Bibliothek

feed icon rss

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solid state electrochemistry 1 (1997), S. 215-220 
    ISSN: 1433-0768
    Schlagwort(e): Key words Prussian blue ; Ammonium ; Voltammetry ; Flow-through ; Kjeldahl
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A new method is described for the determination of ammonium in aqueous solutions with electrodes modified by Prussian blue (PB). The specific voltammetric response of PB-modified electrodes to ammonium ions is used for their analytical determination. In the presence of ammonium ions, a concentration-dependent inhibition of the low-spin iron(II/III) system of PB occurs. Only thallium and rubidium ions cause similar inhibition. A useful electrochemical determination method is thus available for detecting ammonium ions in the presence of frequently interfering potassium and sodium ions. Paraffin-impregnated graphite electrodes modified with a mechanically transferred PB layer and bulk-modified PB-composite electrodes are studied. The method is applicable within a concentration range which extends from 4 × 10−5 mol/l to 10−2 mol/l NH4 +. The composite electrode is used in an electrochemical flow-through system in conjunction with the Kjeldahl method.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    ISSN: 1432-0878
    Schlagwort(e): Nucleation ; Crystal formation ; Organic matrix ; Active centres of nucleation ; Dentine
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Beschreibung / Inhaltsverzeichnis: Zusammenfassung Von neu gebildetem, gefriergetrocknetem Dentin in Rattenschneidezähnen und von alkohol- und formol-fixiertem, reifem menschlichen Dentin wurden Ultradünnschnitte bei Vergrößerungen 20 000∶1 und 40 000∶1 in Fokusreihen aufgenommen.Die gut fokussierten Aufnahmen des Ratten-Dentins wurden auf nichtschrumpfendem Photopapier und Diafilm-Material 20 0000∶1 nachvergrößert. Mit einem Meßmikroskop wurden 507 Abstände zwischen den punktförmigen Keimen in den Ca-Phosphat-Nadeln und -Ketten sowie 536 Seitenabstände zwischen dicht zusammenliegenden, parallel verlaufenden Nadeln und Ketten bestimmt. Außerdem konnten in beiden Dentin-Arten die am häufigsten auftretenden Abstände beider Abstandsarten durch Anwendung der Laserbeugung auf die bei 20 000∶1 aufgenommenen Filme erhalten werden. Die morphologisch bestimmten Punktkeimabstände und die Seitenabstände lagen vor allem im Bereich von 37–63 Å, die durch Laserbeugung erhaltenen Werte für das neugebildete Dentin im Bereich von 30–52 Å, während sie beim reifen menschlichen Dentin noch bis zu Werten um 65 Å reichten. Wie bei Höhling u. Mitarb. (1970) wurden die Punktkeimabstände als Abstände zwischen den akiven, keiminduzierenden Zentren auf einer kettenartigen Matrix diskutiert. Aus der Morphologie der Keime wurde ferner geschlossen, daß sich hier die blättchenförmigen Kristallite im allgemeinen durch Zusammenwachsen von Nadeln bilden, wenn diese dicht und parallel zusammenliegen.
    Notizen: Summary The growing ends of rat incisors were freeze-dried and embedded in methacrylate without contact with any other solution. Dentine from alcohol and formalin fixed human teeth was also embedded in methacrylate. Ultrathin sections were prepared and electron micrographs taken at original magnifications of X20 000 and X40 000. The best focussed pictures from through focus series were selected for photographic enlargement to a total of X200 000. 507 measurements of the distance between dot-like nuclei in the calcium phosphate needles and chains and 536 measurements of the distance between the neighbouring parallel chains and needles were made using a measuring microscope. In addition, the most commonly occurring separation distances between the dot-like nuclei — within individual rows or between neighbouring rows—were measured by laser diffraction of the x20 000 EM negatives. The most commonly occurring range for the distance between the dot-like nuclei and the lateral distance between the rows as determined morphologically was 3.7–6.3 nm. The corresponding value as determined by laser diffraction for the recently formed rat incisor dentine lay in the region 3.0–5.2 nm, whereas the same value reached to 6.5 nm in the case of mature human dentine. The distances between the dot-like nuclei are regarded as representing the distances between active nucleus-inducing centres on a chain-like matrix. From a study of the morphology of the nuclei it is concluded that the plate-like crystallites usually arise through fusion of needle-like rows of dot-like nuclei when these lie close and parallel to one another.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solid state electrochemistry 4 (1999), S. 17-23 
    ISSN: 1433-0768
    Schlagwort(e): Key words Lithium nickelate ; Solid state electrochemisty ; Proton intercalation ; Voltammetry ; Immobilized microparticles
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Lithium nickelate was synthesized by self-propagating high-temperature combustion. The electrochemical behaviour of the product was studied by cyclic voltammetry of microparticles immobilized on the surface of graphite electrodes. Whereas numerous previous studies have dealt with non-aqueous electrolyte solutions, here the behaviour of lithium nickelate in contact with aqueous electrolyte solutions was investigated. It could be shown that protons are intercalating upon reduction of the Ni(III) to Ni(II) and deintercalating upon oxidation. This insertion electrochemistry is chemically reversible. Within 1600 oxidation-reduction cycles, the response diminished only by about 10%. Scanning electron microscopy reveals a considerable recrystallization during the electrochemical cycles. Energy dispersive X-ray detection proved that no metal cations are intercalating. The electrochemical system is accessible only in very alkaline solutions as it shifts to more positive values with decreasing pH.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solid state electrochemistry 1 (1997), S. 62-67 
    ISSN: 1433-0768
    Schlagwort(e): Key wordsSpectroelectrochemistry ; Diffuse reflectance spectrometry ; Solid state electrochemistry ; Voltammetry ; Microscopy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract An instrumental setup is described which allows electrochemical measurements to be performed with solid particles immobilized on the surface of a graphite electrode with in situ recording of diffuse reflectance spectra under an incident light microscope. The instrument used includes a special electrochemical cell and a microscope which is interfaced by a light␣guide to a transputer-integrated photodiode-array spectrometer allowing measurements ranging from 320 to 950 nm with a resolution of 3.2 nm/pixel and a PC-interfaced potentiostat. The 0R0 geometry of the optical arrangement and the use of crossed polarization filters for blocking specular reflectance makes it possible to use the Kubelka-Munk function for quantifying the optical measurements. The above instrument has been used for the study of the electrochromic system of solid silver octacyanomolybdate(IV/V) adjacent to a silver nitrate solution. The in situ diffuse reflec tance spectroelectrochemical measurements prove that the electrochemical reaction starts at the graphite/sample interface and then advances into the bulk of the sample towards the sample/electrolyte interface. The ratios Red:Ox determined by spectrometry and chronocoulometry as a function of electrode potentials are identical.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...