ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Hydrolysis of the trans and exo-cis forms of 3,5-dibromo-tricyclo[2,2,2,02,6]-octane, 6 and 7 respectively, proceeds at an enhanced rate and leads exclusively to tricyclo[2,2,2,0]2,6]octane-3,5-endo-cis-diol (diol B, 31). In the presence of acid, ca 70% of this kinetically controlled product is converted into five isomeric diols, viz. bicyclo[3,2,l]oct76-ene-2, 8-exo-diol (diol A, 25), bicyclo[2,2,2]oct-5-ene-2,3-trans-diol (diol C, 29), bicyclo[3,2,l]oct-6-ene-2-exo-8-endo-diol (diol D, 27), tricyclo-[2,2,2,02,6]octane-3, 5-trans-diol (diol E, 33) and tricyclo[2,2,2,02,6]octane-3, 5-exo-cis-diol (diol F, 32).
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19630460640
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