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  • 1
    Electronic Resource
    Electronic Resource
    Functional polymers. XIVPart XIII: S. Yoshida and O. Vogl, J. Polym. Sci. Polym. Chem. Ed., to appear.. Grafting of 2(2-hydroxy-5-vinylphenyl)2H-benzotriazole onto polymers with aliphatic groups (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 19 (1981), S. 3307-3314 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Successful grafting of 2(2-hydroxy-5-vinylphenyl)2H-benzotriazole onto saturated aliphatic C—H groups of polymers has been accomplished. When the grafting reaction was carried out in chlorobenzene at 150-160°C with di-tertiary butylperoxide as the grafting initiator, grafts as high as 20-30% at grafting efficiencies of 50 and 80% have readily been obtained. It was very important to carry out the grafting reaction in tubes sealed under high vacuum since trace amounts of oxygen cause complete inhibition of the grafting reaction by the phenolic monomer. Grafting reactions were carried out on a variety of different polymers including atactic polypropylene, ethylene/vinyl acetate copolymer, poly(methyl methacrylate), poly(butyl acrylate), and polycarbonate.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.170191223
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  • 2
    Electronic Resource
    Electronic Resource
    Esters of alternating copolymers of maleic or 2,3-dimethylmaleic anhydride with alkyl vinyl ethersThis paper is dedicated to Professor Junji Furukawa on the occasion of his seventieth birthday, with warmest personal wishes. (1983)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 21 (1983), S. 891-911 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Maleic anhydride or 2,3-dimethylmaleic anhydride was copolymerized with a number of alkyl vinyl ethers, with AIBN as the initiator. The comonomers were always alternating and were obtained in yields ranging from 15 to 99%. The acid anhydride group in both series of copolymers was converted to the corresponding methyl esters in a two-step reaction. The structure of these polymers was established by elemental analysis and by infrared, 1H-and 13C-NMR spectroscopy. Addtional characterization of these copolymers were carried out by viscosity measurements, differential scanning calorimetry for the determination of glass transition temperatures, and thermal degradation for the determination of the thermal stability of the copolymers.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1983.170210323
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  • 3
    Electronic Resource
    Electronic Resource
    Terpolymerization of acrylonitrile, styrene, and 2,3-dibromopropyl acrylate (1983)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 21 (1983), S. 1913-1928 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The terpolymerization of acrylonitrile with styrene and 2,3-dibromopropyl acrylate in emulsion and dimethyl formamide solution was investigated. Polymerizations, when stopped at low conversions, yielded terpolymers that showed good agreement between experimental and theoretical copolymerization composition data, calculated from the Alfrey-Goldfinger equation. The relationship between monomer feed and terpolymer compositions is displayed on triangular coordinate graphs proposed by Slocombe. By using a computer program the lines of unique composition and binary azeotropic composition for both systems were established. In the case of emulsion polymerization the azeotropic ternary point was determined at a molar ratio for acrylonitrile/styrene/2,3-dibromopropyl acrylate of 0.27/0.61/0.12. The experimental results of emulsion terpolymerization fit the calculated curves satisfactorily over a wide range of monomer compositions up to high conversions. The influence of 2,3-dibromopropyl acrylate on the thermal and flammability characteristics of the terpolymers is described.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1983.170210704
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  • 4
    Electronic Resource
    Electronic Resource
    Terpolymerization of acrylonitrile, styrene, and 2,4,6-tribromophenyl acrylate (1983)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 21 (1983), S. 2713-2725 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Acrylonitrile was terpolymerized with styrene and 2,4,6-tribromophenyl acrylate in aqueous emulsion and dimethylformamide solution. Experimental terpolymerization data agreed well with calculations based on the Alfrey-Goldfinger equation. Triangular coordinate graphs show the feed/terpolymer relationships; the lines of unique and binary azeotropic compositions were identified. No points of true azeotropic composition were found but a “pseudo-azeotropic” region was recognized. The experimental data of the emulsion terpolymerization experiment agreed well with the theoretical curves over a wide range of monomer compositions up to high conversions. Incorporation of 2,4,6-tribromophenyl acrylate in the terpolymer decreased the thermal stability but improved the flame retardancy of the terpolymers.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1983.170210909
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  • 5
    Electronic Resource
    Electronic Resource
    Poly(alkylene oxide) ionomers. XI. Polymerization and copolymerization of methyl ω-epoxyundecanoate and characterization of the polymersPart X: J. Muggee and O. Vogl, J. Polym. Sci. Polym. Chem. Ed., 23, 651 (1985). (1985)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 23 (1985), S. 673-701 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Methyl 10-undecenoate was epoxidized in nearly quantitative yield with m-chloroperoxy-benzoic acid to methyl 10,11-epoxyundecanoate. The functional epoxide monomer was polymerized by the reaction product of triethylaluminum/water/acetylacetone (1.0/0.5/1.0) to a high molecular weight elastomer having pendent carboxyl groups, and a molecular weight distribution near the most probable distribution. With the same initiator system, methyl 10,11-epoxyundecanoate was copolymerized with ethylene oxide, propylene oxide, 1-butene oxide, 1-hexene oxide, phenyl glycidyl ether, epichlorohydrin, and 4,4,4-trichloro-1-butene oxide. The copolymers were typically high in molecular weight, elastomeric, and had methyl 10,11-epoxyundecanoate incorporations similar to the initial feed ratio of comonomers. The new family of functional polymers were characterized by their infrared and NMR spectra, dilute solution viscosity and thermal transitions.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1985.170230307
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  • 6
    Electronic Resource
    Electronic Resource
    Functional polymers. XVI.For Part XIV see ref. 1. Synthesis and polymerization of 2(2-hydroxy-5-isopropenylphenyl)-2H-benzotriazole and a new synthesis of 2(2-hydroxy-5-vinylphenyl)2H-benzotriazole (1982)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 20 (1982), S. 2735-2754 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2(2-Hydroxy-5-isopropenylphenyl)2H-benzotriazole was synthesized in 40% overall yield starting from o-nitroaniline. Diazotization in aqueous hydrochloric acid gave o-nitrophenyl diazonium chloride which was condensed with p-hydroxyacetophenone; the azo compound was reduced to 2(2-hydroxy-5-acetylphenyl) 2H-benzotriazole with zinc powder in sodium hydroxide solution and the 2-hydroxy group of the compound was acetylated. Treatment of the acetyl compound with methyl Grignard reagent resulted in the methylation of the 5-acetyl group to 2[2-acetoxy-5(2-hydroxy-2-propyl)phenyl]2H-benzotriazole which was then dehydrated with potassium hydrogen sulfate to the desired 2(2-hydroxy-5-isopropenylphenyl)2H-benzotriazole. This monomer did not homopolymerize, but was copolymerized readily with styrene, methyl methacrylate, and n-butyl acrylate with azobisisobutyronitrile as the initiator. 2(2-Acetoxy-5-acetylphenyl)2H-benzotriazole was also reduced with sodium borohydride to form 2[2-acetoxy-5-(1-hydroxyethyl)phenyl]2H-benzotriazole which was dehydrated and hydrolyzed to the known 2(2-hydroxy-5-vinylphenyl)-2H-benzotriazole. This route provides a novel and simpler synthesis of 2(2-hydroxy-5-vinylphenyl)2H-benzotriazole.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1982.170201001
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  • 7
    Electronic Resource
    Electronic Resource
    Poly(alkylene oxide) ionomers. XIII.Part XII: D. A. Bansleben and O. Vogl, J. Polymer Science, Polymer Chem. Ed., in press. Copolymers of trioxane with the epoxide and 1,3-dioxolane of methyl 10-undecenoate (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 3263-3288 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cationic copolymerization of 1,3,5-trioxane with methyl 10,11-epoxyundecanoate or methyl 7,8-epoxyoctanoate and terpolymerization with 1,3-dioxolane was successfully carried out. Co-and terpolymerization of 1,3,5-trioxane with 4-(1-carbomethoxynonyl)-1,3-dioxolane was also achieved. Feed compositions of the functional comonomers were varied from 5 to 40 mol %; in all cases the isolated copolymers contained less than 5% of the functional mer units. The composition of the copolymers showed that the methyl ω-epoxyalkanoates were much less reactive than 1,3,5-trioxane. A similar trend was observed with the functional dioxolane monomer, although significantly shorter induction periods were observed in comparison with the epoxy/trioxane copolymerizations. The oxymethylene copolymers and terpolymers were characterized primarily by their infrared spectra; however, the thermal and base stabilities of selected copolymers were also determined.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1984.170221143
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  • 8
    Electronic Resource
    Electronic Resource
    Functional polymers. XIXPart XVIII: M. Kitayama and O. Vogl, Polym. J. Jpn., in press.. Biuret oligomers and polymers of biologically active primary aliphatic amines (1982)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 20 (1982), S. 2477-2499 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Biuret oligomers and polymers from primary aliphatic amines and aromatic or aliphatic diisocyanates have been synthesized. To demonstrate the feasibility of the synthesis of polybiurets, aliphatic primary amines with n-propyl, n-hexyl, n-octyl, and n-dodecyl groups have been incorporated. For the synthesis of biuret oligomers of biologically active primary aliphatic amines [8-(4-amino-1-methylbutylamino)-6-methoxyquinoline] (primaquine) and adamantanamine were selected. Primaquine was also incorporated into polyepichlorohydrin by nucleophilic substitution of the chlorine of the chloromethyl group by the primary aliphatic amino group of primaquine. The structure of the biuret polymers was established by elemental analysis, and by infrared 1H- and 13C-NMR spectroscopic characterization. Several attempts to use primaquine as a diamine for the formation of condensation polymers, including reaction of primaquine with sebacoyl chloride (to form polyamides), or with diisocyanates (to form polyureas) were unsuccessful.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1982.170200910
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  • 9
    Electronic Resource
    Electronic Resource
    Head-to-head polymers. XXIV.Part XXIII: F. Xi and O. Vogl, J. Macromol. Sci. Chem., in press. Synthesis of head-to-head polyisobutylene by Grignard coupling reaction (1983)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 21 (1983), S. 2629-2648 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Head-to-head polyisobutylene of molecular weight 3000 to 10,000 was prepared in about 30% yield by Grignard coupling polymerization of 2,2,3,3-tetramethyl-1,4-dibromobutane with copper(I) tris(triphenylphosphino)bromide as the catalyst. Head-to-head polyisobutylene is crystalline, with a Tm of 187°C and a Tg of 87°C and still has bromine end groups left. The polymers have been characterized by their infrared, 1H-, and 13C-NMR spectra and compared to the corresponding head-to-tail polymers of similar molecular weight. A substantial portion of the reaction product of the Grignard coupling polymerization is not polymeric but was identified as cyclized product, 1,1,2,2-tetramethylcyclobutane.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1983.170210903
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  • 10
    Electronic Resource
    Electronic Resource
    Poly(alkylene oxide) ionomers. VII.Part VI: O. Vogl, P. Loeffler, D. Bansleben, and J. Muggee, in Coordination Polymerization, C. C. Price and E. J. Vandenberg, Eds., Polymer Science and Technology, Vol. 19, 1983, p. 95. Use of triethylaluminum/water/acetylacetone (1.0:0.5:1.0) for the polymerization of oxiranes (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2489-2500 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polymerization studies of oxiranes were conducted using a modified aluminumalkyl initiator, derived from the low-temperature reaction by chelating agents (5°C) and hydrolysis products of triethylaluminum. The stoichiometric reaction product of acetylacetone and triethylaluminum, after partial hydrolysis with water, gave a homogeneous initiator that polymerized the oxides of ethylene, propylene, 1-butene, 1-hexene, 3-chloro-1-propene, and 4,4,4-trichloro-1-butene to the corresponding high molecular weight poly(alkylene oxides). The initiator, similar in nominal composition to the classical trialkylaluminum/water/acetylacetone (1.0/0.5/1.0) initiator developed by Vandenberg, retained a high level of activity, when properly stored, for nearly 4 weeks. The composition was inactive when the sequence of chelation and hydrolysis was reversed. Inclusion of a proton-trapping agent in polymerization experiments of propylene oxide provided evidence that protons do not play a role in the initiation of oxirane polymerizations with modified organoaluminum oxides. Characterization of the various alkylene oxide polymers was carried out by spectroscopic, solution, and thermal techniques.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1984.170221017
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