the volume at room temperature. The smaller flexural modulus of tris-hydroxyphenylmethane than that of the other samples was explained by the volume of intermolecular-space holes obtained from τ3. Aging effects were seen in the data of the intensities, I3, of ortho-positronium, which became smaller after heating the samples above Tg. I3 and τ3 were strongly affected by the density of cross-linkings, and their chemical structures. The larger the density of cross-linkings, the smaller I3 and higher Tg were obtained. Epoxy compounds with the higher water-absorption rates had larger intermolecular-space holes. © 1993 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1993.070491107
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  • 6
    Electronic Resource
    Electronic Resource
    Oxygen dissolution and transport in cobaltporphyrin-bound organophosphazene membranes (1993)
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 4 (1993), S. 17-20 
    Details
    ISSN: 1042-7147
    Keywords: Poly(organophosphazene) ; Cobaltporphyrin ; Facilitated transport ; Oxygen-separating membrane ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Rubbery poly(organophosphazene)s were synthesized, and were combined with cobaltporphyrin (CoP) which binds molecular oxygen rapidly and reversibly. The apparent oxygen-binding equilibrium constant (Kapp) is in proportion to the physical solubility coefficient of oxygen in the polymer, although the reduced equilibrium and thermodynamic parameters are not dependent on the polymer matrix species. Diffusivity of oxygen via the fixed CoP(DC) is enhanced for poly(organophosphazene) membranes with a larger oxygen diffusion constant. Poly(organophosphazene) membranes with both a large Kapp and DC yield high oxygen permeability.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pat.1993.220040104
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  • 7
    Electronic Resource
    Electronic Resource
    Synthesis of copolyamide-esters and some aspects involved in their hydrolysis by lipase (1979)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 24 (1979), S. 1701-1711 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Copolyamide-esters (CPAEs) were synthesized by the amide-ester interchange reaction. The change of intrinsic viscosity during CPAE synthesis was negligible. Polyamide blocks were shortened with increasing reaction time and polyester content. The polymerization degree of nylon 12 blocks on CPAE was smaller than that of nylon 6 blocks. CPAEs were hydrolyzed by Rhizopus delemar lipase. The biodegradability decreased with the shortening of the polyamide blocks and with increasing polyamide content. It was concluded that the amount and distribution of the hydrogen bonds, based on the amide group, in the CPAE chains strongly influenced their biodegradation by this lipase.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1979.070240710
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  • 8
    Electronic Resource
    Electronic Resource
    Sputtering of metals with 20 keV O2+: Characteristic etch patterns and sputtered atom yields (1980)
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 2 (1980), S. 212-216 
    Details
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The surface structures of polycrystalline pure metals bombarded with 20 ke V O+2 were observed by a SEM and their sputtered atom yields obtained by measuring the depth of crater with an interferoscope. The etch patterns produced were classified according to the binding energy of mono-oxide BMO of the target atom M and an oxygen atom; the surface become smooth as the binding energy increased. The sputtered atom yield showed similar periodicity to those obtained by noble gas ion bombardment. It was therefore concluded that the sputtered atom yield was primarily determined by physical collision of atoms in the target material and was not affected very much by the chemical reaction of implanted oxygen atoms.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/sia.740020605
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  • 9
    Electronic Resource
    Electronic Resource
    Evaluation of correction accuracy of several schemes for AES matrix effect correctionsPaper presented at ECASIA 89, Antibes, France, 23-27 October 1989. (1990)
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 15 (1990), S. 466-472 
    Details
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A matrix effect correction is required to improve the accuracy of quantitative AES analysis. The correction includes terms involving the atomic density (n), electron back-scattering factor (R) and electron escape depth (L). Many schemes have been proposed by various people for corrections of the R and L terms. However, up to now, there have been no systematic investigations of the correction accuracy of the proposed schemes. We have evaluated the correction accuracy, based on measured intensity data for Au—Cu alloys of different compositions. Comparison was made between the observed intensity ratio K (=Iunk/Istd) and the calculated intensity, ratio K′ (= C(nunk/nstd)(Runk/Rstd)(Lunk/Lstd)), where C and I represent the concentration and intensity, respectively. The superscripts ‘unk’ and ‘std’ denote that the parameters are for unknown and standard specimens, here the pure elements. If the correction works well, the error Er (= K′ — K)/(K) will become smaller. Evaluations were carried out on three schemes for the R correction and on seven schemes for the L correction using the Au 239 eV, Au 2024 eV and Cu 920 eV transitions. The root mean square (RMS) of the calculated errors showed several per cent for the best case and 20-30% for the worst case. The RMS error varied a few per cent between schemes for the R correction but it varied ∼30% for the L correction.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/sia.740150805
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  • 10
    Electronic Resource
    Electronic Resource
    The reliability of quantitative analysis with AES (1990)
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 16 (1990), S. 140-143 
    Details
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The Japanese VAMAS-SCA working group is composed of 19 institutes. Three kind of Au—Cu alloys (Au 75 at.-%-Cu 25 at.-%, Au 50 at.-%-Cu 50 at.-%, Au 25 at.-%-Cu 75 at.-%) were prepared, and these specimens, pure Au and pure Cu were distributed to the members of the VAMAS-SCA working group. The surface concentrations of these alloys were calculated from the Auger peak amplitudes in two ways. One method used the published relative sensitivity factors, and the other used pure Au and Pure Cu as the standard materials. The mean values of the surface concentrations calculated with the published relative sensitivity factors were almost the same as those calculated with the standard materials. This means that the published relative sensitivity factors are reliable to some extent. The error of the surface concentration calculated with pure Au and pure Cu as the standard materials lay between about 3% and 10%, and that with the relative sensitivity factors lay between about 7% and 20%. The calculated surface concentrations of Au were larger than the bulk concentrations of Au when the matrix effect was neglected.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/sia.740160127
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