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  • 1980-1984
  • 1965-1969  (710)
  • 1966  (710)
  • Physics  (398)
  • Chemical Engineering  (310)
  • Analytical methods  (2)
  • Nuclear reactions
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Material
Years
  • 1980-1984
  • 1965-1969  (710)
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Keywords
  • 1
    Electronic Resource
    Electronic Resource
    Membrane characterization by measurement of transient osmotic pressures (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 659-662 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040410
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  • 2
    Electronic Resource
    Electronic Resource
    Crystallographic studies of nylon 4. I. Determination of the crystal structure of the α polymorph of nylon 4Paper presented at the First Middle Atlantic Regional Meeting of the American Chemical Society, Philadelphia, February 4, 1966. (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 899-911 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The crystal structure of the α polymorph of nylon 4 has been determined from the x-ray diffraction patterns of uniaxially oriented monofilaments. In general the crystal structure of α nylon 4 is similar to that of α nylon 6. The unit cell is monoclinic with the following dimensions: a = 9.29 ± 0.05 A., b = 12.24 ± 0.05 A., c = 7.97 ± 0.05 A., and β = 114.5 ± 1.0°. There are eight monomeric units in the unit cell. The theoretical density is 1.37 g./cc. and the observed density 1.25 g./cc. The space group is P21. The nylon 4 chains are of the extended planar zigzag type, with the plane of the zigzag approximately parallel to the a axis of the unit cell. Along the a axis, every other chain is inverted - an antiparallel arrangement of chains - thus permitting complete hydrogen bonding and the formation of sheets of nylon 4 chains. Along the c axis of the unit cell, the second sheet is displaced by3/10 of the b axis, thus leading to a staggered arrangement of sheets. The sheets are held in place by van der Waals forces.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040606
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  • 3
    Electronic Resource
    Electronic Resource
    Narrow molecular weight distribution poly(styrenesulfonic acid). Part I. Preparation, solution properties, and phase separation (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 599-610 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A method is described for the conversion of polystyrene to poly(styrenesulfonic acid) without change in the molecular weight distribution; the reaction is performed at room temperature in 100% H2SO4 and uses Ag+ catalyst. The resulting polyelectrolyte has solubility and other characteristics significantly different from those of previously investigated poly(vinylsulfonic acid). This permits a study of the influence of the aromatic group on the local and long range interactions in solution. The barium salt of poly(styrenesulfonic acid) is unusual in showing both upper and lower consolute temperatures in solution.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040405
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  • 4
    Electronic Resource
    Electronic Resource
    Epitaxial crystallization of homopolymers on single crystals of alkali halides (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 611-629 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Epitaxial deposition of homopolymers from solution [polyethylene, isotactic polystyrene, poly-3,3-bischloromethyloxacyclobutane (Penton) and polypropylene] was found on the (001) faces of cleaved alkali halide single crystals. Electron and optical microscopy studies have shown that the polymer usually grew from small, rodlike crystallites which were oriented in (110) directions of the halide crystal. Large oriented, four-leaved, “rose” structures also were observed for polyethylene. Electron diffraction studies indicate that the polymer chain axes for polyethylene, isotactic polystyrene, and Penton generally lie parallel to the (001) faces of the halide crystal and are also oriented in the 〈110〉 directions of the crystal face. Investigations on the effect of various halide substrates upon the epitaxial crystallization habit of polyethylene inferes that lattice matching does not play the major role in orientation. Two possible explanations are offered for this epitaxial behavior.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040406
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  • 5
    Electronic Resource
    Electronic Resource
    Effect of molecular weight upon the heterogeneous nucleation of crystallization in polypropylene (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 631-638 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The effect of basic aluminium dibenzoate upon the supercooling of polypropylene fractions of molecular weight 9.2 × 103-1.25 × 106 was determined by differential thermal analysis. The response to heterogeneous nucleation within the precision of the method used appears to be only slightly dependent, if at all, upon the molecular weight of the polymer.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040407
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  • 6
    Electronic Resource
    Electronic Resource
    Wideline NMR studies of oriented nylon 66 (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 639-647 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Wideline NMR techniques have been applied to both singly and doubly oriented specimens of nylon 66. Variations in the spectra obtained are observed for different orientations of the specimens relative to the applied field. These variations demonstrate that the zigzag chain axis is essentially parallel to the draw direction and that motion occurs in all of the sample. The motion is of two types: random in the mobile regions and rotation of segments about the chain axis in the rigid regions.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040408
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  • 7
    Electronic Resource
    Electronic Resource
    Molecular weight averages of polymers as determined by density gradient centrifugation. II. Application to nylon 66 (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 663-665 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040411
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  • 8
    Electronic Resource
    Electronic Resource
    Crystallization in poly(n-octadecyl methacrylate) monolayers (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 649-657 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The crystallization kinetics of poly(n-octadecyl methacrylate) has been studied at the air-water interface. The rate of the crystallization has been measured by the decrease in the area of monolayers with time at various temperatures and surface pressures. The crystallization isotherms have been analyzed by the general mathematical treatment of the kinetics of phase changes, and the results show linear growth to be dominant. The variation of the rate constant with temperature and pressure has been illustrated by the difference in the supersaturation defined by introducing the equilibrium pressure-area isotherms.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040409
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  • 9
    Electronic Resource
    Electronic Resource
    Microfibrillar textures in polymer fibers (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 668-672 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040413
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  • 10
    Electronic Resource
    Electronic Resource
    Specific heats of poly(vinyl chloride) compositions (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 673-684 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Specific heats of plasticized poly(vinyl chloride) can be readily obtained by means of the thin foil calorimeter when the polymer is fabricated into sheet or film. The effects of temperature and plasticizer content on the specific heat and of the plasticizer content on the glass temperature are readily observed. The data may be used to estimate the glass temperatures of plasticizers where those temperatures are not readily reached by normal techniques. The specific heat at the glass temperature is approximately 0.255 for the ranges of 0-30 phr plasticizer. A definite glass transition is not observed with 60 phr plasticizer. No other transitions were observed between 200 and 400°K. The previous history of the polymer is important, as it can change the specific heat of the polymer noticeably, especially above the glass temperature. Comparison of the values listed here with those obtained by others should be made with the understanding that these samples were fabricated by extrusion and were free of observable strain. The degree of crystallinity of these polymers is very small, probably less than 10%, since none was found by x-ray diffraction. The plasticizing effect of some stabilizers was noted.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040501
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  • 11
    Electronic Resource
    Electronic Resource
    Persistent polarization in polymers. II. Depolarization currentsPresented in part before the 13th Canadian High Polymer Forum, Ottawa, Ontario, Canada, September 22-24, 1965. (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 697-704 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Depolarization currents were used to study the persistent polarization induced in polystyrene and poly(methyl methacrylate) by cooling with flow under pressure. These studies showed that the charge on electrets made by flow under pressure consists in part of a surface charge which leaks off rapidly in moist air and in part of a charge due to volume polarization which decays more slowly. The volume polymerization produced in poly(methyl methacrylate) by flow under pressure is of the same order as that produced by cooling under a voltage drop, but flow under pressure produces a larger surface charge.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040503
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  • 12
    Electronic Resource
    Electronic Resource
    Persistent polarization in polymers. I. Relationship between the structure of polymers and their ability to become electrically polarizedPresented in part before the 13th Canadian High Polymer Forum, Ottawa, Ontario, Canada, September 22-24, 1965. (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 685-695 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The ability of various polymers to acquire persistent polarization (i.e., to become electrets) was investigated. Polarization was induced in the polymers by two methods: (a) by cooling under a voltage drop and (b) by cooling with flow under pressure. There was found to be an optimum temperature for electret formation by either method. This optimum temperature was roughly 37°C. above Tg when polarization was produced by application of a voltage drop and roughly 57°C. when polarization was produced by flow under pressure. Crystallinity and the nonhomogeneities present in blended polymers were harmful to electret formation, but a small critical amount of ionic impurity was helpful.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040502
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  • 13
    Electronic Resource
    Electronic Resource
    Molecular structure of polyethylene. XIII. An improved cryoscopic method for determining number-average molecular weight of polyethylene (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 705-714 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The determinations of the number-average molecular weight of polyethylene by cryoscopy has been improved, permitting precise measurements with both linear and branched polyethylenes in the molecular weight range 4,000-30,000. Improvements include a cryometer of new design, a lower-melting cryoscopic solvent containing a nucleating agent to control supercooling and rate of crystallization of the solvent, and more precise measurement of freezing point depression. Polyethylene samples are dissolved in hexamethylbenzene admixed with 0.1% of cadmium iodide, and steady-state freezingpoint depressions are measured with a thermistor to a maximum sensitivity of 5 × 10-5°C. Molecular weight measurements are reproducible to within ±10%. The cryoscopic apparatus and procedure are described in detail, and results obtained with samples of linear and branched polyethylene are presented and discussed.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040504
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  • 14
    Electronic Resource
    Electronic Resource
    Les polyélectrolytes à l'interface liquide-liquide (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 765-775 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The behavior of films of polyelectrolytes at the water-organic liquid interface depends on the nature of the interface and the pH of the substratum. The present paper investigates the influence of these two factors on the cohesive forces between monomer units. Two polyelectrolytes were studied: poly(methacrylic acid) (APM) and poly-2-vinylpyridine (2-PVP). In the case of uncharged films, the collapse pressure decreases when the polarity of the organic phase becomes more important, whereas the term ω/kT, which appears in the theory of Motomura and Matuura, increases. A quantitative relation between the parameter ω/kT and the collapse pressure may be deduced. The behavior of the ionized surface film at different pH values is modified by the choice of the interface. However, there exists a competition between two phenomena: the dissolution of ionized residues in the substratum and the electrostatic repulsion between charges in the surface plane. Depending upon whether the first or the second parameter is more important, we observed that the surface pressure decreased or increased with the degree of ionization.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040508
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  • 15
    Electronic Resource
    Electronic Resource
    Axial dispersion of polymer molecules in gel permeation chromatography (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 731-743 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Gel permeation chromatography is an elution chromatographic process depending on the permeation of the solute through a bed of gel particles. This process is used in the estimation of molecular weight distributions of polymers, since elution occurs in decreasing order of molecular size. The eluting species, however, are not perfectly fractionated, and apparent broadening of the distribution occurs. This broadening results from an axial (longitudinal) mixing of the eluting species. Consideration of the accessible bed volume for each species permits a correction to be made for this axial dispersion. The concept was applied to heterodisperse distributions by solving the resulting simultaneous equations. A least-squares regression may be employed to utilize the experimental data most effectively. The experimental chromatogram can be described in terms of accessible bed volume and dispersion coefficient of each species together with flow rate, sample concentration, and chromatograph column geometry. The chromatogram corrected for the axial dispersion describes the molecular weight distribution more accurately than does the experimentally determined curve. The correction procedure was applied to a well-characterized polystyrene; the results of the gel permeation chromatography show excellent confirmation of the results of fractionation and of other instrumental analyses.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040506
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  • 16
    Electronic Resource
    Electronic Resource
    Effect of crosslink density on the creep behavior of natural rubber vulcanizatesPaper presented at the 36th Annual Meeting of the Society of Rheology, Case Institute of Technology, Cleveland, Ohio, October 25-27, 1965. (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 745-763 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Torsional creep measurements on four natural rubber vulcanizates, crosslinked to different degrees, were carried out in the temperature range from -50 to 90°C. This investigation complements the studies on identical samples of the stress relaxation behavior by Chasset and Thirion and of the dynamic mechanical response by Ferry, Mancke, Maekawa, Ōyanagi, and Dickie. The creep measurements reported are shown to be in agreement with the stress relaxation results. In addition to the usual temperature reduction, a superposed curve was obtained for the long time response using the apparent molecular weight between crosslinks, Mc, as a reduction variable. The variation in viscoelastic response with crosslink density is interpreted as a restrictive action of the chemical crosslinks on the transient entanglement network.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040507
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  • 17
    Electronic Resource
    Electronic Resource
    Effect of stereosequence length on crystallization kinetics of propylene oxide polymersPresented to the Division of Polymer Chemistry, 150th American Chemical Society Meeting, Atlantic City, N. J., September 1965. (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 715-729 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Crystallization kinetics of crystalline fractions of propylene oxide polymers made with different catalysts have been studied by isothermal dilatometric and microscopical measurements. Isothermal microscopical measurements indicate that spherulite growth in these polymers proceeds from predetermined nuclei. The half time for spherulitic appearance is less than, but of the same order as, the half time for complete crystallization. Only by taking this factor into account can the dilatometric data be represented by the Avrami equation. The deviation of the crystallization isotherm from that predicted from the microscopical data using the Avrami theory is attributed to a secondary crystallization process taking place within the spherulite. Crystallization continues long after spherulites completely occupy the available volume in the polymer. By assuming that the secondary crystallization proceeds as a first-order process in the uncrystallized, but crystallizable, portions of the melt, it is shown that the crystallization isotherms can be completely described in terms of four parameters. These are: (1) the time constant for the primary crystallization process; (2) the time constant for nucleation; (3) the time constant for the secondary crystallization process, and (4) the extent of secondary crystallization. The important conclusions of these studies are: the rates of nucleation and of spherulitic growth are far more dependent on temperature than on stereoregularity; the ratio of the rate of the secondary crystallization process to that of the primary crystallization process is almost independent of temperature, but increases with increasing stereoregularity of the polymer.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040505
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  • 18
    Electronic Resource
    Electronic Resource
    Structure of pressure-crystallized polypropylene (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 777-788 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The structure of polypropylene crystallized at pressures up to 5000 atm. has been studied. Upon slow cooling from the melt at 320 atm., the γ modification, previously found only in low molecular weight and stereoblock fractions, begins to appear in small amounts in addition to the normal α monoclinic form. As the pressure is increased further, a larger proportion of the sample crystallizes in the γ form until, at 5000 atm., only the γ modification is present. X-ray and DTA studies show that the γ form of polypropylene transforms to the normal α modification at a temperature only slightly below the γ melting point. Evidence is presented which favors the occurrence of a solid-state transition as a model of transformation to the α form. Results from isothermal crystallizations at low supercoolings and annealing experiments under high pressure show that the melting point of the γ modification of polypropylene is very sensitive to crystallite perfection.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040509
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  • 19
    Electronic Resource
    Electronic Resource
    Molecular weight determination of polyamides by vapor pressure osmometry (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 817-825 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The vapor pressure osmometry method for determining the molecular weight of polyamides has been studied by use of the newly developed solvents. Polymers used were polycaprolactams, polyenanthamides, and polypelargonamides. The measurements were carried out with 2,2,3,3-tetrafluoro-1-propanol and 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-1-heptanol as solvents at 50 and 130°C., respectively. Endgroup determinations on samples were also done in m-cresol by 0.1 N-hydrochloric acid. Reduced resistance differences (ΔR/C)0 obtained by vapor pressure osmometry at 50°C. were found to be in linear relation with the reciprocal of the number-average molecular weight determined by endgroup titrations; but anomalous results were obtained when dodecafluoroheptanol was used as the solvent at 130°C.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040512
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  • 20
    Electronic Resource
    Electronic Resource
    Orientation behavior of stereoregular poly(vinyl alcohols) (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 797-816 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The orientation behavior of stereoregular poly(vinyl alcohols) was investigated during stretching and after releasing the stress on the bulk polymers at relatively high humidity (80% R. H.) A structural model, differing from polyethylene, was proposed in which the crystallites were embedded in a considerably swollen amorphous matrix without any definite physical interaction so as to form an aggregation of crystallites, a superstructure. The crystal orientation followed, in principle, “the first borderline case” of Kratky, but with some difference from theory in orientation, while the noncrystalline orientation was represented by the freely jointed equivalent chain model of Kuhn and Grün with a value of N/γ as small as around 5. The difference between crystal orientation found and the theorietical orientation is discussed and some factors which prevented the crystal orientation are considered.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040511
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  • 21
    Electronic Resource
    Electronic Resource
    Group motions in the glassy state of some substituted polystyrenes and poly(vinyl benzoates) (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 789-796 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Mechanical damping measurements were carried out in the range of 103-105 cps and between 60°K. and the softening point on some substituted Polystyrenes and poly(vinyl benzoates) containing different substituents (methyl groups, methoxy groups, and halogen atoms) either in the ring or in the main chain. The ortho and meta ring-substituted polystyrenes do not show any secondary mechanical relaxation in the glassy state, although all the other substituted polystyrenes, exhibit a low-temperature damping peak (δ process) (which is in some way connected with ring motions) whose height and temperature location depend on nature, position, and number of substituents. Substituents in the para position of the ring or in the α position in the backbone chain shift the δ peak of the unsubstituted polystyrene towards higher temperatures; this shift is accompanied by an increase of the apparent activation energy E*. Substitution in the β position, on the contrary, does not affect the δ peak. Analogous results are obtained for substituted poly(vinyl benzoates), which exhibit, in addition, a β relaxation effect, associated with carboxyl group motions. A very good correlation is found between the values of E* and the limiting relaxation time τ for the δ relaxation of polystyrenes and poly(vinyl benzoates), similarly substituted in the ring, indicating that the δ relaxation leads to absorption curves in the mechanical relaxation spectrum which are characteristic of the structure of the aromatic side chain.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040510
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  • 22
    Electronic Resource
    Electronic Resource
    The equilibrium melting point of polyoxymethylene (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 827-829 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040513
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  • 23
    Electronic Resource
    Electronic Resource
    Preparation and use of very tight osmotic membranes (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 830-831 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040514
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  • 24
    Electronic Resource
    Electronic Resource
    Second virial coefficient of amylose acetate (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 835-844 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The second virial coefficients of amylose acetate fractions have been determined at different temperatures and have been analyzed according to recent theories of second virial coefficient.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040601
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  • 25
    Electronic Resource
    Electronic Resource
    Relaxation phenomena in concentrated polyelectrolyte solution. II (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 845-854 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Dynamic viscoelastic properties of 10 and 20% aqueous solutions of sodium polyacrylate were studied by the electromagnetic transducer method at 500 cps in the temperature range of 0-50°C. These solutions distinctly showed a relaxation phenomenon in this temperature range which was also affected by addition of such compounds as sodium chloride, urea, and dioxane. An anomalous behavior that cannot be explained as due to the relaxation phenomenon was observed on the addition of small amounts of these agents. One of the causes of this behavior is ascribed to the ion association in the solution. The static viscosity of the solution was also measured by using a rotating cylinder viscometer and the results compared with the dynamic data.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040602
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  • 26
    Electronic Resource
    Electronic Resource
    Glass transitions in ionic polymersContribution no. 1890 from the Department of Chemistry, University of California, Los Angeles, Calif. (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 855-868 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The glass transitions of an ionic polymer in bulk have been studied as a function of the counterion for various homo- and copolymers. It is shown that the glass transition temperature can vary by as much as 530°C., from -10°C. for the nonionic material to +520 for Ca2+ or Zn2+ substituted polymer. From simple electrostatic considerations, it is shown that a linear correlation should exist beween the glass transition and the ratio of the cation charge, q, to the internuclear distance, a, between cation and chain anion; for this particular material (the polyphosphate chain) the relation is Tg = 625(q/a) -12 where q is in units of one electron and a is in A. If the data are interpreted in the light of the Gibbs-DiMarzio theory, it is seen that both the chain stiffness and the intermolecular energy increase in an approximately parallel manner as q/a increases.
    Additional Material: 8 Ill.
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    URL: http://dx.doi.org/10.1002/pol.1966.160040603
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  • 27
    Electronic Resource
    Electronic Resource
    Configurational entropy of polyethylene and other linear polymers (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 869-880 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The configurational entropy of the polyethylene chain at the melting points calculated in two ways. In both calculations, tetrahedral angles and discrete trans and gauche arrangements of all bonds are assumed, and trans bonds are assumed more stable than gauche by energy U1. First, calculations are made on chains of up to N = 18 bonds, disallowing all configurations having overlapping atoms, and the result is extrapolated to large N. Second, a calculation is made directly for long chains, with overlaps excluded only over every short chain segment. The results are in almost exact agreement, suggesting that the second method can be safely used with other molecules. The calculated configurational entropy is in line with that suggested by the entropy of fusion, assuming the chains to acquire a configurational freedom in the melt which approaches that of independent chains.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040604
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  • 28
    Electronic Resource
    Electronic Resource
    Angular distribution of intensity of rayleigh scattering from comblike branched molecules (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 881-897 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The angular distribution function P(θ) for intensity of light scattered by a dilute solution of comblike branched molecules has been determined for three situations of some interest for evaluation of experimental data: (1) the molecules are identical with branches of equal length attached equidistantly along linear backbone chains; (2) the molecules are homogeneous in mass, with the same number of branches on each molecule, but the branches are distributed at random along the chain; (3) branches and main chains are still uniform, but the molecules are heterogeneous in mass with the number of branches per molecule distributed according to the binomial distribution and the branches in any molecule spaced randomly along the backbone. Examination of numerical results shows that the scattering functions for models (1) and (2) are not very different. The function for case (3) is somewhat different from the others when the mean number of branches per molecule is small but they contain a large fraction of the mass of the molecule. Over a limited range of the pertinent variables (corresponding roughly to observations on typical vinyl polymers of molecular weights up to 106) all three functions agree quite well with P(θ) for homogeneous linear chains with the same mean-square radius of gyration.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040605
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  • 29
    Electronic Resource
    Electronic Resource
    Light-scattering study of the molecular weight distribution of polypropylene (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 923-942 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A light-scattering study is presented of two isotactic polypropylene samples with broad molecular weight distributions (Mw/Mn = 8.1 and 8.7, respectively) dissolved in α-chloronaphthalene at 147°C. Incident radiation of 5460, 4358, and 3650 A. was used. The reciprocal intramolecular scattering function, P-1(u) is expressed as a function of the variable [sin(θ/2)/λ′]2. This provides a wider range of experimental values of the variable u = 16π2(b2/6) [sin(θ/2)/λ′]2 than is accessible by the usual technique of using only one wavelength. The shape of the function P-1(u) is closer to that predicted theoretically if the weight distribution function f(N) in the equation \documentclass{article}\pagestyle{empty}\begin{document}$ P(u) = \int_0^\infty {Nf(N)P_N (u)dN} /\int_0^\infty {Nf(N)dN} $\end{document} is given by the log-normal distribution rather than the distribution function of Schulz and Zimm. The method is applicable to polymer samples for which the average molecular weights are too low to be measured by the light-scattering method of Benoit and Loucheux.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040608
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  • 30
    Electronic Resource
    Electronic Resource
    Effect of chemical reagents on the fine structure of cellulose. Part III. Action of caustic soda on cotton and ramie (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 571-586 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The changes in x-ray orientation brought about by the treatment of cotton and ramie with caustic soda of different concentrations have been studied. With ramie the effect of the treatment is to decrease the x-ray orientation, while with cotton the reverse is true. The cause of this difference is traced to a difference in the morphology of the two fibers rather than a difference in their fine structure.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040403
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  • 31
    Electronic Resource
    Electronic Resource
    Frequency and temperature dependence of the dynamic mechanical properties of poly-4-methylpentene-1Presented at the 33rd Annual Meeting of the Society of Rheology, Baltimore, Maryland, October 29-31, 1962. (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 559-569 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dynamic mechanical properties of poly-4-methylpentene-1 have been measured in torsion in the temperature range from 25 to 160°C. at frequencies from 10-3 to 10 cps. Two transitions are found. The first, with a peak at 40°C. at 1 cps, appears as a normal glass transition. A broad high temperature peak appears at 130°C. The dynamic compliance-frequency data can be superposed by the conventional method of reduced variables for temperatures up to 100°C. The temperature dependence of the shift factors follows the WLF equation. Above this temperature, superposition can be achieved by applying horizontal and vertical shifts to both components of the dynamic compliance. When the vertical shift is permitted, the range of applicability of the WLF equation is extended to 160°C.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040402
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  • 32
    Electronic Resource
    Electronic Resource
    Dynamic mechanical properties of crystalline, linear polyethylene (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 545-557 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Two sets of dynamic mechanical property data and some stress relaxation data for semicrystalline, linear polyethylene are treated by data reduction methods previously described. These data can be represented by a master plot of reduced modulus versus reduced frequency and two sets of temperature-dependent shift factors. The first of these factors reflects the change of viscoelastic relaxation times with temperature. The second represents a separable change of modulus with temperature which applies over the entire time or frequency range of the experiments. This change is larger and in the opposite direction to that found applicable in the behavior of noncrystalline plastics and rubbers. The two sets of dynamic data show the same frequency-temperature dependence which can be represented by an activation energy of 22 kcal./mole. Small differences in the modulus-temperature dependence are attributed to differences in molecular weight or annealing conditions. The stress relaxation data superposes to a curve in good agreement with the dynamic data but with a factor of 20 difference in time scale. This difference is attributed to the finite strains used in the stress relaxation measurements. Such strains might be expected to increase free volume in simple extension deformations and so accelerate the relaxation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1966.160040401
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  • 33
    Electronic Resource
    Electronic Resource
    NMR observations of drawn polymers. V. Sorption into drawn and undrawn polyethylene (1966)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 587-598 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: NMR measurements on undrawn polyethylene (PE) samples in contact with a solvent such as C2Cl4 indicate an increase in the mobility of the mobile chain segments as compared to dry samples. Highly drawn PE shows no such effect. This is because Sa, the sorption per unit mass of noncrystalline material present, decreases from 20.9 wt.-% (dry basis), found for undrawn quenched PE, to 0.63 wt.-% after drawing (Sa determined at 25°C. and 0.80 vapor activity). Drawing also reduces the segment mobility according to the NMR spectrum. It is shown that these effects are caused by considerable structural changes occurring in the noncrystalline regions of PE upon drawing. Annealing of drawn PE samples at successively higher temperatures leads to a gradual relaxation of the noncrystalline regions towards the state characteristic of undrawn PE. With increasing annealing temperature Sa as well as the mobility approach values found with undrawn PE.
    Additional Material: 5 Ill.
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    URL: http://dx.doi.org/10.1002/pol.1966.160040404
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    Electronic Resource
    Electronic Resource
    Chemical engineering and society (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 3-4 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120103
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  • 35
    Electronic Resource
    Electronic Resource
    The influence of surface coverage on catalytic effectiveness and selectivity. The isothermal and nonisothermal cases (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 20-23 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Both nonisothermal and isothermal catalytic effectiveness factors are computed for kinetic rate laws of the Langmuir-Hinshelwood, Hougen-Watson type, involving surface coverage by reactant and products. Selectivity taxation is also treated and the significant influence of interphas heat and mass gradients surrounding the catalyst is displayed. The complexities of these real kinetic systems suggest caution in the use of prior generalizations based upon simpler rate laws.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120107
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  • 36
    Electronic Resource
    Electronic Resource
    The condensing of low pressure steam on vertical rows of horizontal copper and titanium tubes (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 31-35 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer data are presented for condensing steam at 2 in. Hg absolute pressure on the outside of nine copper and nine titanium horizontal tubes in a vertical row. The condensing coefficient correction factor was maximum for the top titanium tube and was 46% higher than the correction factor for the top copper tube. The difference between the correction factors for titanium and copper tubes diminished with the number of tubes in a vertical row to 8% higher than the correction factor for copper tubes with six to nine tubes in a vertical row.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120109
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  • 37
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    Electronic Resource
    Pressure drops and void fractions in horizontal two-phase flows of potassium (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 50-58 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Vapor-liquid flow of a potassium-8% sodium mixture was studied with the use of a boiling heat transfer test loop. Pressure drop data were obtained from a 36-in. long, 0.495-in. I.D. unheated test section. Void fractions were measured at the midpoint of the test section with gamma ray attenuation.Flows were essentially frictional. Quality, total flow rate, and absolute pressure were the principal variables affecting the pressure drop results, which were correlated in terms of a two-phase friction factor. A metallic void fraction correlation was developed from previously reported data for other metallic fluids together with the potassium data of this study.The potassium two phase friction factors fall substantially lower than values predicted by well-known frictional pressure drop correlations. Metallic void friction values are appreciably lower than data for other fluid systems. Velocity slip ratios appear to be much higher than for other fluid systems due to high liquid-to-vapor density ratios and low void fractions.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120112
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  • 38
    Electronic Resource
    Electronic Resource
    Masthead (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966) 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120201
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  • 39
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    Electronic Resource
    Introduction to the analysis of chemical reactors, Rutherford Aris, Prentice-Hall, Inc., Englewood Cliffs, New Jersey (1965). xi and 337 pages, $14.50, text edition $10.95 (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 210-407 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120202
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  • 40
    Electronic Resource
    Electronic Resource
    Heat transfer to non-Newtonian fluids in transitional and turbulent flow (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 221-232 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Turbulent and transitional flow heat transfer correlations for non-Newtonian fluids are presented. By means of an extension of the Reichardt-Metzner-Friend correlation to nonisothermal flow, and a new definition of Prandtl number to account for deviations from Newtonian behavior, turbulent flow data are correlated to a standard deviation of 14.8%. By means of a normalizing procedure, data for the complex case of transitional flow heat transfer to non-Newtonian fluids are correlated to a standard deviation of 17.7%. At the transition region boundaries, the correlation is consistent with laminar and turbulent flow correlations. A basic similarity in the Newtonian and non-Newtonian heat transfer mechanisms is suggested.
    Additional Material: 11 Ill.
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    URL: http://dx.doi.org/10.1002/aic.690120205
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  • 41
    Electronic Resource
    Electronic Resource
    Momentum, heat, and mass transfer in turbulent non-Newtonian boundary layers (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 69-75 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The boundary-layer equations and a Blasius type of relationship between f and NRe gen are used to derive expressions for velocity distribution, local boundary-layer thickness, local shear stress, and total drag force for the turbulent boundary-layer flow of a power law non-Newtonian fluid across a flat plate at zero incidence. Relationships are derived for the velocity at the edge of the laminar sublayer and for the thickness of the laminar sublayer.An analogy between heat and momentum transfer is then used to obtain expressions for local and mean values of the heat transfer coefficient in a turbulent thermal boundary layer for power law materials flowing over flat plates. Analogous extensions to mass transfer are indicated.A tentative criterion is suggested for characterizing the transition from laminar to turbulent boundary-layer flow of power law fluids.Relationships combining the effects of a part laminar, part turbulent boundary layer are presented.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120115
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  • 42
    Electronic Resource
    Electronic Resource
    Effect of ultrasonic waves on mass transfer rates of selected fluids (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 90-95 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The application of ultrasonic energy to a fluid in a capillary has resulted in greatly increased rates of mass transfer (of the order of 800 to 2,000% above that without insonation) to occur at specific heights in the capillary. Reproducible results with several selected fluids (carbon tetrachloride, acetone, ethanol, and methanol) have shown that these specific heights are always at the half wavelengths of the particular fluid investigated. The mathematical model developed herein predicts that at these half wavelengths, the fluid particle displacement of the ultrasonic wave becomes quite large, exceeds the threshold value necessary for the stability of the surface waves, and causes droplets to be ejected into the vapor above the surface in the form of a fog. The resulting decrease in the diffusional path length of the ejected fluid provides the final mechanism for an increased mass transfer from the capillary tube.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120118
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  • 43
    Electronic Resource
    Electronic Resource
    A generalized equation for computer calculation of liquid densities (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 95-99 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A generalized equation explicitly relating reduced density to reduced temperature and reduced pressure has been developed for calculating liquid densities of pure compounds on a digital computer. The analytical formulation is based mainly on a modified corresponding states principle and the graphical correlation of Lydersen, Greenkorn, and Hougen. The calculated densities from the equation reproduce the literature data within 2% for sixty-two saturated liquids and nineteen compressed liquids.With the aid of a pseudocritical method and a generalized equation of vapor pressure, the same equation is readily applied to the estimation of liquid mixture densities. The method of Prausnitz and Gunn is chosen for the evaluation of pseudocritical constants. For fifteen binary systems, one ternary system, and one quinary system, the one hundred fifty-nine calculated densities agree with the literature data to within 3%. This method is limited to pseudoreduced temperatures less than 1.0.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120119
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  • 44
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    Forced convection mass transfer: Part III. Increased mass transfer from a flat plate caused by the wake from cylinders located near the edge of the boundary layer (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 124-130 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Enhanced rates of mass transfer in the wake region behind detached cylindrical turbulence promoters were investigated with the use of the naphthalene sublimation technique. The maximum increase in the average rate of mass transfer through laminar boundary layers was over 170%. The remarkable feature of these results was that the enhanced rates of mass trasfer persisted for over one hundred and thirty cylinder diameters downstream from the cylinder generating the wake. The observed effect was not only strongly dependent on the free stream velocity and the location of the cylinders relative to the mass transfer surface, but there were marked differences observed between the rate of mass transfer in the wake region behind one and behind two cylinders. These results resemble a “tuning phenomenon” and are believed to be due to Tollmein-Schlichting instabilities and premature transition.
    Additional Material: 6 Ill.
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    URL: http://dx.doi.org/10.1002/aic.690120124
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  • 45
    Electronic Resource
    Electronic Resource
    The time-optimal control of discrete-time linear systems with bounded controls (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 143-152 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The discrete-time, time-optimal control of high-order, linear systems with bounded controls is formulated as a problem in linear programming. The solution obtained requires a certain minimum number of controls to be on their bounds. Numerical results are obtained for a system with controls bounded on one and both sides and extensions indicated for state variable constraints. The method proves to be extremely fast and simple to solve on a high-speed digital computer.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120127
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  • 46
    Electronic Resource
    Electronic Resource
    Enthalpy determinations on the helium-nitrogen system (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 137-143 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental isobaric heat capacity and differential latent heat measurements have been made on the helium-nitrogen system. Compositions studied were nominal 5, 25, 50, and 100% helium in nitrogen over the range 0 to 2,000 lb./sq.in.abs. and -250° to 50°F.These data, combined with the previously reported work on nitrogen and the Joule-Thomson coefficients of Roebuck, are used to construct the complete pressure-enthalpy-composition network over the investigated limits of pressure and temperature.The enthalpies obtained from experimental heat capacity and Joule-Thomson data are compared with enthalpies computed from PVT data. The changes of phase determined by differential latent heat measurements are compared with literature vapor-liquid equilibrium data.This information is used to prepare pressure-enthalpy diagrams for all the mixtures investigated. A three-dimensional representation of the data on a pressure-enthalpy-composition diagram is presented. Constructions are outlined from which heats of mixing and partial molal enthalpies can be obtained.The thermodynamic network developed is believed accurate within 1% and should be of use to those concerned with low-temperature separation of helium from nitrogen.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120126
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    Electronic Resource
    A computational model for the structure of porous materials employed in catalysis (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 180-185 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A computational model for the structure of porous materials such as those employed in catalysis is proposed. The void volume within the solid is considered to be composed of two major arrays of pores, centrally convergent and centrally divergent, respectively, interconnected at specified intervals within the arrays. The exact shape of these arrays is determined uniquely from the volume-area distribution of the porous structure.The model is applied to computation of counterdiffusional flux through a porous solid as measured in a Wicke-Kallenbach experiment. The effects of dead end pores and of mixing on the results are discussed, and comparison with experimental data reported for a particularly well-defined system is given.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120132
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  • 48
    Electronic Resource
    Electronic Resource
    The effect of wave induced turbulence on the rate of absorption of gases in falling liquid films (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 186-192 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Concentration profiles for carbon dioxide diffusion into thin water films with waves flowing down an inclined plate have been determined. Film Reynolds numbers were varied from 732 to 1,834 at a cell angle of inclination of 9 deg. 44 min. Total diffusivities measured from the concentration profiles showed a marked increase in the central region of the film, with the diffusivity tending toward the molecular diffusivity at the boundaries of the film. Interferometer pictures of the concentration profile showed that the effect of the waves was to compress and expand the profile as the surface of the film changed, but indicated no direct effect on the variation of eddy diffusivity normal to the liquid surface.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120133
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  • 49
    Electronic Resource
    Electronic Resource
    Sinusoidal flow simulation with pulses (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 203-203 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120138
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  • 50
    Electronic Resource
    Electronic Resource
    Advances in chemical engineering, Thomas B. Drew, John W. Hoopes, Jr., and Theodore Vermeulen, Editors, Giles R. Cokelet, Assistant Editor. Academic Press, New York and London (1964). Volume 5. 317 pp, $14.00 (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 204-205 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120139
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  • 51
    Electronic Resource
    Electronic Resource
    Heat transfer and reaction in laminar tube flow (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 213-220 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analytical study was made of the temperature and composition distribution and heat transfer characteristics for a reacting fluid in a tube. The reaction was assumed to be first order and irreversible and the flow to be laminar.The results, which consisted of radial and axial profiles of temperature, composition, and Nusselt number could be expressed in terms of four parameters. The gradient of radial composition was usually sufficient to judge the effect of reaction on the heat transfer coefficient. Owing to residence time and temperature effects, the Nusselt number even for an exothermic reaction was usually greater than that for an inert system. For endothermic cases, the energy flux due to diffusion increases the total energy flow, and the Nusselt number may be several fold that in the corresponding nonreactive system.For certain values of the parameters the radial temperature and composition profiles showed maxima and minima between the wall and center of the tube. At these conditions the direction of the flow of energy due to diffusion could not explain the increase in Nusselt number.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120204
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  • 52
    Electronic Resource
    Electronic Resource
    Effects of interfacial instability on film boiling of saturated liquid helium I above a horizontal surface (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 238-244 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Film boiling above a horizontal surface has been investigated theoretically and experimentally at standard gravity and 1 atm. Theoretical film boiling results for conventional fluids have been extended, on the basis of interfacial instability due to gravity, to include liquefied gases properties, such as low viscosity and small surface tension. In the experiments, primarily ordinary liquid helium I has been studied to extend the range of the film boiling Rayleigh numbers (based upon Laplace's reference length) from about 107 (reported for room temperature liquids) to values of the order of magnitude unity. The heat transfer data taken at surface excess temperatures ΔT (above the boiling point) between 80° and 300°K. have been correlated with a theoretical model which presumes the absence of any scaling length (Laplace length) associated with surface tension. At low ΔT the experimental results have been found to agree with a model which presumes a negligible influence of a scaling length due to surface tension and absence of detectable viscosity effects.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120207
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  • 53
    Electronic Resource
    Electronic Resource
    The finite-difference computation of natural convection in a rectangular enclosure (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 161-166 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study is made of the natural convection of a fluid contained in a long horizontal enclosure of rectangular cross section with one vertical wall heated and the other cooled. Two-dimensional motion is assumed. The governing vorticity and energy transport equations are solved by an implicit alternating direction finite-difference method. Transient and steady state isothermals and streamlines are obtained for Grashof numbers up to 100,000 and for height-to-width ratios of 1, 2, and 3.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120129
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  • 54
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    Electronic Resource
    Formation of interfacial area at high rates of gas flow through submerged orifices (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 174-180 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Interfacial area was formed by passing air through orifices that were submerged horizontally beneath 4.5 ft. of each of four different liquids. The flow rates of the air ranged from 0.095 to 1.34 (st. cu. ft./min.), the diameters of the orifices ranged from 0.03125 to 0.1875 in., and the I.D. of the orifice holders ranged from 1 to 2.5 in.The areas were measured with a photocell, a recorder, and an integrator. This combination gave the time average of the interfacial area that passed a selected plane of the column.The interfacial area produced was correlated as a function of the physical properties of the fluids, the diameter and number of orifices per plate, and the gas flow rate.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120131
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  • 55
    Electronic Resource
    Electronic Resource
    The second law. Caratheodory's principle with simplified mathematics (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 195-197 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120135
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  • 56
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    Electronic Resource
    The kinetics of sorption by ion exchange resin beds (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 304-308 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of sorption of dilute aqueous solutions of acetone, n-propanol, ethylen glycol, and glycerine by packed beds of Dowex 50W-X8 (H+) resin have been investigated experimentally. Data indicate that intraparticle diffusion of the solute is rate controlling and that density mixing and nonlinear equilibrium effects must be considered in analyzing this type of operation.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120218
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  • 57
    Electronic Resource
    Electronic Resource
    Axial laminar flow of a non-Newtonian fluid in an annulus (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 328-332 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The equation of motion has been solved for steady axial, laminar, isothermal flow of an Ellis model fluid in a conduit of annular cross section. Tables are presented which may be used to obtain flow curves for annular flow of fluids whose Ellis parameters are known.The Ellis fluid predictions are compared to experimental data on dilute polymer solutions flowing in annuli. Ellis fluid predictions of flow curves are also compared to those predicted by the generalized Newtonian fluid and the power law fluid.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120222
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  • 58
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    Electronic Resource
    Binary physical adsorption of argon and nitrogen on fixed beds of activated silica gel (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 339-344 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The physical adsorption and desorption of argon and nitrogen on fixed beds of 18 × 20 mesh silica gel at -78.5°C. and 1 atm. have been studied. Binary mixtures containing 5.52, 10.34, 51.0, 90.16, 95.13 mole % nitrogen, as well as pure argon and pure nitrogen, were used. Superficial gas velocities were varied from 0.10 to 0.27 ft./sec. Concentration vs. time curves were obtained at bed depths of 5.3, 8.6, and 12.0 in.Resistance to mass transfer from the gas stream to the outside surface of the particles was found to be negligible. The rate is limited due to mass transfer from the outside surface to the internal surface of the particle. The data were correlated by the integrated Rosen diffusion solution with D = 9.60 (10-8) sq.ft./sec. or alternatively, by the Hiester and Vermeulen integrated model with kp = 0.23 sec.-1.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120224
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  • 59
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    Electronic Resource
    Application of the Gibbs-Konovalow equations to binary phase equilibria (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 364-368 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Gibbs-Konovalow relations are shown to provide a unified approach to the description of binary two-phase equilibria. The relations are applied to a consideration of high order transitions (7) and are shown to easily lead to well-known, but generally uncorrelated, hehavior of slopes of lines separating two single-phase regions in binary systems. In particular, the conditions under which the slope of the temperature-composition line is zero, constant, or undefined in the neighborhood of congruent and peritecticThe meanings of these terms will be amplified in the text processes are derived.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120229
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  • 60
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    Electronic Resource
    Catalytic hydrogenation of propylene and isobutylene over platinum. Effect of noncompetitive adsorption (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 369-377 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical and kinetics model is presented for reactions catalyzed by solid surfaces where both competitive and noncompetitive adsorption take place, a situation that may be general in reactions between large and small molecules catalyzed by solid surfaces.In the adsorption of large molecules steric hindrance or multiple site adsorption cause maximum surface coverage of such molecules before all sites are occupied. This does not, however, preclude further adsorption of small molecules on the remaining isolated vacant sites nor does it preclude further surface reaction. The overall reaction model for such conditions may be expressed as This particular model has been evaluated for the catalytic hydrogenation of propylene and isobutylene with the expectation that it may be useful in reactions that are of industrial importance. A reaction model based on either competitive adsorption or noncompetitive adsorption alone fails to correlate the experimental data.In these two reactions maximum rates occur at olefin concentrations below 5 mole % and the catalytic adsorption constants for the olefins are a hundredfold greater than for hydrogen. This reaction model is similar to that proposed by Bond and Turkevich (15), who have further demonstrated through the deuteration of propylene that the actual mechanism of the reaction is much more complicated.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120230
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  • 61
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    Development of a two-phase contactor without pressure drop (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 604-605 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120340
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  • 62
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    A generalized method for predicting the minimum fluidization velocity (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 610-612 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120343
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  • 63
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    Mass Transfer and Absorbers, T. Hobler, Pergamon Press, New York (1966). English Translation, 525 pages, $18.50 (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 626-823 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120402
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  • 64
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    Convergent solutions to the first-order difference equation (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 405-405 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120236
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  • 65
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    Thermodynamics of multicomponent systems, Bruce H. Sage, Reinhold Publishing Corporation, New York (1965). 366 pages (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 409-410 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120238
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  • 66
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    Industrial heat transfer, Alfred Schack (translated by I. Gutman), John Wiley and Sons, New York (1965). 456 pp (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 617-618 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120304
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  • 67
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    Boiling heat transfer and two-phase flow, L. S. Tong, John Wiley and Sons, New York (1965). 242 pages, $14.00 (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 616-617 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120303
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  • 68
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    Turbulent flow in annular pipes (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 437-444 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An extension to annular conduits of the well-known method of calculating the resistance coefficient for turbulent flow in circular pipes is presented. The method is new in that it does not borrow any information from laminar flow theory; it gives, therefore, a location for the maximum velocity based only on turbulent flow characteristics. Expressions and a few essential graphs are given for the average as well as inner- and outer-wall resistance coefficients for both hydraulically smooth and rough regimes and also for the transitional regime. A comparison with available experimental information for fully developed turbulent flow is presented.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120310
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    The application of the Geddes fractionation index to crude distillation units (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 432-437 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The degree of separation effected by a fractionator can be measured by a fractionation index n. The index is the equivalent number of theoretical plates, operating at total reflux, which would effect the same component separation as the fractionator.The value of the fractionation index is readily calculated from the Fenske-Underwood equation when component analyses of the feed and products are available.In the case of crude oils, the number of components is so great that resolution in the laboratory is not practicable, and the feed and products are customarily analyzed by high efficiency laboratory fractionators which give their true boiling point characteristics. In this form, the data have been broken down into short fractions which have then been treated as pseudo components in subsequent column calculations.This paper presents a method for treating the product TBP curves as algebraic functions without the necessity for breaking the feed TBP data into arbitrary short fractions. The fractionation index can be derived directly from product TBP data, or the TBP data can be calculated when the fractionation index is known.Data from performance tests on three commercial units have been analyzed. The TBP distillation analyses of the crude oils and the products enabled the fractionation indices pertaining to each section of the fractionators to be evaluated.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120309
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  • 70
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    Modified description of wave motion in a falling film (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 445-455 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The presence of gravity-capillary waves at the surface of a viscous falling film has been studied theoretically by a more rigorous linear treatment than presently available.The present analysis is based on the assumption of steady state periodic solutions of the complete Navier-Stokes equations. It provides methods of prediction, to a first order of approximation, for the wavelength, celerity, and wave number, in terms of the Weber number which emerges as the governing dimensionless group. This treatment includes as special cases the low Weber number analyses of Yih, Benjamin, Hanratty and Hershman, and Kapitza, as well as the high Weber number theory of Ishihara, Iwagaki, and Iwasa. Agreement with experimental observation is improved over that obtained from previous analyses.The stream function of the system has been derived and the instantaneous streamlines have been constructed for application to heat and mass transfer.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120311
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  • 71
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    Axial mixing and extraction in a mechanically agitated liquid extraction tower (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 472-477 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Axial mixing was measured in both phases for a countercurrently operated, mechanically agitated extractor of the Oldshue-Rushton design for water continuous and toluene and kerosene dispersed. Results in terms of an eddy axial diffusivity were correlated in terms of the variables studied. These correlations were then applied to column performance during extraction of n-butyl amine from kerosene into water, and the true mass transfer coefficients, corrected for axial mixing, were determined. These are shown to be predictable for droplets of dispersed phase considered to be rigid spheres.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120315
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  • 72
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    Experimental vapor-liquid equilibrium data for propane-isobutane (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 484-487 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Isothermal vapor-liquid equilibrium data for propane-isobutane, a system of industrial importance, have been obtained in two pieces of apparatus at temperatures from 20° to 250°F. Over this temperature range, propane-isobutane form ideal solutions. The paper discusses the sampling errors which occur in volatile systems.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120317
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  • 73
    Electronic Resource
    Electronic Resource
    A mathematical treatment of the effect of particle size distribution on mass transfer in dispersions (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 499-508 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model is proposed that takes into account interaction between drops or bubbles in a swarm as well as the effect of particle size distribution. The model is used to solve the equations for unsteady state mass transfer with and without chemical reaction when the drops or bubbles are suspended in a nonextraordinarily purified agitated fluid. Steady state diffusion to a family of moving drops with clean interface and without interaction and chemical reaction has been also analyzed. The model demonstrates the sort of error that may arise when one applies uniform drop size assumptions to drop populations. It is shown quantitatively that this error is usually small when one replaces the variable particle size by the mean. By using variables that can be determined and predicted, the equations presented permit the estimation of diffusion rate per unit area of interface, as well as the average concentration and the total average rate of mass transfer in the disperser under pseudo steady state conditions.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120320
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  • 74
    Electronic Resource
    Electronic Resource
    Mass transfer from large oscillating drops (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 530-534 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mass transfer model for vigorously oscillating single liquid drops moving in a liquid field has been developed with the concepts of interfacial stretch and internal droplet mixing. The model takes into account both amplitude and frequency of drop oscillations. Experimental values of fraction extracted were predicted with an average deviation of 15%. Oscillations break up internal circulation streamlines and a type of turbulent internal mixing is achieved.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120325
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  • 75
    Electronic Resource
    Electronic Resource
    Diffusion of gases in electrolytic solutions (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 548-552 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements of the diffusion coefficients of hydrogen and methane in strong aqueous electrolytes have been made with the use of the diaphragm cell method. The variation of the diffusion coefficients with electrolyte concentration, type of ion, and temperature has been studied over the electrolyte concentration range zero to saturated, and for temperatures in the range 25° to 65°C.The results have been interpreted with the Eyring rate theory. The presence of ions in water increases the activation energy for diffusion which results in a decrease in the diffusion coefficient. The increase in activation energy is represented by terms that are additive for the ions involved. The influence of ions on the diffusion coefficient increases rapidly with ionic charge, but seems to be little affected by temperature or solute for the systems studied.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120328
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  • 76
    Electronic Resource
    Electronic Resource
    Viscosity and thermal conductivity of nitrogen - n-heptane and nitrogen - n-octane mixtures (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 559-562 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements of the thermal conductivity and viscosity of n-heptane and n-octane in the gas phase were made at temperatures of 100° and 160°F. and at pressures below 1 atm. In addition, measurements of the viscosity and thermal conductivity of binary gas mixtures of nitrogen and n-heptane were made at 160°F. at pressures below 1 atm.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120330
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  • 77
    Electronic Resource
    Electronic Resource
    Local thermodynamic consistency of vapor-liquid equilibrium data for binary and multicomponent systems (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 586-588 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Gibbs-Duhem equation, integrated over specific concentration ranges, is used to determine local thermodynamic consistency of vapor-liquid equilibrium data. Several specific applications of the test are given for binary systems, although the method is equally applicable to linear paths in multicomponent systems. The test is particularly useful for evaluating the consistency of incomplete data, that is, data measured over only part of the concentration range.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120335
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  • 78
    Electronic Resource
    Electronic Resource
    A new reduced vapor pressure equation (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 599-602 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120338
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  • 79
    Electronic Resource
    Electronic Resource
    On thermodynamics of mixed-gas adsorption (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 606-608 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120341
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  • 80
    Electronic Resource
    Electronic Resource
    Scale-up of residence time distributions (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 612-613 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120344
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  • 81
    Electronic Resource
    Electronic Resource
    Questions and answers with grant swinger (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 627-627 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120403
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  • 82
    Electronic Resource
    Electronic Resource
    Skin friction of power law fluids in turbulent flow over a flat plate (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 637-641 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analysis is presented for skin friction of power law fluids in turbulent flow over a flat plate. A momentum balance is combined with a logarithmic velocity profile and the resulting equation is integrated. Skin friction is shown to be a function of non-Newtonian Reynolds number and power law shear rate exponent. Closed form solutions for viscous drag are obtained for some values of shear rate exponent, but in general a numerical integration is necessary.The equations and curves presented are valid for any power law fluid. Computations may be carried out once the fluid viscosity and shear rate exponent are known. As an example, the results are applied to a power law fluid consisting of Carbopol in water. It is shown how viscous drag is affected by changes in the polymer concentration.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120406
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  • 83
    Electronic Resource
    Electronic Resource
    Uniform flux heat transfer to a gas in laminar forced convection in a circular tube (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 648-655 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer from a circular tube to a contained gas in laminar forced convection was studied dimensionally and experimentally. The boundary condition of uniform heat flux was physically achieved, and the experiments were conducted in a statistically designed pattern. The dimensional analysis, based upon the principle of corresponding states, and more general than any hitherto proposed, indicated four independent variables in this experiment. Of these, only bulk velocity showed a statistically significant effect in the region studied: a reduction in heat transfer coefficient with decreasing bulk velocity. No existing theories could explain this effect.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120408
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  • 84
    Electronic Resource
    Electronic Resource
    Reaction of chlorine and uranium tetrachloride in the fused lithium chloride-potassium chloride eutectic (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 693-699 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rates of the reaction of chlorine gas with uranium tetrachloride dissolved in the lithium chloride-potassium chloride eutectic have been studied in a wetted-rod contactor. The reaction was studied at temperatures from 400° to 700°C., uranium tetrachloride concentrations of 1 to 3 wt. %, and chlorine partial pressures of 0.25 to 1 atm. The production of uranium hexachloride appears to be limited by the equilibrium of the reaction UCL4 (solution) + Cl2 (g) = UCl6 (solution) at the interface and by U+4 diffusion in the liquid phase.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120414
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  • 85
    Electronic Resource
    Electronic Resource
    Entrainment of air into a liquid spray (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 708-717 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An investigation has been carried out into the flow pattern existing in and around a flat spray, particular attention being paid to the region of disintegration of the liquid sheet. The mass of air entrained into the spray, the decay of air velocity along the spray axis, and the spread of the drops in the plane normal to that of the sheet have been related to the operating conditions by equations theoretically derived and experimentally confirmed. Similarities between the characteristics of air entrainment into liquid sprays and into gas jets have been noted.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120416
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  • 86
    Electronic Resource
    Electronic Resource
    Similarity solutions for non-Newtonian fluids (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 700-708 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Similarity transformations are possible for power law fluids in the following systems: momentum transfer in general Falkner-Skan flows and Goldstein flows; and momentum and energy transfer in forced convection about a right angle wedge, natural convection with constant heat flux at the boundary surface, and general Falkner-Skan flows with nonconstant heat conductivity and a restricted boundary temperature distribution. Similarity transformations are also possible for momentum and heat transfer of Eyring viscous fluids about a right angle wedge. A numerical solution is obtained for forced convection of power law fluids about a right angle wedge with an isothermal surface. From the numerical results an approximate expression is obtained for the local Nusselt number.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120415
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  • 87
    Electronic Resource
    Electronic Resource
    Surface catalysis of the hydrogen-oxygen reaction on platinum at low temperatures (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 718-721 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The reaction between hydrogen and oxygen has been investigated at low temperatures with a dilute platinum catalyst. Experimental conversion data indicate a strong effect of product water on reaction rate and a second-order dependence of rate on hydrogen partial pressure in the presence of a large excess of oxygen. This observed behavior is considerably different from expectations based on prior literature.Stable activity levels are much lower than those reported by Boreskov for this reaction on platinum; it is shown that present results are consistent with the effect of chemisorbed oxygen proposed by Boreskov and with the conditions imposed for reaction on a dilute catalyst. Activation energy for the reaction at 100°C. was determined to be 10± 2 kcal./g.-mole.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120417
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  • 88
    Electronic Resource
    Electronic Resource
    Response of a gas-liquid interface to concentration pulses (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 741-746 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Frequency response techniques have been applied to the study of the absorption of sulfur dioxide in water contaminated with surface-active material. The response of a 0.004-in. thick liquid film to a sinusoidally varying sulfur dioxide pressure was determined for frequencies ranging from 1 to 10 cycles/sec.The total quantity of sulfur dioxide dissolved was observed continuously by measuring the amount of light absorbed by the film, which contained a colored hydrogen ion indicator, cresol red. The experimental data indicate the presence of a surface phase of absorbed material through which sulfur dioxide molecules had to pass as they were transferred between gas and liquid. In addition to creating a resistance to the passage of the solute molecules, the surface phase apparently was capable of storing the molecules temporarily.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120421
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  • 89
    Electronic Resource
    Electronic Resource
    Axial dispersion in liquid flow through packed beds (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 767-773 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Step-function injection and purging of a dilute salt tracer in water was used to measure axial dispersion for low Reynolds number liquid flow through beds of uniform sized, random packed glass spheres. The resultant data and those of several previous studies are coordinated and interpreted in terms of Reynolds, Schmidt, and Peclet numbers.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120425
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  • 90
    Electronic Resource
    Electronic Resource
    Vapor-Liquid equilibria for five cryogenic mixtures (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 780-784 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Phase equilibrium data have been obtained for the binary systems nitrogen-argon and nitrogen-carbon monoxide at 83.82°K. and for the systems nitrogen-methane, argon-methane, and carbon monoxide-methane at 9.67°K. Total pressures and compositions of both phases were measured. Parameters have been calculated for the Redlich-Kister and Wilson equations for the excess Gibbs energies of the mixtures. The data are thermodynamically consistent within experimental error.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120427
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  • 91
    Electronic Resource
    Electronic Resource
    Interfacial tensions of binary and ternary two-phase liquid systems (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 795-801 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theory is developed to enable prediction of interfacial tension in unsymmetrical, regular, binary liquid systems from solubility data. This is also shown to be applicable to nonregular aqueous binary systems by using solubility parameters and molar volumes calculated from mutual solubilities as substitutes for true molar volumes and the solubility parameters obtained from energies of vaporization.The theory is extended to include unsymmetrical, regular, ternary liquid systems, and is shown to be applicable to systems consisting of perfluoro-n-hexane and other nonpolar organic liquids. The theory is not adequate for aqueous ternary systems.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120430
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  • 92
    Electronic Resource
    Electronic Resource
    On the Nonuniqueness of the Entry Length (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 816-816 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120437
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  • 93
    Electronic Resource
    Electronic Resource
    Fuel cells. Their Electrochemical Kinetics, V. S. Bagotskii and Yu. B. Vasil'ev, Editors, Consultants Bureau, New York (1966). 121 pages, $15.00 (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 823-824 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120440
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  • 94
    Electronic Resource
    Electronic Resource
    Laboratory instruction (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 835-835 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120503
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  • 95
    Electronic Resource
    Electronic Resource
    Thermodynamics, J. T. Vanderslice, H. W. Schamp, Jr., and E. A. Mason, Prentice-Hall, Englewood Cliffs, New Jersey (1965). 244 pages, $7.95 (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 834-834 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120502
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  • 96
    Electronic Resource
    Electronic Resource
    Application of integral momentum methods to viscoelastic fluids: Flow about submerged objects (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 1019-1022 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120534
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  • 97
    Electronic Resource
    Electronic Resource
    An observation concerning pulse testing of flow systems (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 1026-1026 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120537
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  • 98
    Electronic Resource
    Electronic Resource
    Effect of surface alignment on hydrodynamic stability in falling liquid films (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 1029-1029 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120540
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  • 99
    Electronic Resource
    Electronic Resource
    Design versus research? (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 1043-1043 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120602
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  • 100
    Electronic Resource
    Electronic Resource
    Stresses in concentrated polymer solutions: Part I. Shear dependence of viscosity (1966)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 1064-1070 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is suggested for calculating stresses in sheared polymeric liquids. It synthesizes Kirkwood's correlation function techniques and Fixman's formulation for the stress tensor P. The dependence of P on powers of solute concentration, in the concentrated solution range, arises from a consideration of intermolecular forces. A non-Newtonian viscosity, characterized by only two parameters (low shear viscosity limit ηo and time constant λ), is derived from simple choices of functions which appear in the expression for P.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690120606
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