ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. Polarography has been used to study the kinetics of the pseudomonomolecular reactions of α-allene bromides with amines. 2. Reactions of α-bromoallene derivatives containing either a hydrogen atom, or an alkyl substitutent at the bromoallene carbon atom, with neutral nucleophiles such as piperidine are overall second-order processes which follow a bimolecular SN2′ type nucleophilic substitution mechanism.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01179454
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