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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 84 (1998), S. 428-432 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Three different paramagnetic [RhCl6]4− complexes were detected in x-ray irradiated solution-grown NaCl single crystals: RhCl64−⋅nVac, n=2, 1, 0. These complexes all have a 4d7 ground state, with the unpaired electron spin mainly in a 4dz2 orbital and differ only by the presence of two, one, or none next-nearest cation vacancy (Vac). The RhCl64−⋅2Vac is formed at 77 K and partially converts into RhCl64−⋅1Vac at about 190 K. At room temperature the RhCl64−⋅0Vac is dominant, but traces of the RhCl64−⋅1Vac and RhCl64−⋅2Vac centers remain. A thermally induced reorientation motion of the 4dz2 molecular orbital is used to explain the temperature dependence of the RhCl64−⋅1Vac electron spin resonance spectrum. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 98 (1994), S. 354-363 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Alimentary pharmacology & therapeutics 8 (1994), S. 0 
    ISSN: 1365-2036
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: Background: Coffee and tea are believed to cause gastrooesophageal reflux : however, the effects of these beverages and of their major component, caffeine, have not been quantified. The aim of this study was to evaluate gastro-oesophageal reflux induced by coffee and tea before and after a decaffeination process, and to compare it with water and water-containing caffeine. Methods: Three-hour ambulatory pH-metry was performed on 16 healthy volunteers, who received 300 ml of (i) regular coffee, decaffeinated coffee or tap water (n = 16), (ii) normal tea, decaffeinated tea, tap water, or coffee adapted to normal tea in caffeine concentration (n= 6), and (iii) caffeine-free and caffeine-containing water (n= 8) together with a standardized breakfast. Results: Regular coffee induced a significant (P 〈 0.05) gastro-oesophageal reflux compared with tap water and normal tea, which were not different from each other. Decaffeination of coffee significantly (P 〈 0.05) diminished gastro-oesophageal reflux, whereas decaffeination of tea or addition of caffeine to water had no effect. Coffee adapted to normal tea in caffeine concentration significantly (P 〈 0.05) increased gastro-oesophageal reflux. Conclusions: Coffee, in contrast to tea, increases gastrooesophageal reflux, an effect that is less pronounced after decaffeination. Caffeine does not seem to be responsible for gastro-oesophageal reflux which must be attributed to other components of coffee.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford UK : Blackwell Science Ltd.
    Alimentary pharmacology & therapeutics 11 (1997), S. 0 
    ISSN: 1365-2036
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: Patients with reflux disease often complain of heartburn after ingestion of coffee. Induction of gastro-oesophageal reflux has been demonstrated by pH-metry following the intake of coffee in healthy volunteers. The reflux was reduced when the coffee had undergone a decaffeination process. The aim of this study was to investigate the effect of decaffeination of coffee on reflux in patients with reflux disease.〈section xml:id="abs1-2"〉〈title type="main"〉Methods:Seventeen reflux patients underwent two oesophageal 3-h pH measurements. The patients received, in a double-blind study design in a randomized order, 300 mL of either regular or decaffeinated coffee together with a standardized breakfast. The fraction time oesophageal pH 〈 4 was calculated during the three postprandial hours.〈section xml:id="abs1-3"〉〈title type="main"〉Results:For regular coffee the fraction time was calculated to a median of 17.9% with a range of 0.7–56.6%. The fraction time was significantly reduced to 3.1% (0–49.9%) after ingestion of decaffeinated coffee.〈section xml:id="abs1-4"〉〈title type="main"〉Conclusion:The amount of gastro-oesophageal reflux induced by the intake of regular coffee in patients with reflux disease can be reduced by the decaffeination of coffee.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular medicine 68 (1990), S. 926-926 
    ISSN: 1432-1440
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular medicine 69 (1991), S. 866-866 
    ISSN: 1432-1440
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular medicine 66 (1988), S. 322-322 
    ISSN: 1432-1440
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular medicine 66 (1988), S. 208-211 
    ISSN: 1432-1440
    Keywords: Food intolerance ; Food aversion ; Pain ; Duodenal ulcer ; Non ulcer dyspepsia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary In 50 duodenal ulcer out-patients and 50 non ulcer dyspeptic patients suffering from low to moderate epigastric painful symptoms the intolerance of 39 foods were significantly increased compared to a group of 50 healthy subjects. Food intolerance was not different between duodenal ulcer and non ulcer dyspeptic patients. Intolerance was related in the majority of nutrients to aversion and pain or to an increased incidence of aversion alone in patients and normals. In duodenal ulcer, coffee and fruit juice were associated with an elevated incidence of pain.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular medicine 70 (1992), S. 487-491 
    ISSN: 1432-1440
    Keywords: Beer ; Wine ; Water ; Ethanol ; Gastric emptying ; Gastrocaecal transit time
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Acute ingestion of pure ethanol has been reported to delay gastric emptying and to enhance the propulsive movements of the intestine. The aim of the present study was to investigate the comparative effect of beer (7.0% v/v), white wine (7.5% v/v), ethanol (7.5% v/v), and water on the gastric emptying of a liquid test meal and on the gastrocaecal transit time of lactulose added to the test meal. Gastric liquid emptying was assessed by means of a nasogastric intubation technique using polyethylene glycol 4000 as the non-absorbable marker. The gastrocaecal transit time was evaluated by a hydrogen breath test. Beer (P〈0.001) and white wine (P〈0.05) significantly accelerated gastric emptying in comparison with ethanol of the same concentration. The gastrocaecal transit time was significantly shorter when the liquid meal was administered with beer compared with ethanol (P〈0.005) and water (P〈0.01). The constituents in beer and white wine responsible for our observations remain to be found.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Naunyn-Schmiedeberg's archives of pharmacology 253 (1966), S. 395-401 
    ISSN: 1432-1912
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Administration of potassium chloride to normal rats causes a decrease in the hyperglycemic response to diazoxide. The hyperglycemic effect of diazoxide has been shown to exaggerate in animals with progressively increasing negative potassium balance. Potassium deficiency results in a decrease in intracellular potassium concentration accompanied by an increase in intracellular sodium concentration. There is no influence of varying potassium and sodium concentrations on 3′,5′-AMP phosphodiesterase activity. The activity of phosphorylase phosphatase has been found progressively reduced with increasing sodium concentration in the incubate. Diazoxide administered in doses insufficient to increase phosphorylase activity in normal rats has been shown to gain such action in rats with potassium deficiency. These data indicate the increase in the hyperglycemic action of diazoxide in potassium deficiency being caused by a reduction in phosphorylase phosphatase activity in consequence of the increase in intracellular sodium concentration.
    Type of Medium: Electronic Resource
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