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  • 1970-1974  (1,049)
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  • 201
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 679-686 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The equations for multistage countercurrent operations are difference equations of the boundary-value type, which are generally solved by trial and error or iterative procedures. The invariant imbedding concept is used to solve these boundary-value problems as initial-value problems. It is shown that by the combined use of invariant imbedding and iterative linearization, a sequence of estimator equations for the missing terminal conditions is obtained. These estimator equations can be used to obtain the desired terminal conditions and the number of stages required to perform a specified separation.
    Additional Material: 2 Ill.
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  • 202
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 203
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 712-717 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The equations of motion and energy are solved numerically for fully developed laminar flow of a power law fluid in a vertical pipe with constant heat flux at the wall. Density is assumed to be the only temperature dependent physical property of the fluid. Temperature profiles, velocity profiles, and Nusselt numbers are presented as functions of the power law exponent and the ratio of the Grashof number divided by the Reynolds number.
    Additional Material: 9 Ill.
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  • 204
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 729-732 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Surface renewal models based on wave induced drift currents are proposed to explain gas absorption data in deep tanks. A model assuming plug surface flow was found to best represent the available data for the absorption of carbon dioxide, oxygen, propylene, and helium into water. Velocities obtained by fitting the mass transfer data agree with experimental velocities obtained from dye studies.
    Additional Material: 2 Ill.
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  • 205
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 749-754 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model of a through-circulation packed bed dryer is presented in this paper. The semitheoretical model treats the case of constant rate drying in a deep bed of granular solids under initially uniform drying conditions. Experimental data for drying in superheated steam, mixtures of superheated steam and air, and air alone showed good agreement with predictions of the model.Based on the model, a static optimization method is developed for optimal operation of a continuous through-circulation dryer subject to the inequality constraints of maximum permissible air-horsepower per unit bed area and maximum permissible local final moisture content in the bed. A nonlinear capacity function is defined in terms of the independent drying variables and is maximized under the above nonlinear restraints.
    Additional Material: 5 Ill.
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  • 206
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1100-1102 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
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  • 207
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1034-1038 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Chromatographic techniques are used with nonadsorbable and slightly adsorbable tracers to evaluate mass transfer parameters in packed beds. If accurate values of intraparticle diffusivities are to be obtained, it appears that long beds of relatively large particles must be used. Otherwise the moments of the chromatographic peaks are too small for accurate analysis. With adsorbable gases, such precautions are not necessary, and, in addition, the adsorption rate constant can be estimated. However, the intraparticle diffusivity determined for adsorbable gases can include a contribution due to surface migration. The method is applicable to all types of porous particles used as catalysts or catalyst carriers.A combination of measurements of slightly adsorbable and nonabsorbable tracers can be used to approximate the adsorption rate constant for a slightly adsorbable gas such as nitrogen.
    Additional Material: 5 Ill.
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  • 208
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 848-856 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Solid-fluid reactions often involve two or more simultaneous reactions because either the feed contains multiple fluid reactants or the fluid products are reactive with the solid. Three types of simultaneous reactions, independent, parallel, and consecutive, are examined in terms of the selectivity and the effectiveness factor based on the unreacted core shrinking model under isothermal conditions. Criteria for high selectivities are derived, and effects of diffusion and chemical reaction are discussed.
    Additional Material: 8 Ill.
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  • 209
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 857-867 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The evaporation of pure liquid drops and the drying of drops containing suspended and dissolved solids in an atmosphere of superheated vapor were studied. Changes in the weight and temperature of approximately 2 μliter drops of four food products, five miscellaneous materials, and pure water were measured as evaporation and drying proceeded at different drying temperatures. Evaporation of water was found to take place more slowly in superheated steam than in air. However, the medium, in which faster drying occurred, depended upon the material being dried. No major differences between the final products were observed for these two drying media except that some materials yielded denser particles in superheated steam than in air.
    Additional Material: 12 Ill.
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  • 210
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 889-890 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Tab.
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  • 211
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1106-1107 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 212
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 897-902 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Optimal control of concurrent nonlinear tubular reactors for complex reaction system is studied. The jacket side temperature is allowed to vary along the reactor length and with time. The optimal control possesses feedforward component only, and the nonlinear gain may be precomputed. For a Denbigh type of reaction system, if the heat generation is negligible, the control temperature is insensitive to feed concentration variations. With heat generation effect present, the optimal control is time dependent, and the nonlinear feedforward gain is obtained. The gain may be approximated by a linear function to construct a simple linear feedforward control loop which contains a synchronized time delay.
    Additional Material: 6 Ill.
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  • 213
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 916-924 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The time optimal control problem for jacket cooled continuous flow stirred tank reactor (CSTR) with an exothermic, irreversible, second-order, homogeneous, liquid-phase reaction (the saponification of ethyl acetate) was solved with the maximum principle and phase plane analysis. Both experimental studies and analogue computer simulation studies were conducted.The overall performance of the experimental system agreed very well with the performance of the corresponding system simulated on an analogue computer. However, there were enough differences in the observed and predicted operating states and switching curves to warrant the conclusion that the experimental performance can be significantly improved if experimental results are used to modify the results predicted with computer analysis. These differences were attributed to uncertainties in the model and the values of the model parameters as well as nonrandom (and unforeseen) measurement errors.
    Additional Material: 17 Ill.
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  • 214
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 157-157 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 215
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 37-43 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements of the total viscosity and total conductivity were made as a function of position and Reynolds number for the flow of air between two parallel plates with a separation of approximately 0.7 in. The temperature of the upper plate was 130.0°F. and that of the lower plate 70.0°F. The investigations were carried out at Reynolds numbers from 40,000 to 100,000 and were in good agreement with earlier data obtained at Reynolds numbers up to 40,000. The results obtained indicate little change in the total Prandtl number with increasing Reynolds number from the value of the molecular Prandtl number.
    Additional Material: 8 Ill.
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  • 216
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    AIChE Journal 16 (1970), S. 300-304 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The relationship between μ*ξ and TR for nonpolar gases at normal pressures is used to predict the viscosity for their mixtures. For such mixtures, pseudocritical temperatures are used to obtain TR. To establish ξm for a mixture, a binary interaction model has been applied that utilizes composition and the ξ values of the pure components.Viscosities have been calculated for twenty binary systems which include helium and hydrogen. These calculated values produce an average deviation of 1.97% for 148 compositions. This method was also applied to the helium-neon-argon ternary system at 100°C. to obtain for four mixtures examined an average deviation of 2.2%.
    Additional Material: 6 Ill.
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  • 217
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 314-316 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 218
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    AIChE Journal 16 (1970), S. 326-329 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 219
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    AIChE Journal 16 (1970), S. 509-510 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 220
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    AIChE Journal 16 (1970), S. 353-355 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The permeation of polyethylene film by carbon dioxide, ethane, and propane at elevated pressures was investigated. In addition, the separation of mixtues of ethane and propane by permeation was studied.Both hydrocarbon vapors' permeation exhibited pressure dependence, with propane showing the greatest variation over the same range.In the case of the mixture separation study, the achieved degree of separation was lower than would be predicted on the basis of the pure component permeation constants. Moreover, the total flow of vapor through the film was greater than would be expected on the basis of the individual gas flows. This was attributed to an anomalous diffusion phenomenon of ethane in the presence of dissolved propane due to a plasticization of the polymer network.
    Additional Material: 3 Ill.
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  • 221
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 222
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    AIChE Journal 16 (1970), S. 345-352 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the context of a previously proposed new description for multiphase flow through porous media, we examine constitutive equations for gi, the force per unit volume which phase i exerts upon the pore walls and other adjacent fluids. The principle of material difference is used to determine the most general dependence of gi upon saturation gradient for a nonoriented (no porosity gradient) permeable structure.Three problems are solved and the results compared with analyses based upon our interpretation of Muskat's equations. The first concerns a semi-infinite porous column in air, the bottom of which is saturated with a liquid. The same saturation distribution is found with our approach as with Muskat's equations.The analysis of the second problem indicates the relation between our relative permeability and that of Muskat.The jump balances for mass and for momentum at a surface of discontinuity (or shock wave) with respect to volume averaged variables are derived. The significance of solutions in which such surfaces of discontinuity appear is discussed.In the third problem, a plane surface of discontinuity with respect to local saturation moves through an infinite permeable structure. This is similar to the displacement of oil by an aqueous solution in a secondary recovery process. The results are comparable to those with Muskat's equations only in the limit where capillary pressure is neglected (the Buckley-Leverett case). When capillary pressure differs from zero, Muskat's equations do not admit a shock wave solution.
    Additional Material: 1 Ill.
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  • 223
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    AIChE Journal 16 (1970), S. 359-363 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The light intensity distribution in a perfectly mixed photoreactor has been studied experimentally and analytically. Experimental measurements of intensities within the reactor were made with a specially designed light probe. These data were then used to test the validity of a model which treats the ultraviolet lamp as a linear source radiating in all directions. It was found that this model, which seems appropriate and allows reasonable computations, is somewhat in error owing to the neglect of the finite size of the lamp and the existence of reflection and refraction effects within the reactor. An empirical correction function was determined for use with the model which then yields predictions in close agreement with experimental data when the reactor is filled with a light absorbing liquid.
    Additional Material: 6 Ill.
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  • 224
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    AIChE Journal 16 (1970), S. 380-385 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid-phase Peclet numbers have been measured for 1/4 in. Raschig rings with countercurrent air flow in a 2 in I.D. column. The response curve has been analyzed by a computer program, since the output data was collected directly on paper tape. The Peclet number calculated from a moments analysis is considered unreliable, and the diffusion model can be rejected for the liquid phase. If the Peclet number is calculated by a least-squares fit, and if the result is forced through the peak in the response curve, then a correlation for over one hundred runs with gas flows from 0 to 99% of flooding is given by Equations (7) and (8).
    Additional Material: 9 Ill.
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  • 225
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    AIChE Journal 16 (1970), S. 397-404 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A kinetic mathematical model of catalytic cracking is described which accounts for conversion and gasoline yield in isothermal fixed, moving, and fluid bed reactors. The model has been tested and verified by using laboratory moving bed data with a commercial gas oil and catalyst. It is shown that under certain conditions, the selectivity behavior and maximum gasoline yield of fixed, fluid, and moving bed reactors will be identical. Maximum gasoline yield is defined in terms of both the kinetic parameters and the process variables for fixed, moving, and fluid bed reactors.
    Additional Material: 11 Ill.
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  • 226
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    AIChE Journal 16 (1970), S. 426-435 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A one-dimensional column is considered in which a number of chemical reactions with arbitrary kinetics may take place among an arbitrary number of components. Initially, the column is in complete chemical and physical equilibrium. A localized small perturbation is introduced in the column at time t = 0. It is shown that, in general, this initial perturbation separates into a definite number of peaks which move with different velocities. Each peak broadens according to an asymptotic relation, depending on a characteristic dispersion coefficient. If n is the number of components, m the number of independent reactions, and σ the number of equations of state to be considered, there are n-m-σ peaks. These peaks do not correspond to single substances as in classical chromatography, but each peak has an eigencomposition. The velocities of the peaks are derived as functions of stoichiometry and equilibrium data. The dispersion coefficients depend, in addition, on the kinetics of the chemical reactions and on the rate of mass transfer. Thus, perturbation chromatography offers a means of determining both equilibrium and rate data. The theory is illustrated by means of two examples.
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  • 227
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    AIChE Journal 16 (1970), S. 211-217 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The stability of a continuous flow stirred tank reactor with consecutive chemical reactions A→B→C was investigated here for the first time. The system equations were integrated numerically, and parts of the three-dimensional phase space were generated for systems having one and three steady states, respectively.The surface separatrix was determined by trajectory plotting after extensive computation. The system was also analyzed by Liapunov's second method. Krasovskii's form was used to generate Liapunov functions which proved to be satisfactory but extremely conservative in the estimation of the largest possible regions of asymptotic stability.
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  • 228
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    AIChE Journal 16 (1970), S. 502-505 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 229
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    AIChE Journal 16 (1970), S. 281-286 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Several studies have been made in Couette systems of the primary motion (angular translation and rotation) of spheres suspended in viscous liquids. Radial migration trajectories, however, have been unreported for single spheres.In this study, a prediction of radial migration is developed and compared with experimental measurements. The predicted trajectories were found to agree well with the measured ones.Ultimately, radially migrating spheres reached an equilibrium position located approximately midway between the cylinder walls. The model developed predicted an equilibrium position just slightly inside the midpoint, while measured equilibrium positions fell between the midpoint and 0.4, the annular thickness from the inner cylinder walls. The differences in equilibrium positions are attributed to the approximate nature of the model.
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  • 230
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    AIChE Journal 16 (1970), S. 317-318 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 231
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    AIChE Journal 16 (1970), S. 325-325 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 232
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    AIChE Journal 16 (1970) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 233
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    AIChE Journal 16 (1970), S. 356-358 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An adiabatic loop reactor was operated at naturally unstable steady states in experiments employing the reaction between sodium thiosulfate and hydrogen peroxide in aqueous solution. The unstable states, the intermediate states in a multiple state regime, were stabilized by manual manipulation of the recycle ratio. Resulting temperature data agreed well with those predicted from a plug-flow model. Observations of the transient response to small disturbances from the intermediate states verified that they were indeed unstable as had previously been predicted theoretically. Cursory attempts to stabilize the system by means of automatic feedback control employing a three-mode controller were unsuccessful.
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  • 234
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    AIChE Journal 16 (1970), S. 670-672 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A basic inequality which is necessary and sufficient for macroscopic stability of lumped dynamical systems is applied to obtain further insight into the construction of stability regions, development of stability and control criteria, and meaning and simplified derivation of some conventional results.
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  • 235
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    AIChE Journal 16 (1970), S. 688-690 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 236
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    AIChE Journal 16 (1970), S. 696-698 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 237
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  • 238
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    AIChE Journal 16 (1970), S. 725-729 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The self-diffusion coefficient of methane has been measured from 150° to 350°K. and from 200 to 5,000 lb./sq. in. abs. At constant temperature, the density-diffusivity product is constant up to neighborhood of critical density and decreases sharply above that density. The temperature dependence of the low density data agrees with Chapman-Enskog theory. The Lennard-Jones (6-12) parameters determined from the low density data (∊/k = 130°K., σ = 3.85Å.) are in good agreement with those determined by other methods. A correlation for the self diffusion coefficient for methane has been developed which may provide predictions of other spherical nonpolar gases.
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  • 239
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    AIChE Journal 16 (1970), S. 691-693 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 240
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    AIChE Journal 16 (1970), S. 698-699 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 241
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    AIChE Journal 16 (1970), S. 802-816 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study was made of spray quenching by high velocity gas atomization. A mathematical model of both high and low temperature spray quenching was developed. Data were taken for proving and validity of the model.Experiments were performed on a vertical downward flow of air-water in a 1.0 in. diameter tube. Injection was by either of two modes. The first was a set of six peripheral liquid jets projecting water perpendicularly into the high velocity airstream. The second mode of liquid injection was by means of a 360° peripheral, annular slot, which laid down a continuous wall film at the point of injection. Air velocities of 430 and 200 ft./sec. and liquid injection rates of from 150 to 1,200 ml./min. were studied. The following physical quantities were measured: liquid fluxes, wall film flow rates, drop size distributions, and median drop size. An attempt was made to measure gas temperature in a dense spray by using two different types of temperature probes, but only liquid temperatures could be detected. A comparison of data with published data and correlations was made.The best quenching conditions obtained were a liquid-to-gas mass ratio of 0.25, a Sauter mean drop diameter of 45 μ, and an indicated characteristic quench time of 10-3 sec.
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  • 242
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    Additional Material: 9 Ill.
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  • 243
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    AIChE Journal 16 (1970), S. 911-916 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A novel feedback control system, called a predictive feedback control system, is developed for the regulation of the exit composition of a continuous flow stirred tank reactor (CFSTR). The control system utilized two basic feedback signals. One is the effluent concentration of the composition to be controlled. This is measured by a batch type of composition analyzer such as a chromatograph. The other is a predictive feedback signal which continuously predicts the difference between the actual value of the controlled variable and the measurement supplied by the analyzer. The predictive signal is generated from a plant model which approximately relates the controlled variable and the continuously measured reactor temperature.Unlike direct feedback control systems, the stability of the predictive system is unaffected by the periodic sampling and time delays introduced by the batch analyzer. Moreover, at steady state the predictive feedback signal disappears, and, like direct feedback systems, predictive feedback systems yield very accurate steady state control.A computer simulation of the predictive feedback control of a particular CFSTR has shown that predictive control is considerably more effective in composition control than conventional direct feedback control, is more effective than conventional temperature control, and retains the advantages of direct feedback control while partially eliminating the undesirable effects caused by the batch analyzer.
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  • 244
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    AIChE Journal 16 (1970), S. 658-669 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental measurements of the temperature response of a fixed bed reactor to sinusoidal disturbances in the feed concentration, temperature, and flow rate show that a simple one-dimensional mathematical model with distributed thermal capacitance satisfactorily describes the dynamic behavior of the reactor for modest excursions about an operating point. The reaction considered is a liquid-phase exothermic reaction whose rate depends on the concentration of two reactants and the temperature.A computational analysis reveals that the amplitude and phase of the traveling concentration and temperature waves are influenced in a complex manner by the interaction between the two waves. The interaction, which is treated here as interference between traveling waves, is made complex by the difference in the rates of propagation of the temperature and concentration waves and by the variation of their speeds throughout the bed.
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  • 245
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    AIChE Journal 16 (1970), S. 1087-1088 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 246
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    AIChE Journal 16 (1970), S. 1092-1092 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 247
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    AIChE Journal 16 (1970), S. 754-761 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A finite difference technique has been developed which is suitable for the derivation of feedforward control algorithms for the control of distributed parameter processes. The method embodies both steady state and transient feedforward compensation.An experimental study, involving closed loop, on line, analogue computer control of a simple distributed parameter process proves the feasibility of the finite difference technique. The process under study is a steam water heat exchanger subject to inlet temperature forcing and controlled by flow rate manipulation. The new technique yielded significantly improved results when compared with the performance of a conventional two-mode feedback controller, or a linearized feedforward control algorithm.
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  • 248
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    AIChE Journal 16 (1970), S. 985-991 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A modified Redlich-Kwong equation of state is developed in which the two parameters are expressed as functions of temperature. The critical values for the two constants in the equation are completely determined by the values of the critical properties of the gas. The optimum values of the constants for each isotherm (Z vs. P) are found, followed by a curve-fitting routine that obtains the constants as functions of temperature. The resulting equation of state predicts experimental helium compressibility data to within an average of 0.90% absolute error for data in the range 0 〈 pressure ≤ 700 atm., 5.26°K. ≤ temperature ≤ 1,500°K. For hydrogen, the prediction is to within an average of 0.79% absolute error for temperatures from 34° to 600°K. and pressures up to 2,900 atm.
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  • 249
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    AIChE Journal 16 (1970), S. 1093-1097 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 250
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    AIChE Journal 16 (1970), S. 1108-1110 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Absract.
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  • 251
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    AIChE Journal 16 (1970), S. 955-963 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Temperature profiles of water in a spray column heat exchanger, 15 cm. in diameter and 150 cm. long, operating with a dense packing of kerosene drops, were measured. The range of superficial velocities was 0 to 0.8 cm./sec. of water and 0.5 to 1.7 cm./sec. of kerosene. The bottom of the dense packing was either slightly above or 15 cm. below the bottom of the column proper.The physical picture of heat transfer is similar to that for dispersed packings of drops and emphasizes the dominant role of wakes in the heat transfer mechanism. The mathematical equations for dispersed packings of drops were modified to take into account the reduction of wake size at the interface of the two packings and the difference in the mixing patterns at the top of the column. An empirical allowance for the effect of bypassing is suggested. The volume of the wakes and the rate of wake shedding were estimated from the temperature profiles. General agreement was found between the theory and the experimental data of this and three other studies.
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  • 252
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    AIChE Journal 16 (1970), S. 9-17 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The flow of brine through the ice bed in gravitational counterwashers is investigated by analytical methods. Two types of counterwashers are considered: a drained-top counterwasher and a flooded one. Only counterwashers of rectangular cross section and two dimensional flows are investigated. By assuming that the ice crystals move vertically upwards with a uniform velocity and that the relative flow of brine and wash water with respect to the ice bed obeys Darcy's law, the differential equations and the boundary conditions of the flow are derived. The solutions are obtained by using complex variables and conformal mapping. The solutions are presented as formulae, which make possible the rational design of counterwashers and the optimization of their dimensions and operation parameters.
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  • 253
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    AIChE Journal 16 (1970), S. 82-90 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical solution for the impingement flow of a jet with a parabolic velocity distribution is given. Viscous generation and diffusion of vorticity in the jet were neglected. Experimental velocity and pressure distributions measured in an impinging jet of air originating with Poiseuille flow compare well with theory, thus justifying the assumption of inviscid flow. Pressure distributions on the deflecting surface were independent of nozzle height in the range 1 to 12 nozzle radii. For lower nozzle heights the effect of the constriction of flow between the nozzle and the surface followed the predicted behavior.
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  • 254
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    AIChE Journal 16 (1970), S. 101-107 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A hemispherical bubble, attached to a plate, is surrounded by an initially quiescent and isothermal liquid. By suddenly heating the plate, a thermal gradient over the bubble surface results. Because surface tension is temperature dependent, tangential stresses arise at the bubble surface. The liquid is viscous, and motion in the liquid phase begins. Such motion is an example of thermocapillary flow. This problem, besides being of interest from a fundamental point of view, is of possible concern in the design of space vehicles capable of storing cryogenic fluids for long periods of time in a weightless condition.Solutions to the problem are developed by numerical treatment of the governing equations. Flow and temperature fields, which depend upon the Prandtl and Marangoni numbers, were obtained for Prandtl numbers 1 and 5 and Marangoni numbers from 0 to 100,000.Results show that liquid is pulled toward the intersection of the bubble and the plate, then flows around the bubble surface, and leaves the bubble as a jet. The extent of the jet increases with increasing Marangoni number and decreases with increasing Prandtl number.Thermocapillary flow increases heat transfer (Nusselt number) over that obtained from conduction, but the increase is modest. The Nusselt number increases with the Marangoni number and is insensitive to the Prandtl number. At a Marangoni number of 40,000, the local Nusselt number was increased by a factor of 2. In order for thermocapillary flow to become a dominant heat transfer mechanism, the Marangoni number must exceed 100,000.
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  • 255
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    AIChE Journal 16 (1970), S. 163-168 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: From studies of turbulence in round jets of Newtonian and non-Newtonian fluids, it has been found that the response of wedge shaped, hot-film probes can be influenced by the structure of the flow. In water and in weakly viscoelastic fluids the probe is little affected by turbulence, but for more highly viscoelastic fluids the rate of heat transfer from the hot film is markedly increased. Increases as great as 37% were found in this work; this corresponds to a 250% increase in apparent velocity. For this reason, care must be taken in interpreting measurements obtained with hot-film wedges (and probably cylinders and cones also) in flows with both laminar and turbulent regimes.
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  • 256
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    AIChE Journal 16 (1970), S. 185-193 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of various soluble and insoluble surface active agents on the absorption of ammonia into a static aqueous system was studied. Saturated straight-chain hydrocarbons with four to twenty-two carbon atoms and polar end groups were selected as the surface active agents to be studied. Alcohol, amine, and amide end groups were investigated. Most of the insoluble surface active agents, which were studied as films, were found to decrease the ammonia absorption rate. There was a definite correlation between the amount of mass transfer reduction and the hydrocarbon chain length, while the effect of the various end groups appeared to depend on the chain length. Surface mass transfer coefficients were computed for each surface active agent that retarded mass transfer. Most of the soluble surface active agents were found to increase the ammonia absorption rates. For all cases of enhanced mass transfer, movements in the interface could be observed. It was concluded that the interfacial movements were caused by the Marangoni effect. In general, as the chain length of the surface active agent decreased, the mass transfer enhancement increased. A mathematical model based on a surface renewal theory was fitted to the experimental data.
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  • 257
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    AIChE Journal 16 (1970), S. 204-211 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The laminar boundary-layer equations are solved asymptotically for simultaneous mass and energy transfer in a variable property binary gas mixture when one component is rapidly transferred toward the surface. Flow is past a surface of arbitrary geometry, and both forced and free convection are studied. Advantage is taken of a mole fraction formulation of the boundary-layer equations, which considerably simplifies the final results. General results are obtained for energy and mass transfer rates when physical properties are arbitrary functions of both temperature and composition. By considering two sets of property variations, representing extremes between which many actual variations lie, it is shown that in many forced convection problems the rates of energy and mass transfer can be expressed in a particularly simple form. The results also show that property variations are generally more important for free convection than for forced convection.
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  • 258
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    AIChE Journal 16 (1970) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 259
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    AIChE Journal 16 (1970), S. 198-203 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper presents a quantitative study of two types of decoupling elements to achieve non-interacting feedback control of overhead and bottoms compositions in binary distillation. Ideal decoupling, where the closed loop response of each loop is the same as it would be if the other loop were on manual control, and simplified decoupling, where two interaction compensators are used to isolate each loop, are investigated.The decoupling elements themselves are physically realizable in both cases, but unstable loops develop with ideal decoupling in higher purity columns because of increased positive feedback. Simplified decoupling gave effective, stable, noninteracting loops for all the cases studied.The decoupling elements are designed in the frequency domain from a linear model of the column, and their effectiveness is tested by digital simulation of the nonlinear column model.
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  • 260
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    AIChE Journal 16 (1970), S. 218-223 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simple model for describing residence time distributions (RTD) in packed beds is derived and applied to a trickle flow system. It is based on the concept of fluid elements being randomly delayed in time on their passage through the bed and leads to a simple and flexible mathematical description.
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  • 261
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    AIChE Journal 16 (1970), S. 261-267 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The viscosity of concentrated solutions of polystyrene were measured in steady shearing flow with a Weissenberg rheogoniometer. The polymers ranged in weight average molecular weight M̄w from 97,000 to 3,370,000 and in distribution breadth M̄w/M̄n from 1.05 to 3.1. The solvent was n-butylbenzene, and the solutions ranged in concentration from 0.20 to 0.55 g./cc. These data were supplemented by measurements on bulk polystyrenes and polyethylenes with distribution breadths as high as M̄w/M̄n = 20. Master curves of reduced viscosity vs. reduced shear rate were calculated theoretically for each molecular weight distribution. The experimental viscosity data superimposed satisfactorily on these curves and furnished the viscosity at zero shear rate τ0 and an experimental time constant τ0 for each solution. The time constant paralleled closely the Rouse relaxation time τR in all systems. Residual variations in the ratio τ0/τR with molecular weight and concentration correlated uniquely with the product cM̄w. These results indicate that the viscosity behavior of a polymer can be predicted with reasonable accuracy from data on its molecular weight distribution.
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    AIChE Journal 16 (1970), S. 273-280 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Combined reactors in which the mixed reactor is followed by a tubular reactor can be optimal for a large number of simple adiabatic exothermal reactions. In the present paper, optimality criteria defined earlier for simple reactions involving a single reactant species have been extended to reactions involving two reactant species and for a system of consecutive reactions.The oxidation of benzone has been studied in an adiabatic semifluidized mixed tubular (MT) reactor. A definite improvement is possible when the oxidation is carried out in this reactor, as observed by a comparison of the experimental results obtained in tubular, mixed, and MT reactors under adiabatic conditions.
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  • 263
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    AIChE Journal 16 (1970), S. 410-419 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Steady state and transient characteristics of an adiabatic, continuous flow, stirred reactor were studied in experiments employing the exothermic reaction between sodium thiosulfate and hydrogen peroxide in aqueous solution. Results illustrate the multiplicity of steady states in this system over a range of residence times. Temperatures of unstable states were attained experimentally by observing the effect of perturbations from stable temperatures. The observed steady states of the reactor under various mixing conditions are shown to be in good agreement with the predictions of a mathematical model which is based on the assumptions that mixing is perfect and that a single independent chemical reaction occurs. Less exact quantitative agreement between theoretical and experimental unsteady performance is accounted for in terms of the sensitivity of the unsteady state to small errors in the system parameters and the existence of appreciable extraneous heat capacities of the experimental equipment.
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  • 264
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    AIChE Journal 16 (1970), S. 441-445 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A modification is presented of the Kb method described by Holland. This modified procedure exhibits substantially improved convergence characteristics when compared with the unmodified procedure or with the classical bubble point approach. Further, it provides by far the fastest algorithm known to the author. A second procedure for determining stage temperatures is also given. In this method, flow equations as well as equilibrium relations are satisfied by the temperature profile at each iteration. Next, an improved scheme for handling nonideal mixtures is given. Finally, it is shown that a positive solution to the convergence acceleration equations of Holland may not exist when this procedure is applied to a purity specification.
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  • 265
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    AIChE Journal 16 (1970), S. 229-232 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper presents a new, general method for mathematical simulation of equilibrium stage operations. The procedure solves component material balance equations with a tridiagonal matrix algorithm. Heat balances and summation equations are handled with Broyden's method. The unique feature of this procedure is that, in a mathematical sense, all equations are solved simultaneously. Therefore, the method can be used for all types of equilibrium stage processes. Additionally, the use of Broyden iteration insures solutions which are both stable and more rapid than current techniques. An exact solution for a twenty tray column with twenty components takes approximately 30 sec. on an IBM 360/65 computer. Successful simulations have been made for both absorption and distillation type of operations which have included complex columns with multiple feeds and side product streams. Design applications of the method cover a variety of equilibrium stage processes in the chemical and petroleum industries.
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    AIChE Journal 16 (1970), S. 254-260 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental study was made on the breakup of a single drop in two phase liquid-liquid developing turbulent pipe flow. The predominant breakup mechanism was controlled by dynamic pressure forces, and the drop breakup was characterized by one or two smaller drops breaking off a larger drop.The effect on the increase in interfacial area and the resulting size distribution of the fragmented drops of drop velocity, interfacial tension, initial drop size, and the distance down the pipe was studied. Regression analysis was used to determine the significant effects. Most of these regression equations had significant cubic and two-factor interactions, which is indicative of the complexity of drop breakup.The size distribution of the fragmented drops can be approximated by a normal distribution. However, the steady state distribution was not fully developed in the work here.
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    AIChE Journal 16 (1970), S. 520-527 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Temperature and velocity measurements were carried out at the center of the test section of an 8-in. I.D. cylindrical graphite chamber in a confined nitrogen jet issuing from a 40-kw. D.C. plasma torch. The test section was located 10.5 in. below the torch nozzle, and temperatures and velocities up to 4,300°F. and 120 ft./sec. were obtained.The overall rates of heat transfer by forced convection were measured to water cooled circular and square cylinders in two orientations. Results indicated that, owing to the high level of turbulence of the jet, turbulent boundary layers prevailed in the low range of Reynolds numbers investigated. Correlations are presented in terms of the Nusselt, Reynolds, and Prandtl numbers, with the physical properties of the gas evaluated at the bulk temperature.
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  • 268
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    AIChE Journal 16 (1970), S. 538-541 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Predictive equations for terminal velocities of liquid drops in Newtonian and non-Newtonian systems are reviewed. The wave theory analogy is extended to include liquid-liquid systems. Experimental data obtained with seven different systems are presented. The agreement with predictive equations is satisfactory. Interface rigidity was observed in all the systems investigated.
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  • 269
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    AIChE Journal 16 (1970), S. 569-574 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Approximate expressions of velocity profile and drag coefficients have been obtained for viscous incompressible non-Newtonian flow over a fluid sphere in the intermediate Reynolds number range.The equations of motion of both external and internal fluids are satisfied by using Galerkin's method. The internal fluid is assumed to be Newtonian, while the external is assumed to be non-Newtonian and can be described by the power law model. Furthermore, the condition that the tangential stress is transmitted across the fluid-fluid interface without diminution is also satisfied with Galerkin's condition.Comparisons are also made between the predicted results and the experimental data available in the literature. The possible reasons for the discrepancy are also discussed.
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  • 270
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    AIChE Journal 16 (1970), S. 594-601 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Linear perturbation analyses are extended to determine the lowest Rayleigh number at which convection initiates in a vertical cylinder heated on the bottom and cooled on the top. The critical Rayleigh number for the first mode of convection in a right circular cylinder with a perfectly conducting wall is shown to be three times larger than that in such a cell with a perfectly adiabatic side wall. An adjusted wave number is shown to make the results of Pellew and Southwell applicable to the adiabatic wall in a manner similar to that used by Pnueli and Ostrach for the perfectly conducting side wall. The results are compared with experiment and are in very good agreement.
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  • 271
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    AIChE Journal 16 (1970), S. 392-396 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Particle collection efficiency and gas pressure drop for venturi and other atomizing scrubbers can be predicted by means of equations developed in this paper. The significance of the details of the liquid atomization process, the collection of particles on single drops, and the uncertainty regarding them are discussed. The role of drop holdup in the scrubber throat is also important.
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  • 272
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    AIChE Journal 16 (1970), S. 420-425 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Thermodynamic properties of the chemically reactive system N2O4 ⇌ 2NO2 ⇌ 2NO + O2 have been evaluated over a pressure range of 0.005 to 200.0 atm. and a temperature range of 200° to 900°K. by making use of Lennard-Jones potential. In these calculations, the dissociation of nitrogen tetroxide to nitrogen dioxide, nitric oxide and oxygen, and the effect of pressure on the equilibrium constants for the system of reactions N2O4 ⇌ 2NO2 and 2NO2 ⇌ 2NO + O2 have been taken into account.
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  • 273
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    AIChE Journal 16 (1970), S. 673-678 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Methods are described for predicting the dynamic behavior of high purity fractionators. The paper shows how to model both the composition and hydraulic response in towers with many trays and in towers which are subject to a variety of disturbances. The technique involves the transformation of the linear dynamic equations to the frequency domain and the solution of the resulting complex algebraic equations for specific values of frequency. The paper includes a description of the model formulation, solution, and validation, and applications including the design of feedforward controllers.
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  • 274
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    AIChE Journal 16 (1970), S. 742-748 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By using curve fitting techniques, mathematical formulas are obtained for the catalyst effectiveness factors for nonisothermal first-order and second-order irreversible chemical reactions. The effects of intraparticle mass and heat diffusion upon the concentration and temperature profiles in adiabatic and nonadiabatic catalytic reactors are examined. A relation between the maximum interstitial adiabatic temperature and the maximum intraparticle temperature in the reactor is obtained. For some sets of parameters in a nonadiabatic reactor, the concentration and temperature and, consequently, the reactor effluent are sensitive to small changes in the properties of catalyst particles.
    Additional Material: 10 Ill.
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  • 275
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    AIChE Journal 16 (1970), S. 705-711 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The objective of the present study was to obtain data on the rate of liquid-phase controlled mass transfer in two-phase gas-liquid flow in horizontal pipes. Studies were made on the effect of the mean gas and liquid flow rate, pipe diameter, and pipe orientation on kla, the mean liquid-phase film mass transfer coefficient. Experimental studies were made on 1 and 4 in. I.D. horizontal pipelines; on 4 in. I.D. 180 deg. vertical short radius bend (H/D = 2); and on 3/16, 5/16, and 7/16 in I.D. tubes wound in 4-in. diameter spirals (upflow). A general correlation is presented for kla as a function of the two-phase frictional energy dissipation, liquid-phase physical properties, and pipe diameter.
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  • 276
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    AIChE Journal 16 (1970), S. 733-738 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Low temperature, phase-equilibria data for binary systems containing hydrogen, helium, and neon were used to develop a correlation relating deviations from the geometric mean combining rule for the characteristic energy parameter to the ionization potentials of the component species. With the exception of oxygen systems, this relatively simple relationship correctly predicts published deviations, determined by different methods, for a number of systems within expected uncertainties. It is shown that consideration of attractive forces only, as done by Hudson and McCoubrey, is inadequate for such predictions.
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  • 277
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    AIChE Journal 16 (1970), S. 738-741 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Compressibility measurements of the gas phase are reported for the compounds n-C6F14, 2-CF3C5F11, 3-CF3C5F11, 2,3-(CF3)2C4F8, and cyclo C6F12. The measurements range from 1 to 18 atm. pressure and from 80° to 180°C. Second and third virial coefficients and critical properties have been calculated and are reported.
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  • 278
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    AIChE Journal 16 (1970), S. 542-553 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Significant error can result when the plug flow model is applied to the analysis or design of luminar flow reactors due to nonconstant radial profiles of velocity, composition, and temperature.An analysis and comparison of suitable models for the nonisothermal, homogeneous, first-order, irreversible, laminar, gas flow reactor has shown the finite-difference solution for radial profiles to be superior to the power-series approximation of radial temperature and composition profiles.New capabilities of the present computer solution include isothermal or adiabatic wall, dilute or concentrated feed, any stoichiometric product-to-reactant ratio. Chapman-Enskog model for gas diffusivity, calculation of both heat transfer parameters, and a correction factor to apply to plug flow calculations.The new, improved computer solution may be used in the basic design or analysis of tubular, laminar flow reactors.
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    AIChE Journal 16 (1970), S. 580-587 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method of calculating the critical properties of binary hydrocarbon systems is presented which is based upon the rigorous thermodynamic equations for the critical point of a binary mixture. By using these equations together with an equation of state, a completely analytical procedure was developed with the aid of a digital computer. The Redlich-Kwong and the Dieterici equations of state were chosen for study. The Redlich-Kwong equation was found superior for predicting critical pressures and temperatures by this method, although the Dieterici equation was better for critical volumes. The two interaction parameters arising from the equation of state were calculated from combining rules or from available experimental critical data on binary systems. To facilitate the latter approach, a mathematical optimization routine was used to find the best values of the interaction parameters for twenty-one binary hydrocarbon systems for which critical data were experimentally determined. The optimum values of the interaction parameters were correlated as functions of the ratio of molecular weights of the components. These correlations enable one to predict quite precisely the critical properties of the binary systems from the pure component data alone.
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  • 280
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    AIChE Journal 16 (1970), S. 614-619 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The transport equations for the region exterior to a cylindrical jet issuing continuously from an orifice are solved through the introduction of a similarity transform. The possibility of mass transfer normal to the jet is allowed. Of particular interest are the local transport coefficients (Cf, NNu, NSh) and their dependence on the rate of transfer from the jet.
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    AIChE Journal 16 (1970), S. 609-614 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study of the feasibility of using ion exchange resin systems for carbon dioxide absorption from gas streams was completed with the conclusion that such a system could compete very successfully with atmospheric control systems now in use. A detailed study of such a system based on polyethylenimine showed that this material is superior to any of the commercially available weak base resins tested. The kinetic data obtained correlated very well when a model was postulated that was based on diffusive transfer through a gas film, a water film, and the resin particle in series, with diffusion with the resin particle as the rate determining step.
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  • 282
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    AIChE Journal 16 (1970), S. 639-644 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The quasilinearization technique is used to overcome the dimensionality difficulty in dynamic programming. The advantage of this approach is that not only the dimensionality or the fast memory requirement can be reduced, but the computation time required can also be reduced considerably. A technique is also devised to overcome the linearity difficulty encountered in this reduction in dimensionality. To illustrate the approach, the three dimensional crosscurrent extraction problem is solved as a one- and a two-dimensional problem in the dynamic programming algorithm. Only approximately 1 min. is required to solve this one-dimensional problem. However, if this problem were solved as a three-dimensional problem, computation time of the order of hours would be required.
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    AIChE Journal 16 (1970), S. 949-954 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The physical adsorption isotherms for three methane-helium mixtures, two nitrogen-helium mixtures, and one methane-nitrogen-helium mixture were measured at 76°K. and pressures of 2 to 65 atm. on a coconut shell charcoal. The adsorption isotherms of the pure components (nitrogen, methane, and helium) were also determined over the appropriate pressure ranges.Methods for predicting the mixture adsorption isotherms by using only the pure component isotherms are discussed and are shown to be adequate for these systems.The concentration vs. time or breakthrough curves were also measured for both the binary and ternary mixtures at a number of different flow rates. Mass transfer coefficients for both the gas phase and the absorbed phase were obtained from these breakthrough curves.
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  • 284
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    AIChE Journal 16 (1970), S. 972-978 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The unsteady state behavior of a tubular heterogeneous catalytic reactor, in which significant adsorption effects occur, has been investigated theoretically and experimentally. Transient responses of conversion to step increases and decreases of flow rate as well as to periodic variations in flow rate are considered. A simplified procedure for anticipating gross effects in cyclic processes is suggested.
    Additional Material: 8 Ill.
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  • 285
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    AIChE Journal 16 (1970), S. 907-910 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A parallel plate rheometer has been devised which permits measurements of shear stresses of 102 to 105 dynes/sq.cm. and shear rates of 10-5 to 1 sec.-1. A linear, air lubricated bearing is used to align the apparatus, and a linear variable differential transformer is used to sense changes in position. With a sample of polyisobutylene and with several samples of poly(dimethyl siloxane), it has been established that a Hookean range exists for each sample at low stresses. Hooke's law in shear states that the modulus is independent of stress, where the modulus is defined as the ratio of the shear stress in steady, creeping flow to the strain which can be recovered after the stress is removed. Other conclusions supported by the present work are that the Hookean range does not extend to stresses which are high enough to cause non-Newtonian flow, that the modulus decreases with increasing molecular weight although not in direct proportion, and that a sample with a broad molecular weight distribution has a lower modulus than one with a narrow distribution.
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  • 286
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    AIChE Journal 16 (1970), S. 930-942 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Microconductivity probes were used for the measurement of point values of mean concentrations and root-mean-square concentration fluctuations for mixing of salt solutions in turbulent shear flows. Mixing studies covered a range of flow conditions, with Reynolds numbers on the order of 104, and included ducted turbulent jets, dispersion in turbulent pipe flow, a plane mixing zone, and several multiple injection systems. The test sections all had characteristic dimensions of about 2 cm. The results for mixing experiments are compared with available previous work. Lack of resolution for root-mean-square concentration fluctuations in some previous work is indicated.Reaction product concentrations for a rapid, second-order, irreversible reaction in multiple injection systems, the plane jet, and the mixing zone were also obtained. The relation between conversion in reaction experiments and fluctuation level and decay in the equivalent mixing experiments is illustrated.
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  • 287
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    AIChE Journal 16 (1970), S. 964-966 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pressure losses at the sharp edged entrance to a cylindrical tube were investigated for glycerine-water solutions over a Reynolds number range of 6 to 2,000.For the experimental area contraction ratio of 0.0156, the Hagenbach (K) and Couette (K') coefficients are 2.4 and 295, respectively. Comparison with limited previous work shows that both coefficients increase with the area contraction ratio β over range 0〈β〈0.162.
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  • 288
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    AIChE Journal 16 (1970), S. 1072-1080 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Drop-size distributions in turbulently flowing dispersion of immiscible liquids were investigated. The observed drop-size distributions were actually a composite of two superimposed distributions. One is the distribution produced by the injection nozzle and the other is that produced by breakup in the turbulent flow field. A mathematical model was developed which predicted both the shape of the observed distributions and kinetics of the droplet breakup process for the distribution produced by the turbulent flow field.The flowing dispersion composed of water and insoluble organic phase was photographed at 27, 209, 421, and 576 pipe diameters below the mixing jet and at distances of 0.05, 0.1, and 0.4 diam. from the wall. Average flow rates varied from 14 to 20 ft./sec. in the 0.750-in. I.D. tube. Three organic phases were studied at concentrations ranging from 0.6 to 10% by volume. Dispersed phase viscosity and interfacial tension varied from 1 to 18 cp. and 13 to 40 dynes/cm.No distribution law with any theoretical basis could be found which correlated experimental distributions.The stochastic model describing the breakup process postulates that each breakup event leads to two daughter drops with uniformly distributed volume ratios and a very small satellite droplet. An empirical correlation exists to predict only one of the three parameters of the model.
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    AIChE Journal 16 (1970), S. 1098-1100 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 290
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    Journal für Praktische Chemie/Chemiker-Zeitung 312 (1970), S. 935-946 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Für die 13C-NMR-chemischen Verschiebungen einer größeren Zahl von C-1-substituierten Alkanen CnH2n+1X(n = 1-8, X = COOH, OH, Cl, Br, J) sowie in 2-, 3- oder 4-Stellung monosubstituierten Octanen C8H17X (X = OH, Cl, Br) wird ein additives Inkrementsystem angegeben, das es gestattet, die experimentellen Werte mit guter Genauigkeit vorauszuberechnen. Mit Hilfe dieses Systems, das prinzipiell auf beliebige Gruppen substituierter Alkane erweitert werden kann, wurden insgesamt 358 Verschiebungswerte berechnet, die Abweichung vom experimentellen Wert beträgt in etwa 80% der Fälle weniger als 1 ppm. Die Bedeutung eines solchen Inkrementsystems für die Anwendung der 13C-NMR-Spektroskopie für die Kohlenwasserstoffanalytik und mögliche Aussagen über die Struktur der untersuchten Verbindungen werden diskutiert.
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  • 291
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    Journal für Praktische Chemie/Chemiker-Zeitung 312 (1970), S. 1058-1062 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das bisher unbekannte Thiacyclooctanon-(3) 5 ist durch Ringschluß von 1, 7-Dibromheptanon-(2) mit Natriumhydrogensulfid und durch DIECKMANN-Cyclisierung von 3-Thiaazelainsäurediäthylester unter Hochverdünnungsbedingungen zugänglich. Die UV-, die IR-und die Massenspektren der auf beiden Wegen erhaltenen Ketone sind identisch und bestätigen die Struktur.
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  • 292
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    Journal für Praktische Chemie/Chemiker-Zeitung 312 (1970), S. 1105-1111 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch eine modifizierte PFITZINGER-Reaktion wurden 3,3′-überbrückte 2,2′-Dicinchoninsäuren dargestellt und ihre pKs-Werte sowie Stabilitätskonstanten von Kupferkomplexen auf potentiometrischem Wege bestimmt. Die Alkalisalze der 3,3′-Dimethylen-2,2′-dicinchoninsäure bilden wasserlösliche violette Kupfer(I)-Komplexe, die eine photometrische Kupferbestimmung ermöglichen. Eine Methode zur Kupferanalyse in Stahl wird beschrieben. Bei starkem Erhitzen geht 3,3′-Dimethylen-2,2′-dicinchoninsäure in 2,3,8,9-Dibenzo-1,10-phenanthrolin über.
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    Journal für Praktische Chemie/Chemiker-Zeitung 312 (1970), S. 1121-1129 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es werden Synthesen einiger kernhydrierter Stilben- und Tolanderivate beschrieben und die Kinetik der Bromaddition an die C—C-Doppel- bzw. -Dreifachbindung untersucht. Die Geschwindigkeit der Anlagerung von Brom wird durch Messung der Extinktion der Reaktionslösung am Maximum der Bromabsorption in CCl4 bei 417 nm ermittelt. Aus den kinetischen Messungen und den daraus berechneten Aktivierungsenergien lassen sich Schlußfolgerungen über den Einfluß der Substituenten am C-Atom 1 des Cyclohexanringes auf die Reaktionsgeschwindigkeit und die Reaktionsordnung ableiten.
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    Journal für Praktische Chemie/Chemiker-Zeitung 312 (1970), S. 1161-1174 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Synthese von drei Analoga des Bradykinins beschrieben, in denen das Arginin in 1- oder 9-Stellung, bzw. in beiden Positionen durch die homologe Aminosäure Homoarginin (∊-Guanido-α-aminocapronsäure) ersetzt ist. Außerdem wird über eine modifizierte Synthese des Bradykinins berichtet.
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    Journal für Praktische Chemie/Chemiker-Zeitung 312 (1970), S. 1175-1182 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 17β-(2-Hydroxyäthylamino)-Δ1,3,5(10)-östratriene werden durch Umsetzung einer geeigneten SCHIFFschen Base mit einem Reduktionsmittel erhalten. Neben Lithiumaluminiumhydrid und katalytisch erregtem Wasserstoff wurde auch Methylmagnesiumjodid verwendet. Die so zugänglichen Derivate des Aminoäthanols wurden hinsichtlich ihres Verhaltens bei Acetylierung, Oxydation und Oxazolidinbildung untersucht. Die Reduktion eines solchen Oxazolidins führt zu einem am Stickstoff substituierten Hydroxyäthylamino-Steroid. 17β-Amino-Δ1,3,5(10)-östratriene wurden mit p-Toluolsulfosäurechlorid, n-Valeriansäurechlorid und Benzoylchlorid umgesetzt.
    Additional Material: 1 Tab.
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  • 296
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die elektrochemische Oxydation der α-Aryl-α-diazocarbonyl-Verbindungen 4a-n an der rotierenden Platin-Scheibenelektrode in LiClO4/Acetonitril führt im Primärschritt zu Diazonium-Radikalionen 5. Die anodischen Halbstufenpotentiale dieser Elektrodenreaktion liegen in Abhängigkeit von der Struktur der Diazoverbindung bei E1/2 = + 1,36 V bis +1,76 V (GKE). Die unter Verwendung der gleichen Elektrode aufgenommenen KALOUSEK-Umschaltkurven und Oszillopolarogramme der Diazoverbindungen vom Strukturtyp C6H5—CN2—CO—R2 geben charakteristische Hinweise für eine rasche Folgereaktion von 5 unter Bildung reversibel oxydierbarer Produkte (E1/2 = +1,23V bis +1,29V (GKE)). Durch Isolierung von Diphenyl-4,4′-dicarbonsäure 15 aus dem Produktgemisch der Elektrolyse von Phenyl-benzoyl-diazomethan 4c und Phenyl-diazoessigsäure-äthylester 4k wird nachgewiesen, daß die Diazonium-Radikalionen 5 zur Dimerisierung unter Bildung von Diphenyl-Derivaten befähigt sind. Substitution des Phenylrestes in p-Stellung zum Diazo-Kohlenstoffatom verhindert diese oxydative C—C-Verknüpfung. Der Einfluß dieser Folgereaktion auf das polarographische Verhalten der α-Diazocarbonyl-Verbindungen wird diskutiert und der Mechanismus der Bildung weiterer Elektrolyseprodukte erläutert.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 297
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 312 (1970), S. 129-134 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: p-Toluolsulfinamid 1 und N-Isopropyl-p-toluolsulfinamid 2 reagieren in ätherischer Lösung mit Lithiumbutyl zu Lithiumsulfinamiden 1a, 2a, die zur Darstellung N-substituierter bzw. N,N-disubstituierter Sulfinamide geeignet sind.
    Additional Material: 3 Tab.
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  • 298
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 312 (1970), S. 314-317 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Acylieren der 3-Desoxy-D-galaktose mit Benzoylchlorid oder mit Toluylchlorid in Pyridin erhält man die Tetra-O-benzoyl- (1a, 3a) bzw. die Tetra-O-p-toluyl-3-desoxy-α,β-D-galaktopyranose (1b, 3b). Daraus lassen sich durch Behandeln mit Chlorwasserstoff oder mit Bromwasserstoff die Benzochlor-(2a) bzw. die Toluobrom-3-desoxy-α-D-galaktopyranose (2b) darstellen. Ihre Pyranose-Strukturen gehen aus der Überführung in das bekannte Methyl-3-desoxy-β-D-galaktopyranosid hervor.
    Type of Medium: Electronic Resource
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  • 299
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 312 (1970), S. 307-313 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Glucosidierung des Benzimidazolonylenquecksilbers mit Acetobromglucose in siedendem Benzol entsteht das N-Glucosid 2, welches durch Behandeln mit Diphosphorpentasulfid in das N-(Tetra-O-acetyl-β-D-glucopyranosyl)-benzimidazolthion übergeführt werden kann. Durch Kochen von Benzimidazolon mit Acetobromglucose und Silbercarbonat in Toluol erhält man das O-Glucosid 4 neben wenig N-Glucosid 2. Das O-Glucosid 4 lagert sich beim Kochen mit Quecksilber(II)-bromid in Benzol teilweise zum N-Glucosid 2 um. Die Umsetzung von N,N′-Bis-(trimethylsilyl)-benzimidazolon und Acetobromglucose in siedendem Benzol bei Gegenwart von Quecksilber(II)-bromid und Quecksilberoxid liefert das N-Glucosid 2. Das N,N′-Diglucosid 3 läßt sich aus N,N′-Bis-(tetra-O-acetyl-β-D-glucopyranosyl)-2,3-dihydro-benzimidazol durch Oxydation mit Selendioxid in Acetanhydrid darstellen.
    Additional Material: 1 Tab.
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  • 300
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 312 (1970), S. 349-358 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Hydrazinbildung aus nucleofug substituierten Harnstoffen verläuft nach zwei Mechanismen: 1. Nach einem dem HOFMANN-Säureamidabbau analogen Mechanismus und 2. nach einer intramolekularen Aminierungsreaktion, bei welcher Diaziridinon 4als Zwischenstufe durchlaufen wird. Die Synthese von Alkylhydrazinen aus N-Alkylharnstoffen wird beschrieben.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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