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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Mathematical geology 31 (1999), S. 85-103 
    ISSN: 1573-8868
    Schlagwort(e): dispersion covariances ; Pearson correlation ; multivariate geostatistics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Mathematik
    Notizen: Abstract This paper extends the concept of dispersion variance to the multivariate case where the change of support affects dispersion covariances and the matrix of correlation between attributes. This leads to a concept of correlation between attributes as a function of sample supports and size of the physical domain. Decomposition of dispersion covariances into the spatial scales of variability provides a tool for computing the contribution to variability from different spatial components. Coregionalized dispersion covariances and elementary dispersion variances are defined for each multivariate spatial scale of variability. This allows the computation of dispersion covariances and correlation between attributes without integrating the cross-variograms. A correlation matrix, for a second-order stationary field with point support and infinite domain, converges toward constant correlation coefficients. The regionalized correlation coefficients for each spatial scale of variability, and the cases where the intrinsic correlation hypothesis holds are found independent of support and size of domain. This approach opens possibilities for multivariate geostatistics with data taken at different support. Two numerical examples from soil textural data demonstrate the change of correlation matrix with the size of the domain. In general, correlation between attributes is extended from the classic Pearson correlation coefficient based on independent samples to a most general approach for dependent samples taken with different support in a limited domain.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Mathematical geology 31 (1999), S. 701-722 
    ISSN: 1573-8868
    Schlagwort(e): dispersion covariances ; spatial support ; Pearson correlation ; spatial scales of variability ; PCA ; matrix variogram
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Mathematik
    Notizen: Abstract Principal component analysis (PCA) is commonly applied without looking at the “spatial support” (size and shape, of the samples and the field), and the cross-covariance structure of the explored attributes. This paper shows that PCA can depend on such spatial features. If the spatial random functions for attributes correspond to largely dissimilar variograms and cross-variograms, the scale effect will increase as well. On the other hand, under conditions of proportional shape of the variograms and cross-variograms (i.e., intrinsic coregionalization), no scale effect may occur. The theoretical analysis leads to eigenvalue and eigenvector functions of the size of the domain and sample supports. We termed this analysis “growing scale PCA,” where spatial (or time) scale refers to the size and shape of the domain and samples. An example of silt, sand, and clay attributes for a second-order stationary vector random function shows the correlation matrix asymptotically approaches constants at two or three times the largest range of the spherical variogram used in the nested model. This is contrary to the common belief that the correlation structure between attributes become constant at the range value. Results of growing scale PCA illustrate the rotation of the orthogonal space of the eigenvectors as the size of the domain grows. PCA results are strongly controlled by the multivariate matrix variogram model. This approach is useful for exploratory data analysis of spatially autocorrelated vector random functions.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Journal of Chemometrics 5 (1991), S. 455-465 
    ISSN: 0886-9383
    Schlagwort(e): Correspondence analysis ; Cluster analysis ; Optimization ; Eigenanalysis ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Carey et al. utilized principal components analysis (PCA) to analyze frequency shift data obtained from piezoelectric sensors formed by coating quartz crystals with 27 different GC stationary phases and tested using 14 analytes. The objective of the analysis was to determine an optimal reduced set of coatings for detection of the analytes. The results were correlated with those obtained from cluster analysis. In this paper the data are re-analyzed using correspondence analysis (CA). The advantage of using CA include a symmetric treatment of sensor coatings and analytes and better identification of the representation of the analytes in terms of the detection components. The results obtained by the conjunctive use of PCA, a varimax rotation and cluster analysis were obtained by CA.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 40 (1990), S. 595-611 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Corona discharge (CD) treated polyethylene films were examined using X-ray photoelectron spectroscopy (XPS) and a variety of chemical derivatization techniques. The composition of the CD-treated surfaces were found to be relatively unaffected by aging at temperatures between 70 and 80°F. Ink adhesion testing of films treated under progressively more serve conditions indicated the efficiency of adhesion varied directly with the severity of treatment. Derivatization of CDtreated polyethylene films with pentaflurophenylhydrazine (PFPH) resulted in the formation of a stable hydrazone complex. The PFPH complex extends the detection limit for enolizable carbonyl groups ca. eight-fold and provides relative quantitation of the number of these groups on variously treated polyethylenes. Formation of the hydrazone complex destroyed ink adhesion, indicating that the complex had blocked the site responsible for chemical bonding to the ink. Adhesion of water-soluble printing inks to CD-treated polyethylene is a direct consequence of hydrogen bonding between enolic hydroxyls on the polymer surface and carbonyl groups of the ink.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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