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  • compressible flow  (3)
  • Polymer and Materials Science  (2)
  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 2783-2790 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The vinyl acetate centered triad fractions of some free radically prepared ethylene-vinyl acetate and styrene-vinyl acetate copolymers have been determined from the patterns of vinyl acetate methine carbon peaks in their 13C nuclear magnetic resonance (NMR) spectra. The positions and shapes of the carbonyl bands in the infrared (IR) absorption spectra of the copolymers recorded in chloroform are shown to depend on the compositions of the copolymers and on the proportions of the various vinyl acetate centered triads. Infrared absorption measurements may thus be used in part to characterize the monomer sequence distributions of these copolymers.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 20 (1995), S. 887-913 
    ISSN: 0271-2091
    Keywords: compressible flow ; CFD (computational fluid dynamics) ; finite elements in fluids ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The algorithm introduced in Part I of this paper is applied in its explicit form to a variety of problems in order to demonstrate its wide range of applicability and excellent performance. Examples range from nearly incompressible, viscous, flows through transonic applications to high speed flows with shocks. In most examples linear triangular elements are used in the finite element approximation, but some use of quadratic approximation, again in triangles, indicates satisfactory performance even in the case of severe shocks.
    Additional Material: 23 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 28 (1998), S. 1325-1353 
    ISSN: 0271-2091
    Keywords: finite elements ; compressible flow ; artificial viscosity ; Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The performance of different shock capturing viscosities has been examined using our general fluid mechanics algorithm. Four different schemes have been tested, both for viscous and inviscid compressible flow problems. Results show that the methods based on the second gradient of pressure give better performance in all situations. For instance, the method constructed from the nodal pressure values and consistent and lumped mass matrices is an excellent choice for inviscid problems. The method based on L2 projection is better than any other method in viscous flow computations. The residual based anisotropic method gives excellent performance in the supersonic range and gives better results in the hypersonic regime if a small amount of residual smoothing is used. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 23 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 27 (1998), S. 41-55 
    ISSN: 0271-2091
    Keywords: unstructured mesh ; compressible flow ; transient flow ; mesh adaptation ; moving boundaries ; Delaunay triangulation ; Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The solution of high-speed transient inviscid compressible flow problems in three dimensions is considered. Discretization of the spatial domain is accomplished by the use of tetrahedral elements generated by Delaunay triangulation with automatic point creation. Methods of adapting the mesh to allow for boundary movement are considered and a strategy for ensuring boundary recovery is proposed. An explicit multistage time-stepping algorithm is employed to advance the flow solution. A number of examples are included to illustrate the numerical performance of the proposed procedures. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 13 (1974), S. 2103-2115 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A theoretical study of effects of excluded volume intermolecular interactions on the sharpness of helix-coil transitions in solutions of polyamino acids or simple proteins indicates that the transition width may vary appreciably as a function of polymer concentration. The analysis is based on a second virial approximation for the excess free energy of mixing of a solution of polymers of varying degrees of helicity. The virial coefficients involved are roughly estimated on the basis of gross polymer geometry. For large N (degree of polymerization) the transition is found, typically to sharpen with increasing concentration, becoming second order and then first order at sufficiently high concentrations. The critical polymer concentration is found to be roughly of the order N-1.2 d0-1 for an “all or none” model and of order σ1/2 N-0.2 d0-1 for a model with continuously variable degree of helicity (d0 is the volume of a single helical molecule and σ1/2 the normalized statistical weight of a helix-coil interface). In the second case for N ∼ 103 and σ ∼ 10-2-10-4, the predicted critical concentration is in the range 10-1-10-3 g/cm.3 Comparison is made with experiments on solutions of poly(γ-benzyl-L glutamate).
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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