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  • 2000-2004  (3)
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  • 1
    Digitale Medien
    Digitale Medien
    Photodetachment spectroscopy of the C2nH− (n=2–4) anions in the vicinity of their electron detachment threshold (2002)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 116 (2002), S. 6126-6131 
    Details
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The electronic spectra of the C2nH(D)−, n=2–4, anions have been observed in the gas phase using photodetachment spectroscopy. These are assigned to 1Π←X 1Σ+ electronic transitions. The 1Π excited states possess a dipole bound character indicated by the energetic proximity between the origin of the transitions and electron affinities. The dipole bound states are related to the X 2Π ground states of C6H and C8H whereas for C4H, which has an X 2Σ+ ground state, the 2Π is an excited state. Vibronic coupling through a bending motion of the carbon skeleton is inferred to be the reason of the stabilization of this state. © 2002 American Institute of Physics.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1063/1.1451248
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  • 2
    Digitale Medien
    Digitale Medien
    Gas phase electronic spectrum of C3H in the visible (2001)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 115 (2001), S. 6913-6919 
    Details
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The electronic spectrum of C3H has been observed by means of a resonant two color two photon ionization technique sampling a supersonic plasma source. On the basis of ab initio calculations, vibrational and rotational analysis, the complex vibronic system observed in the visible and near UV is assigned to three electronic transitions, A˜ 2A′←X 2Π, B˜ 2A″←X 2Π and C˜ 2A″←X 2Π of C3H. Potential curves along the CCH bending coordinate have been obtained because of its role for the electronic spectrum and dynamics of C3H. © 2001 American Institute of Physics.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1063/1.1404391
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  • 3
    Digitale Medien
    Digitale Medien
    Rotationally resolved A2Πu←X 2Πg electronic transition of NC6N+ (2002)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 116 (2002), S. 924-927 
    Details
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The rotationally resolved A2Πu←X2Πg electronic origin band spectrum of dicyanodiacetylene cation, NC6N+, has been recorded in the gas phase using frequency-production double modulation spectroscopy in a liquid nitrogen cooled hollow cathode discharge and cavity ring down spectroscopy in a supersonic plasma. The analysis of the complementary results provides accurate molecular parameters for the two spin-orbit components in both electronic states. © 2002 American Institute of Physics.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1063/1.1427710
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