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  • Artikel: DFG Deutsche Nationallizenzen  (324)
  • 2020-2024
  • 1980-1984
  • 1955-1959  (324)
  • 1940-1944
  • 1890-1899
  • 1957  (324)
  • Industrial Chemistry  (213)
  • Chemical Engineering  (111)
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  • ZIB Katalog
  • Artikel: DFG Deutsche Nationallizenzen  (324)
Materialart
Erscheinungszeitraum
  • 2020-2024
  • 1980-1984
  • 1955-1959  (324)
  • 1940-1944
  • 1890-1899
Jahr
Schlagwörter
  • 101
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 523-527 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: By experimental means a relation is obtained between the thermal resistance of an eddy and its angular momentum. The eddy is stationary, and no extraneous motion is present. The secondary motion which may develop in the annulus between concentric rotating cylinders is used to obtain the eddies. The fluid motion is well defined at all times and at all points of space. Heat is passed through the eddies, and the Nusselt number is obtained, which varies linearly with the angular momentum. Both Nusselt number and angular momentum vary linearly with the peripheral velocity of the inner rotating cylinder, which can be interpreted in terms of a Reynolds number associated with fluid flow perpendicular to a cylinder.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 102
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 9D-9D 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 103
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 473-479 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A new method is proposed for the calculation of the heat of vaporization of hydroxylated compounds to an accuracy of about ±0.5 kcal./mole from no more data than the molecular structure and a boiling point. The older methods, by comparison, achieved an accuracy of about ±1 kcal./mole with a far greater computational effort, since they required the (usually hypothetical) critical temperature and critical pressure in addition to a boiling point.The method is here applied to aliphatic and aromatic alcohols, to ether-alcohols (e.g., the cellosolves), and to alcohols conaining keto or aldehyde groups (e.g., salicylaldehyde) and supersedes previous correlations covering the heats of vaporization of these compounds. The method can also be used to assess the quality of vapor-pressure data of the compounds covered by it.The method is based on the assumption that the heat of vaporization consists of two terms, the dispersion energy and the hydrogen-bond increment (close but not equal to the hydrogen-bond strength). The first term is calculated from a knowledge of the heat of vaporization of the equistructural hydrocarbon, now easily available from the Tables of A.P.I. Research Project 44. The hydrogen-bond term is calculated from a set of rules given in the report.The application of the increment method of this report to other properties and other functional groups is the subject of a continuing investigation.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 104
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 497-505 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The theory and design of continuous stirred tank reactors are extended to the complex but industrially important field of continuous-heterogeneous-reaction systems. The present investigation is concerned with the elementary process occurring when solid particles and a liquid flow into and from a single reactor or a chain of these reactors. The equations are developed for dissolution processes, and the theoretical size distributions and specific areas are confirmed experimentally. Performance is also related to operating conditions and reactor design.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 105
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 517-522 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Vapor-liquid equilibria of the systems n-octane-Cellosolve, ethylbenzene-Cellosolve, and n-octane-ethylbenzene-Cellosolve were determined at 760 mm. Hg. The activity coefficient data of Yang and Van Winkle (23) for the system n-octane-ethylbenzene and the data of this work on other systems were expressed by Wohl's three-suffix Margules equations. The ternary data are predicted satisfactorily from the binary constants and no noticeable ternary effects seem to exist for this ternary system.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 106
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 528-534 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Flow equations have been proposed for hydroextractor cakes wherein the pores are filled with moving liquid. These equations have been confirmed for the effect of each variable by use of different experimental techniques. The critical wetting rate has provided the most informative steady state, in which the cake is fed with liquid to maintain the inner surface of the liquid at radius rL coincident with that of the cake at radius rc. Transient techniques have also been used wither with a probe to time the movement of a liquid level between two radii less than rc, or with a photoelectric detector to observe the coincidence of rL = rc. The tests have proved the validity of the hydrodynamic assumptions involved in the equations and have provided both precise methods for research and practical methods for industrial purposes.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 107
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 3-10 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Since the shear rate of a non-Newtonian fluid is of importance in fixing the rheological or viscometric behavior of such a material, the present study has been concerned with the development of a general relationship between impeller speed and the shear rate of the fluid. The resulting relationship was then used to interpret and correlate power-consumption data on three non-Newtonian fluids by use of a generalized form of the conventional power-number-Reynolds-number plot for Newtonians.Flat-bladed turbines from 2 to 8 in. in diameter were used exclusively. Tank diameters ranged from 6 to 22 in. and power inputs from 0.5 to 176 hp./1,000 gal. The study encompassed a 130-fold range of Reynolds numbers in the laminar and transition regions. The results to date indicate that power requirements for the rapid mixing of non-Newtonian fluids are much greater than for comparable Newtonian materials.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 108
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 11-15 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Experimental studies of the mixing of coaxial streams of a natural gas and air at atmospheric pressure were made at Reynolds numbers of 44,000 and 79,000 under conditions where the turbulent-velocity profile of nearly uniform flow was altered as little as feasible by the blending of the two streams.Total diffusivities of natural gas in air for the region near the center of the conduit were computed from the data for turbulent, steady, nonuniform flow. The total diffusivities were found to be rather complicated functions of the conditions of flow. Limitations in the configuration of the apparatus did not permit a study of the behavior of the total diffusivities to be made over as wide a range of flow rates as would be necessary to investigate the large-scale trends indicated by this study.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 109
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 29-32 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A phase-behavior approach to the prediction of the performance characteristics of a dissolved-gas-drive reservoir is unique in that the problem of choosing flash, differential, or composite-solution gas-oil ratios and formation-volume factors has been circumvented. Data required are a compositional analysis of the reservoir fluid, the bubble point of this fluid, and the relative-permeability curves for the reservoir rock.Gas-oil ratios and formation-volume factors were calculated under conditions duplicating the performance of the reservoir. A comparison was then made between these results and those obtained by calculations involving a differential, a flash, and a composite process. A vital factor in the solution of the problem is the accuracy of the calculated equilibrium constant. Agreement within 3% was obtained when a calculated differential formation-volume curve was compared with an experimentally determined curve.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 110
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 16-28 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: One of the important factors affecting the efficiency of vapor-liquid contacting operations is the relationship between available interfacial area and contact time.Because of the difficulties in measuring these quantities, little information has heretofore been made available on them. Previous studies have been confined to extreme over-simplifications of the turbulent type of contacting taking place in fractionation devices. The present investigation consisted of the determination of interfacial area and contact time for the formation of air bubbles submerged in water and aqueous solutions. The bubbles were produced at single vertical slots and rose through a flowing liquid. In order to complete the study on physical contacting, a companion study is concerned with vapor-liquid behavior in the forth and entrainment zones. The experimental technique in this study involved taking high-speed motion pictures of the bubbling action. Measurements of the area and volume of bubbles were made at intervals during the course of their growth, and values of total contact time and average interfacial area per unit volume of vapor are presented.It was found that both the average interfacial area per unit volume of vapor a and the total contact time tm were primarily affected by the head of flowing liquid on the slot. Below slot submergence of approximately 2.5 in. of liquid, interfacial area was shown to decrease with increasing slot submergence and increasing slot area. Above 2.5 in. of liquid, interfacial area was a function of skirt clearance, liquid viscosity, and surface tension.Total contact time was found to increase with increasing slot submergence and to decrease with increasing vapor rate and skirt clearance.Through the use of an integrated mass transfer-rate equation, the terms a and tm can be used in conjunction with the appropriate mass transfer coefficient for predicting the point efficiencies on bubble-cap plates.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 111
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 33-36 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Experimental equilibrium vapor and liquid compositions are reported for the hydrogen-methane system at -150°, -200°, and -250°F. and at pressures of 500 to 4,000 lb./sq. in. The ternary system hydrogen-methane-propane was studied at 0°, -100°, and -200°F. at 500 and 1,000 lb./sq. in. Phase compositions were determined for a limited number of similar conditions for the hydrogen-methane-propylene and hydrogen-methane-ethylene-ethane-propylene-propane systems.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 112
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 37-42 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Data are reported for the evaporation of spheres of naphthalene into air, helium, carbon dioxide, and Freon-12, and of liquid diethyl adipate into air at pressures from 0.1 to 3,000μ Hg and at Reynolds numbers from 0 to 1.37. By use of suitable values of the surface-evaporation coefficient and the assumption of additivity of surface evaporation and diffusional resistances, the data are well correlated. The results lend semiquantitative support to the theory of sublimation of crystals developed by Stranski.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 113
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 43-48 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Rates of mass and heat transfer to single spheres and cylinders at low Reynolds numbers are predicted from boundary-layer theory. The velocity distributions which are assumed to exist are those derived from the linearized Navier-Stokes equations by Tomotika and Aoi.In the case of the sphere the Nusselt number is found to be a function only of the Peclet group when the Stokes streamline function is assumed to apply. Experimental data for mass and heat transfer to singel spheres fall 10 to 40% higher than predicted from the theory. Experimental data for heat and mass transfer to single cylinders at large NPe check the theory.Curves are also plotted for the efficiency of removal of colloidal particles by combined direct interception and diffusion for both spheres and cylinders.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 114
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 63-68 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 115
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 56-62 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Liquid extractions of benzoic acid-toluene solutions by means of water were studied under varying flow rates of both solvents in a 2-in. perforated-plate column to which pulsations of different frequencies and amplitudes were applied. Studies on reversal of the phase of the dispersion were made. With fixed flow rates of both solvents, the rate of extraction increased much more rapidly when the flow through the perforation became turbulent. The results are correlated by means of Reynolds number based on the flow through the perforations and are calculated from the product of the frequency and amplitude of the pulsations.
    Zusätzliches Material: 16 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 116
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 49-55 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Heat transfer coefficients were measured experimentally for carbon dioxide in turbulent flow in an 0.18-in. I.D. pipe. The pressure was 1,200 lb./sq. in. abs. and the bulk temperature varied from 70° to 120°F. In this critical region the coefficients between fluid and tube wall ranged from 300 to 2,600 B.t.u./(hr.)(sq. ft./°F.) over a Reynolds number interval of 30,000 to 300,000.Existing empirical and semitheoretical correlations were found inadequate in this region, where the thermal conductivity, viscosity, density, and specific heat are all varying rapidly and nonuniformly with temperature. A method of integrating the heat and momentum transfer equations with variable physical properties, recently proposed by Deissler, was applied to the experimental data and found to fit well. The application required extensive calculations, which were carried out with an Electrodata digital computer.A simplified procedure was proposed for estimating heat transfer coefficients in the critical region by using a semitheoretical equation developed for zero heat flow. Simple rules were suggested for estimating the temperature at which to evaluate the physical properties when this equation is applied to the realt case of finite heat transfer. The method worked well when compared with the computed heat transfer coefficients of Deissler for supercritical wate but showed about 30% deviation when compared with the carbon dioxide results. This discrepancy is believed due to the fact that the carbon dioxide was very close to the critical point (reduced pressure = 1.1) but the water was somewhat further removed (reduced pressure = 1.6).
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 117
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 69-74 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Carbon tetrachloride was evaporated into a stream of air over ranges of gas concentration from 0 to 0.70 mole fraction carbon tetrachloride, Reynolds number from 600 to 15,000, and Schmidt number from 0.23 to 1.17. The data were correlated by an equation and also by a computer solution to the differential equation describing mass transfer from values of eddy viscosity and eddy diffusivity obtained from the literature.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 118
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 75-82 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The equations and graphs presented here for the vapor-liquid equilibrium of the nitrogen-argon-oxygen low-temperature system are based on published binary and ternary experimental data involving mixtures of nitrogen, argon, and oxygen, and on careful thermodynamic study over a period of years of accurate plant-performance data on tall, large air-rectifying columns operating near the minimum reflux ratios. The plants have achieved separations that are impossible according to some of the published equilibrium data, and thus the plant data have made a major contribution toward the preparation of this paper.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 119
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 147-152 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Experimental data are presented for the heats of mixing of liquids at 25°C. and 1 atm. pressure for ten binary and five ternary systems. For nonpolar binary systems a two-constant equation has been developed which correlates the data within experimental accuracy. Several equations which have been proposed for the calculation of ternary heats of mixing from binary data are tested for the systems studied. The method of Jost and Röck (4) for determining the constants in power-series functions from experimental data is considered.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 120
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 161-164 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The densities of acetone-water liquid solutions have been measured over the entire composition range from 20°C. to within 3° to 7°C. of the normal boiling point of the mixture. The density was measured with a Robertson pycnometer (13), which was modified slightly. The density values are thought to be accurate to within ±0.00005 density units. The technique for determining density values of the volatile mixture near the boiling temperature is given in some detail. The refractive index (nD25) of pure acetone has been redetermined and equals 1.35596 ± 0.00003.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 121
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 165-171 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: New absorption- and stripping-factor functions have been developed for use in computing multicomponent separations in fractionators, reboiled absorbers, refluxed strippers, and columns with side-stream strippers. Charts of fraction not absorbed vs. A factor and fraction not stripped vs. S factor are included with the equations for these operations.These functions and procedures are of particular advantage in computing complex columns, i.e., two or more feeds and three or more products, where the proposed A and S factor equations provide a method for converging on a solution.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 122
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 180-182 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Concentration relations between foams and their residual liquids (frothates) have been examined.Clean air streams of 88, 91, and 96% water saturation were bubbled into aqueous solutions of isobutyl alcohol. The concentration of the alcohol in the collected and collapsed foam was plotted against its concentration in the bulk liquid.Varying the saturation of the air stream resulted in both positive and negative enrichment of the foam with the surface-active alcohol. This suggests that where froth-frothate-concentration relations are unfavorable, a change in operating conditions may advantageously affect these relations and allow the mixture to be foam separated.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 123
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 191-197 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Vapor-liquid equilibria of two binary systems, benzene-n-hexane and benzene-cyclohexane, were measured at pressures from 4 to 18 atm. The three-constant Redlich-Kister equation was found satisfactory for correlation.With the benzene-n-hexane system no azeotrope occurred; with the benzene-cyclohexane system an azeotrope appeared, and the mole fraction of cyclohexane in it diminished with increase in pressure. Lack of correction for fugacity in the vapor phase introduced a maximum error of 4% in activity coefficients at highest pressure.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 124
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 213-222 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Data were obtained in flat-plate continuous-flow thermogravitational columns to check the theory developed by Furry, Jones, and Onsaer and a modification of this theory proposed by the authors. Separations of ethyl alcohol-water and benzene-n-heptane mixtures were measured, flow rate, column length, temperature difference, spacing between plates, and inclination of the plates being varied in the experiments. Theory and data are in qualitative agreement for the range of variables studied. Quantitative agreement exists between theory and experiment in the region of practical design for liquid-thermal-diffusion plants.Equations to aid in the design of thermal-diffusion plants are developed, and a plant to treat 1,000 bbl./day of a liquid aromatic-aliphatic mixture is designed and costs are estimated.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 125
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 230-235 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Reaction kinetics for the catalytic dehydrogenation of sec-butyl alcohol to methyl ethyl ketone has been investigated at atmospheric pressure and temperatures ranging from 650° to 750°F. in the presence of solid brass spheres, 1/8 in. in diameter. The nature of this catalyst permitted a direct evaluation of the surface involved in this reaction and allowed the definition of a surface-feed ratio to be expressed as S/F in place of the conventional weightfeed ratio W/F commonly used in catalytic studies. Feed compositions ranged from secbutyl alcohol to mixtures containing high percentages of methyl ethyl ketone and hydrogen.In these studies mass transfer effects were found to be significant and, for a proper representation of conditiated at the catalyst surface, must be taken into account. The effect of feed compositions on the initial rates of reaction showed that the rate-controlling step was the desorption of hydrogen involving a single-site mechanism.In addition, the results of these studies have been used to produce values of height of reactor unit HRU which have been found to correlate with mass velocity and temperature. The HRU provides a simple means of calculating the depth of catalyst necessary to effect a designated conversion.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 126
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 223-229 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A radioisotope technique has been utilized to study the point holdup of the dispersed phase and some operational flow characteristics in a packed countercurrent liquid-liquid extraction tower. The system used was toluene-water and the packing was Raschig rings. The toluene dispersed phase was tagged with gamma-radiating iodine-131.The study revealed that holdup experiences a hysteresis cycle with variations of the continuous-phase flow rate. Correlating equations are presented for “total” and permanent holdup, below loading, to account for this hysteresis. Entrance effects and flow maldistribution effects are readily determined by the method utilized. Displacement studies demonstrated that no simple “operational” dispersed-phase flow holdup exists, but rather a complex dispersed-phase movement, which involves all the “nonhysteresis” permanent holdup.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 127
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 248-256 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 128
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 262-267 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: In spite of the importance of hydrogenation procesing operations in the refining of petroleum there are only limited experimental volumetric and phase equilibrium data concerning mixtures of hydrocarbons and hydrogen. An investigation of the volumetiric and phase behavior of the hydrogen-n-hexane system was therefore undertaken.The experimental study involved measurements of the specific volume of four mixtures of hydrogen and n-hexane at eight temperatures between 40° and 460°F. for pressures up to 10,000 lb./sq. in In addition, the composition of the gas phase in heterogeneous mixtures was determined at six temperatures within the interval mentioned above for pressures as high as 10,000 lb./sq. in.Little about this system was found to be qualitatively unusual except that the critical pressure exceeded 10,000 lb/sq. in. at all temperatures below 340°F. As would be expected, the dew-point gas was rather lean in n-hexane for temperatures below 220°F. and at pressures above 100 times the vapor pressure of n-hexane throughout the pressure range covered by this study.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 129
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 299-304 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The interaction between a turbulent air stream and a water film flowing parallel to it was studied. The variables explored were the liquid flow rate, the gas flow rate, and the film height. The data were correlated in terms of a liquid and a gas Reynolds number. Thinner films or films having a lower Reynolds number were more stable. For the experiments reported in this research the transition from a smooth surface to a surface possessing two-dimensional waves occurs at hUτρliquid/µliquid of about 520. Transition from two-dimensional waves to a “pebbled” surface occurs at a value of this parameter of about 600. Theories presented in the literature for the initiation of waves on a liquid surface do not adequately describe the experimental results.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
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  • 130
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 318-320 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: This paper presentes a correlation to predict the equilibrium ratios of hydrogen in hydrocarbon mixtures by use of the parameters of pressure and convergence pressure. Also a procedure to predict convergence pressures of hydrogen-containing mixtures was developed from a correlation of critical loci. With the predicted convergence pressure the measured values of hydrogen equilibrium ratios in binary hydrogen-paraffin mixtures were predicted with a statistical deviation of 8.1% for 237 measurements. Including hydrogen-olefin and multicomponent mixtures of hydrogen, paraffins, and olefins, the statistical deviation was found to be 11.3% for a total of 375 comparisons with measured values of hydrogen equilibrium ratios.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 131
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 325-329 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The surface tensions against air of acetone-water solutions have been measured over the entire composition range from 20°C. to generally within 1° to 10°C. of the normal boiling points. The capillary-height method was employed and the results are thought to be accurate to better than ±0.5%.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 132
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 343-347 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Constant layer moisture at the hot surface is found to exist during the constant-rate period of drying of sand on a hot surface in still air. It accounts not only for the constantrate period of drying itself but also largely for the length of the period.Temperature of the air-surface interface usually has minor effects on the rate of vaporization because equilibrium between vapor and the bed is not established during periods of rapid vaporization.Numerical relationships have not been established.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 133
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 361-365 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Two-phase critical flow of steam-water mixtures has been investigated over a pressure range from 4 to 43 1b./sq.in. abs. and a quality range from saturated vapor to 1% (weight) vapor. Discharges were measured from 1/4-,1/2-, 3/4-, and 1-in. pipes and from annuli of intermediate cross-sectional areas. The experimental mass flow rates are always grteater than the values calculated on the basis of a homogeneous flow model. Several empirical methods for correlating the data were determined, and comparisons are presented of the predictions of several analytical flow models.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 134
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 373-381 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Applying both their own assumptions and the mechanism of lateral mixing proposed by Ranz (20), the authors obtained theoretical formulas for effective thermal conductivities ke in packed beds. Previously reported experimental data were analyzed with these equations, and the usable data for predicition of ke were shown.In order to see the influence of both packing characteristics and temperature on the effective thermal conductivities, experimental data were obtained with air for beds with various kinds of packing, i.e., iron spheres, porcelain packings, cement clinker, insulating fire brick, and Raschig rings. Correlation of these data with Equation (15) showed that this equation adequately expressed the heat transfer mechanisms in packed beds with motionless gases, especially at hight temperatures.
    Zusätzliches Material: 18 Ill.
    Materialart: Digitale Medien
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  • 135
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 391-394 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A rigorous method is presented for the evaluation of the heat requirements in binary batch fractionations which involve negligible column hold up. The method, in which the additional variables of the discontinuous process are taken into account, is a modification of the methods of Ponchon and Savarit for continuous operation. Two examples, one for a fractionation in which the composition of the product is constant and the other in which the reflux ratio is constant, are given as illustrations of the method.The application of the method permits more accurate evaluation of reboiler and condenser heat loads and, in turn, better design.
    Zusätzliches Material: 7 Ill.
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  • 136
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 276-279 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: On the assumption of laminar Newtonian flow, flow profiles are developed for both the vertical plate and cylindrical column by use of classical equations. From the flow profiles the mass transport, vertical pressure gradient, and optimal design parameters are calculated. With the Reynolds-number criterion used to ascertain the maximum nonturbulent velocity, minimal values for the plate distance and column radius can be calculated. An example is included for each case.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 137
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 268-275 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Values of total pressure drop are presented for the flow of vaporizing water in an internally heated 1-in. I.D. by 1½-in. O.D. annulus at mass velocities of 270 to 1,440, lb./(sec.)(sq.ft.), pressures of 9 to 180 lb./sq. in., and up to 0.34 fraction by weight vaporized. The total heated length over which boiling took place was as large as 6 ft. There is no evidence of “sonic” pressure jumps at the outlet. The results for the annulus mentioned lie within +30 to -11% of the Lockhart-Martinelli curve at higher qualities and with ±45% of the correlation at lower qualities where the actual quality is more uncertain. A simplified correlation in terms of quality and volume fraction of liquid predicted the two-phase frictional pressure drops with an average error of 41%.It was found that the ratio of the two-phase pressure drop through a 0.3-in. orifice to the drop with no vaporization was approximately a linear function of the quality in the vena contracta but was only one tenth to one third as great as would be predicted if the mixture were to expand as a homogeneous fluid. Prediction of orifice presure drops is improved if slip between vapor and liquid is considered.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 138
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 286-288 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The separation of 4.5 g. of americium from approximately a kilogram of light rare earths (primarily lanthanum) was achieved on a pilot plant scale by chromatographic displacement of the mixture from Dowex-50 resin with 0.1% ammonium citrate at pH 8 into hydrogen-form Dowex-50. The americium collected into a narrow band and was eluted free from lanthanum but contained an equal weight of cerium. A 6- and a 2-in.-diam. column were used in tandem. Use of a final column with a much smaller diameter would have permitted a cleaner separation from cerium, but this was left for a laboratory-scale separation by a different process. Precipitation, which was observed in the columns during the first runs, was later avoided entriely by use of high flow rates both initially and during the transfer between columns. No adverse effects were noted from ∼15 curies of alpha activity.
    Materialart: Digitale Medien
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  • 139
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957) 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 140
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 305-312 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The design variables that affect the pressure drop across dry perforated plates were determined and correlated. Average orifice coefficients were calculated for the perforated plates by using a modified form of the single-orifice flow equation.The variables which affected the orifice coefficients were found to be the hole diameter, hole pitch, plate thickness, fraction of the plate covered by the perforated area, and a Reynolds number based on the hole diameter. The orifice coefficients have been correlated with these variables in dimensionless groupings.The correlation presented covers a practicable range of variables for which the pressure drop may be predicted in design.
    Zusätzliches Material: 22 Ill.
    Materialart: Digitale Medien
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  • 141
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 484-489 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Pressure drop due to fluid friction has been measured in a smooth tube; in six smooth concentric annuli; and between smooth, parallel, flat plates. The data cover the viscous, transition, and lower turbulent ranges of flow. Friction factors are in agreement with theory in the viscous range and can be correlated uniquely in the fully turbulent range by means of a modified hydraulic radius concept. Limits of the transition region in annuli are functions of the ration of inner and outer radii. Correlations in the fully turbulent range permit friction factors for the noncircular ducts to be predicted within the uncertainty of smooth-tube data. Such factors can be used for the prpose of correlating other variables as well as for direct calculation of pressure drop.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 142
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 439-442 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The problem of axial mixing in straight pipes is analyzed by a modification of G. I. Taylor's analysis. The treatment presented here includes the effect of both Schmidt and Reynolds numbers throughout the turbulent-flow range. All applicable data on flow of gases and liquids are found to confirm the validity of the method.The analysis indicates that axial mixing increases rapidly as the flow approaches the laminar region, especially for liquids, and that pipe roughness causes a relatively small increase in axial mixing. Turbulent eddy diffusion in the axial direction has a negligible effect.The results of the analysis are applicable to those systems wherein the kinematic viscosity of the flowing mixture does not vary greatly from one region to another and in which the concentration region of interest is spread out along a sufficient length of pipe. These limitations are broad enough to permit most practical problems to be treated by the method.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 143
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 535-538 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The problem of diffusion in a moving medium with given motion of the boundaries is considered. The method presented yields the analytical solution to any desired degree of accuracy provided that solutions for certain associated problems of diffusion in a medium at rest with boundaries at rest are known. The method is applied to the analysis of partial and approximate solutions previously presented for the one-dimensional case of a spherical cavity in a liquid with radial boundary motion induced by evaporation.
    Zusätzliches Material: 5 Ill.
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  • 144
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 145
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 395-404 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 146
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 418-427 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The effects of the physical properties and volume flow rate of liquids on the surface area of sprays produced by a pressure type of atomizing nozzle were determined experimentally. the specific surface area of the sprays is correlated by an equation of two dimensionless groups in terms of the variables surface tension to the -1.0 power, kinematic viscosity to the -0.4 power, and volume flow rate to the 2.4 power. The volume flow rate is correlated by an equation of two dimensionless groups containing the variables viscosity to the 0.17 power, density to the -0.58 power, and spray pressure to the 0.42 power. The conversion of compression energy to surface-area energy appears to be constant at approximately 0.1%.
    Zusätzliches Material: 19 Ill.
    Materialart: Digitale Medien
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  • 147
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 9S 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 148
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 431-431 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 149
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 443-448 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A method is presented for the analysis of a reaction between a porous solid and a gaseous reactant where the kinetic expression is linear in the concentration and where appreciable concentration gradients are established in the pore system as a result of diffusive transport rate. Two cases are treated mathematically: a single cylindrical pore initially of uniform diameter and a porous solid initially containing uniform cylindrical pores with random intersections. The mathematical solutions to the latter case are used to interpret the experimental results reported in the literature on the gasification of graphite rods with carbon dioxide. Values of the computed effective diffusivity are an order of magnitude smaller than the bulk diffusivity at the same temperature and pressure.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 150
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 467-472 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Previous papers have reported equilibrium data for the binary systems cyclohexaneheptane, heptane-toluene, and cyclohexane-toluene. This present study gives similar data for the ternary system cyclohexane-heptane-toluene and compares the activity coefficients with those predicted from the three limiting binaries.The ternary activity coefficients fall well in line between the limiting-binary data. Distribution is about as would be predicted by the ternary Margules equations. As an approximation, if the coefficients are plotted as a function of the aromatic concentration only, without consideration of the ratio of naphthenes to paraffins, reasonably good correlation is observed.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 151
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 11D-11D 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 152
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 10D-11D 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 153
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 12D-12D 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 154
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 83-91 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Measurements are reported on axial mixing of binary gas mixtures at room temperature and atmospheric pressure in a random bed of spherical particles. By means of the Fick's Law equation for diffusion an axial Peclet number, dp U/Ez (where dp is particle diameter, U is interstitial velocity, and Ez is axial eddy diffusivity), was computed in terms of the ratio of the amplitudes of a sinusoidal concentration wave at the inlet and outlet of the bed. An experimental method was devised to eliminate end effects in the system. For the gas systems H2—N2 and C2H4—N2 and for Reynolds numbers between 100 and 400 the mean of twenty-one determinations of axial Peclet number was 1.88 ± 0.15. This value is in excellent agreement with a value of 2.0 predicted theoretically on the assumption that the bed acts as a series of n perfect mixers, where n is the number of particles traversed between inlet and outlet.Axial diffusivity for turbulent flow of gases among particles is about sixfold larger than radial diffusivity, previously determined. It is suggested that axial diffusivity may not, perhaps, be neglected in contacting devices, such as adsorbers and catalytic reactors.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 155
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 117-120 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 156
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 111-116 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The viscosity of a suspension is related to the properties of the suspending liquid and the suspended particles by measuring the viscosity of suspensions made up of closely sized materials such as glass spheres, plastic Zeolite spheres, blasting sand, and salt cubes in a wide range of concentrations in liquids of varying properties made up of castor oil, tetrabromoethane and carbon tetrachloride, or corn syrup and water. The measurements were made under carefully controlled conditions by means of a Brookfield viscometer, and the reproducibility of results was demonstrated by repetitive runs.Equations are derived to describe the viscosities of these various suspensions in terms of the viscosity and density of the suspending liquid and of the shape, size distribution, density, and concentration of solid particles. The range of concentration covered is from infinite dilution to near infinite viscosity.The results obtained can best be explained by postulating nonuniform distribution of particles in a suspension in a network of tetrahedral and simple cubical packings.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 157
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 101-110 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: This paper describes further research on a 4-in. I.D. by 8-ft. spray tower of Elgin design. Previous work concerned limiting flow and holdup in this tower. Owing to its high capacity and low cost, the spray tower would have much greater commercial application in liquid-liquid extraction if its conditions of transient operation could be predicted and if it could be operated to yield low Ht values. This research attempts to show that transient conditions can be predicted and that low Ht values for both mass and heat transfer can be realized near the limiting flow conditions.Theroretical equations for rate of approach to steady state derived and tested for the systems ethylene dichloride-water-propionic acid and ethylene dichloride-water-acetic acid show that the approach depends on the ratio of the phase flow rates. This study is important for the prediction of start-up time for industrial towers.With the same systems the extraction capacity of the spray tower was investigated up to the condition of rejection. The results were correlated as KEa and Ht, OE vs. a function of the ratio of the phase flow rates. The dispersed-phase flow rate was found to have primary significance.The heat transfer rates between water as continuous phase and solvents of various denisties were correlated as Ht′ values plotted against a function of the ratio of the phase flow rates. The advantages of operation near rejection were demonstrated, and the effect of direction of heat transfer was found to be significant.
    Zusätzliches Material: 19 Ill.
    Materialart: Digitale Medien
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  • 158
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 121-126 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Values of thermal conductivity and temperature coefficients for thirty-five pure organic liquids, in addition to those previously reported, obtained with a previously described apparatus (Part I), are presented. Values of thermal conductivity or temperature coefficients for twenty-eight of these liquids have not been reported before. The experimentally determined maximum error is ±1.0%.The two methods for predicting the thermal conductivity of liquids previously proposed (Parts I and II) are extended to cover the types of compounds studied in this investigation, in particular ring compounds.The temperature coefficient of thermal conductivity was observed to decrease rapidly, approaching zero as the freezing point is approached. The existence of a transition temperature or region within the liquid state is shown and identified with the onset of molecular rotation.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 159
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 127-136 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Mass and heat transfer rates in extraction are studied theoretically and experimentally for the practical range of the variables involved. For the particular but typical case of liquid drops moving through another liquid a simple correlation for the over-all mass transfer coefficient is presented, which holds with a probable error of 20%.Included are systems in which the rate is limited by either coefficient, as well as systems in which both coefficients are significant. The correlation, valid for both directions of transfer with either phase dispersed, is useful for the extrapolation of performance from system to system in a given piece of equipment. Also, together with correlations for transfer area and effective driving force, it is part of the information needed for design.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 160
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 144 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 161
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 136-142 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The pressure-drop characteristics associated with one liquid and one gaseous phase flowing concurrently in a pipe or tube have yet to be understood. The operation of evaporators, boilers, and condensers has long stimulated interest in the pressure drop of steamwater mixtures, and more recently this specialized case of one-component, two-phase flow has received even greater attention from the applications in cooling nuclear reactors. The two-phase-flow problems have not been amenable to through theoretical analyses, and therefore empirical and semiempirical correlations have attained unusual prominence in practical applications. The present investigation employs a new research tool for the study of two-phase-flow structure.A variety of geometric flow patterns is possible. Bergelin, Alves, and others have classified these patterns according to visual appearance; whereas the Martinelli classifications were based upon whether the flow in each phase was termed viscous or turbulent. The distinction between viscous and turbulent flow in either phase is rather arbitrary, and if the Reynolds number for one phase, calculated on the basis of the total tube diameter, is greater than 2,000, the flow in the phase is called turbulent. This investigation is confined to the study of annular flow, in which most of the liquid is found in an annular ring surrounding the central vapor core and the flow in each phase is turbulent.Boiling or flashing occurs when superheated water rises in an insulated vertical tube at atmospheric pressure. For a separated two-phase flow geometry, the mean linear steam velocity may exceed that of the water. The fraction of the tube occupied by the steam (void fraction) at a given cross section cannot be obtained directly from a determination of the thermodynamic quality. Void fractions, however, must be known for the estimation of the pressure drops due to head and momentum changes.Void fractions and pressure drops for steam-water flows were measured in an 0.872-in. I.D. vertical tube at atmospheric pressure over a quality range of 0 to 4%. The test section was the hot leg of a natural-circulation loop, and the inlet liquid flow rate ranged from 1 to 3 ft./sec. A new technique for measuring void fractions was used, and the method utilizes the difference between the gamma-ray absorption coefficients of water and steam.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 162
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 10M 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 163
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957) 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 164
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 153-156 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 165
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 176-180 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The dynamics of agitating single- and two-phase liquid mixtures in the absence of an air-liquid interface was compared with that of similar systems with an interface. Two geometrically similar cylindrical vessels, 12 and 18 in. in diameter respectively, were used, each fitted with a similar six-bladed, disk-turbine impeller.New general correlation curves of power number with Reynolds number are presented which show that elimination of the air-liquid interface makes it possible to attain dynamic similarity in scale-up in unbaffled vessels but makes little difference in baffled vessels.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 166
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 187-190 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Equilibrium isotherms are presented for the cation exchange of copper and sodium on Dowex-50 resin in solutions from 0.01 to 4N in chloride content, and the equilibrium data are correlated on the basis of the Donnan equilibrium. Data are also given on the water content of the resin and the diffusible ions present in this water.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 167
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 208-212 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The effective correlations of turbulent velocities and friction losses for tubes and parallel plates recently published have been analyzed further in order to simplify their use and to extend the range of Reynolds number.Working diagrams have been developed from which turbulent friction losses and local velocities for tubes and parallel plates can be calculated without interpolation or trial-and-error procedures. Tentative values of parallel-plate friction factors and average-to-maximum velocity ratios in the transition region are also included, and new experimental values of the velocity ratio in smooth tubes are reported. The working diagrams permit more rapid, accurate, and consistent calculations of fluid behavior to be made over a wider range of operating conditions than was previously possible.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 168
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 236-241 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The decreasing solubility of hydrogen in hydrocarbons with decreasing temperature continues down to the freezing point of the hydrocarbons, around -300°F. This behavior is shown to be an enlargement of phenomena exhibited by normal hydrocarbon mixtures. Methods of predicting equilibrium-phase compositions are presented for hydrogen in ligh-hydrocarbon systems. The correlations are satisfactory for binary and certain ternary systems, but are not reliable for complex mixtures.
    Zusätzliches Material: 18 Ill.
    Materialart: Digitale Medien
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  • 169
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 242-248 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Heat transfer and friction measurements were made for air flow through a smooth copper pipe and six other commercial pipes, with a ratio of diameter to equivalent sand roughness varying from 640 to 64. The Reynolds number range was 10,000 to 80,000. Though some increase in heat transfer coefficients with roughness was found, the heat transmission per unit power loss always decreased.The momentum-heat-transfer anlogies of Reynolds and Colburn are shown to be inadequate for handling the experimental data. Those of Prandtl and Taylor, von Kármán, and Pinkel fail to show a required Reynolds number dependence of jh when friction factor has become independent of Reynolds number for a rough pipe. Martinelli's equation shows such dependence and, even in approximate form, gives good prediction of the experimental results.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 170
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 405-410 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Local convective thermal transfer is difficult to predict for nonuniform three-dimensional boundary flows. Direct measurements of local transfer from objects of practical interest are therefore useful in the prediction of thermal transfer and in an understanding of multidimensional boundary flows.Measurements of the gross and local transfer were made upon a silver sphere 0.5 in. in diameter and a ceramic porous sphere of the same size from which n-heptane was permitted to evaporate. The air stream had a level of turbulence of approximately 5.4% and only small variation in velocity with position. Temperature distributions in the boundary flows around these spheres were determined, and from these distributions local transfer coefficients were established for the forward hemisphere. The gross transfers were established from the electrical energy added to the silver sphere and from the quantity of n-heptane evaporated from the porous sphere.The local thermal transfers were in reasonable agreement with some of the theoretical analyses based upon a three-dimensional laminar-boundary layer. Satisfactory agreement was obtained between spatial integration of the local transfer and the simultaneously measured over-all values. These, in turn, were in fair agreement with correlated values of the gross thermal and material transfer from spheres.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 171
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 462-466 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A kinetic study of the catalytic vapor-phase hydrogenation of three aldehydes (acetaldehyde, propionaldehyde, and n-butyraldehyde) was made at low conversions with a commercial supported nickel catalyst. A simple initial rate equation was determined and found to agree with a mechanism suggested by the ideal kinetics of Hougen and known experimental evidence. By means of this equation the relative reactivities of the aldehydes were compared and found to agree with the predictions of organic theory. An improved reactor designed to ensure isothermal operation is described.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 172
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 480-483 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 173
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 321-324 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 174
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 331-335 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Extension of the kinetics of the catalytic oxidation of nitric oxide on activated carbon and silica gel confirms the rate-controlling step postulated by previous workers. The effect of variables including water vapor on the reaction rate is expressed by an equation containing the constants a, b, c, and w, which have been evaluated for both catalysts at 30°, 45°, and 60°C. The effect of water vapor is to reduce the reaction by reversible adsorption on the active sites of the catalyst. The value of w is dependent on temperature but independent of water-vapor concentration up to a relative humidity of 20%. Above 20% the value of w for activated carbon increases greatly with relative humidity, in agreement with the effect of capillary adsorption at high water contents.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 175
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 353-360 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Linear partial-differential eqations are often encountered when thermal or material diffusion in flowing systems is considered. Analytic solutions of such equations are known for only the simplest situations. In two examples a graphical method of solution is presented and demonstrated which makes feasible, without excessive labor or special computing facilities, the use of available knowledge concerning turbulent flow in the prediction of thermal or material transfers in complex situations involving linear steady flow.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 176
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 381-385 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Heat and mass transfer and coagulation are considered as related to the mean-square relative velocity between particle and fluid uR2 and eddy diffusion as described by the mean-square particle displacement, Xp2. The mathematical methods used are similar to those employed in the early calculations of the Brownian motion.The mean-square relative velocity is obtained as a function of particle characteristics, intensity of turbulence, and a fluid correlation coefficient. In the limiting case of equal particle and fluid density uR2 = 0, and for very heavy particles uR2 → uF2.A general expression for the eddy diffusivity is obtained is obtained which reduces to the same form as that of the fluid for the stationary state. However, the correlation coefficient to be used in the calculations depends on uR2. As a first approximation, it can be assumed that at a sufficiently long time from the introduction of the particles, fluid and particle diffusivities are equal.For short times after injection, the particle spread may be much less than that of the fluid. An illustrative calculation for the initial spreading of a jet of suspended particles is offered. In all cases an effort is made to organize the available experimental data within the framework of the theory.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 177
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 760-761 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 178
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957) 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 179
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 776-780 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Es wird ein UR-Gasanalysator mit einem Strahlengang beschrieben. Durch Erzeugung eines konstanten Wechseldruckes in einer Meßküvette wird eine Wechselstrahlung gewonnen, welche mit einem Wechselstrahlungsempfänger und einem nachgeschalteten Wechselspannungsverstärker gemessen wird.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 180
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 772-775 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Nach Aufnahme von sieben Eickurven wurden 36 neue Dampfdruckkurven von Substanzen aufgenommen, deren Dampfdruckdaten zumindest im Bereich zwischen Siedepunkt und kritischer Temperatur nicht der Literatur entnommen werden konnten. Die experimentell bestimmten Werte wurden nach der van der Waalsschen Dampfdruckgleichung graphisch dargestellt. Für die meisten Substanzen konnte aus diesen graphischen Darstellungen der kritische Punkt experimentell bestimmt werden. Wo dies nicht möglich war, wurde er über die molare Verdampfungswärme und mit Hilfe des Theorems der übereinstimmenden Zustände berechnet. Soweit die Substanzen die Riedelsche Dampfdruckformel erfüllten, wurde der spezifische kritische Parameter αk berechnet. Schließlich wurden die Dampfdruckformel von van der Waals und L. Riedel miteinander verglichen.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 181
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 790-790 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 182
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 817-820 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 183
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Das Drehrohr wird in der Verfahrenstechnik als Kugelmühle für Trocken- und Naßmahlung, Stabmühle, Mischtrommel, Trommelscheider, Wärmeaustauscher, Kühler oder Röhrentrockner und in seinen größten Abmessungen als Drehrohrofen angewendet. Am Beispiel des Zement-Drehofens werden die konstruktiven Probleme beim Antrieb und der Lagerung erörtert. Abschließend werden praktische Erfahrungen bei der Wartung der Öfen mitgeteilt.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 184
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 814-816 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Es werden die Ursachen für Klumpenbildungen und das Haften trockener, staubförmiger Subststanzen besprochen. Bei den Untersuchungen ergab sich eine allgemeine Zustandsgleichung für Staubsysteme, mit der über verschiedene Spezialprobleme wesentliche Aussagen gemacht werden können.
    Materialart: Digitale Medien
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  • 185
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 823-823 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 186
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 824-824 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 187
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 827-828 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 188
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 481-486 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 189
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 487-487 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 190
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 489-490 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 191
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 493-496 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 192
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 517-519 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Es wird ein neues Meßgerät beschrieben, das die bei der Reaktion zwischen Nitriersäure und Benzol auftretende Wärmetönung mißt und somit das Nitriervermögen von Nitriersäuren fortlaufend bestimmt.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 193
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Da sich synthetisch hergestellte Kohlenwasserstoffe wegen ihrer Reinheit und einheitlichen geradkettigen Struktur hervorragend als Ausgangsstoffe für die Petro-Chemie eignen, wird im folgenden untersucht, ob sich nicht billige kohlenoxydhaltige Abgase für die Kohlenwasserstoff - Synthese eignen. Hierfür kommen die kohlenoxyd-reichen Abgase aus der Carbid-Erzeugung mit bis zu 90% CO und die kohlenoxyd-armen Gichtgase der Eisenverhüttung mit 30 bis 35% CO in Frage.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 194
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 520-530 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Druckverlust und Rektifizierwirkung wurden in Abhängigkeit von der Flüssigkeitsbelastung bei 13 verschiedenen Füllkorperarten in einer Füllkörpersäule von 37 mm Dmr. und 1 m Packungshöhe gemesen. Als Testgemisch diente n-Heptan/Methylcyclohexan. Die Druckverlust- und die Rektifizierkurven, aufgetragen über dem Flüssigkeitsstrom, zeigen bei denselben Flüssigkeitsbelastungen Knickpunkte, woraus sich ein logarithmisches Geradliniengesetz zwischen der theoretischen Bodenzahl und dem Druckverlust ergibt.
    Zusätzliches Material: 16 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 195
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 530-535 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Eine Apparatur zur Messung der Gaslöslichkeit in Flüssigkeiten bei Drucken von 0,1 bis 760 Torr und Temperaturen von 0 bis 200° C wird beschrieben, in der während der Gasbeladung die Rotationsschwingungsspektren ultrarot-aktiver Gase aufgenommen werden können. Die Henryschen Konstanten und Ostwald-Koeffizienten von Wasserstoff, Stickstoff, Sauerstoff, Kohlenoxyd, Kohlendioxyd und Kohlenoxysulfid in Paraffinöl und höheren Alkoholen werden angegeben. Die Lösungsenthalpien von Stickstoff und Kohlendioxyd werden unter Berücksichtigung einer von Burrows entwickelten Theorie berechnet.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 196
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 550-550 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 197
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 553-556 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 198
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 29 (1957), S. 557-562 
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Über den Stand und die Probleme der Titanmetallurgie wird zusammenfassend berichtet.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 199
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Absicht der Arbeit ist es, zu zeigen, daß man zu neuen konstruktiven Lösungen selbst bekannter Aufgaben gelangen kann, wenn man vom physikalischen Geschehen in den verfahrenstechnischen Apparaten ausgeht. Diese Richtung wird in allen Ländern bei solchen Neuentwicklungen verfolgt, deren hohe Kosten zu einer Rationalisierung der konstruktiven Arbeit Anlaß geben. Die Rationalisierung besteht einmal in der wissenschaftlichen Ordnung aller zu beachtenden Gesichtspunkte, zum anderen darin, daß man die konstruktive, vom physikalischen Effekt ausgehend, sucht. Das methodische Denken bereitet das Konstruieren vor, das stets eine schöpferische Leistung bleiben wird.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 200
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Industrial Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Grundlegend für die Kennzeichnung körniger Stoffe sind die Häufigkeits- bzw. die Rückstandssummen-verteilungen der Teilchengröße. Die zur Bestimmung dieser Werte entwickelten Analysenverfahren beruhen jeweils auf einer bestimmten physikalischen Gesetzmäßigkeit. Dieser überlagern sich jedoch Einflußgrößen, die im wesentlichen von der Art und Durchführung der Analysen abhängen. Hierdurch ergeben sich unterschiedliche Ergebnisse. So wird gezeigt, daß die Güte der Prüfsiebung besonders für feine Körnungen in hohem Maße von der Arbeitsweise der Siebmaschinen abhängt. - Durch das Geschwindigkeitsprofil in den Sichterrohren nach Gonell müssen für die Bestimmung der Trennkorngrößen von der Sichtdauer abhängende Geschwindigkeitswerte gewählt werden. Diese Analyse liefert im Vergleich zur Sedimentation, deren Ergebnisse von der Konzentration der Suspension beeinflußl werden, wegen nicht vollständiger Dispergierung der Teilchen oft zu grobe Körnungen. - Die Eichwerte des Bahco-Sichters lassen sich auf andere Kornformen nur beschränkt übertragen. - Der Blaine-Test auf Grund der Kozeny-Gleichung liefert keine Maßzahl für die Oberfläche.
    Zusätzliches Material: 19 Ill.
    Materialart: Digitale Medien
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