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  • 1985-1989
  • 1965-1969  (372)
  • 1967  (372)
  • Chemical Engineering  (312)
  • Computational Chemistry and Molecular Modeling  (60)
Material
Years
  • 1985-1989
  • 1965-1969  (372)
Year
  • 101
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 926-931 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In most control applications in the chemical process industries it is not realistic to attempt to define a unique mathematical statement of the control objective, for many criteria will satisfy the physical requirement of the rapid elimination of errors in the product stream as the result of an upset. The strong dependence of the structure of an optimal control system on the choice of objective then makes optimal control theory irrelevant in such situations, since the control engineer has no assurance that a complicated controller is a necessity of the process, rather than a consequence of an unfortunate choice of objective. In this paper an inverse problem is considered, in which an easily implementable feedback control system is first chosen and then is shown to be optimal for a physically meaningful objective in a large class of systems.
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  • 102
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 948-954 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The results of an analytical and experimental study of compressible, axially symmetric, turbulent free jets exhausting into quiescent air are presented. A finite-difference technique was used to obtain a general solution which has eliminated the need for the simplifying assumptions required in previous investigations. The jet Mach number and jet temperature ratio have been found to be the only two initial jet properties which are necessary to characterize the dimensionless velocity and temperature variations in this type of jet. Modifications of dynamic eddy transfer coefficients given in the literature are used in the solution An experimental program was carried out to obtain data on free jet velocity and temperature variation at high initial jet temperatures and high subsonic Mach numbers where there has been a lack of experimental data. The numerical solutions of the time-averaged conservation equations have been shown to agree well with the experimental data of the present study and of previous investigations.
    Additional Material: 12 Ill.
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  • 103
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1018-1019 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 104
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1020-1024 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 105
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1025-1028 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 106
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1030-1031 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 107
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1072-1077 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Volumes translated in wakes of single drops of organic liquids rising through aqueous media have been measured. Organic drops studied comprised methyl isobutyl ketone, toluene, and toluene-carbon tetrachloride mixtures. Aqueous media comprised water and water-sugar solution. Distance of drop rise varied from 10 to 20 in. Drop size was varied such that Reynolds numbers of 40 to 800 were obtained. Volumes translated were nearly independent of distance for nonoscillating drops and decreased rapidly with distance for oscillating drops. Transition from nonoscillating to oscillating drops occurred at Reynolds number of 200. Measurements of drop velocities were also made.
    Additional Material: 6 Ill.
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  • 108
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1141-1154 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Under some conditions, continuous crystallization exhibits cyclic changes of the particle size even with constant input conditions. A linearized stability analysis has been performed to determine under what conditions this behavior can be expected. Numerical solutions of the actual nonlinear system equations were carried out to follow the cyclic behavior and to compute the cycle time and the amplitude of the fluctuations. The effect of seeding on the stability limits and product distribution was also evaluated.
    Additional Material: 11 Ill.
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  • 109
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1160-1166 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental investigation of heat transfer rates in which were used three spray towers varying from 4 to 6 in. in diameter and 7 to 10 ft. in height, and distributor elements with hole sizes varying from 1/8 to 1/64 in. in diameter was carried out. The immiscible liquid system consisted of water and kerosene (normal boiling point range 395° to 490°F.). Volumetric heat transfer coefficients ranged from 100 to 3,600 B.t.u./(hr.)(cu. ft.)(°F.) and the overall film heat transfer coefficients ranged from 4 to 23 B.t.u./(hr.)(sq. ft.)(°F.). Height equivalent to a theoretical stage varied from 1 to 8 ft. Scale-up correlations relating these rate data to operating variables were developed.
    Additional Material: 9 Ill.
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  • 110
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1155-1159 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The pressure drop of water was measured when water flowed through a bed of stainless steel ball bearings packed in an ordered rhombohedral geometry. Experiments were carried out with eleven different packed beds, encompassing the entire range of the square-base array, in the same 10.85 by 10.85 by 30-in. rectangular test column in a forced circulation loop at modified Reynolds numbers up to 17,000. The test variables included water velocity, bed voidage, spacing between adjacent balls, ball diameter, and bed height. Curves of friction factor vs. Reynolds number are presented. An increase in the relative horizontal spacing between balls was found to have a more important effect than an increase in voidage in decreasing the pressure drop. A general correlation relating the mutual effects of bed voidage and ball spacing on pressure drop that would bring all the data points together, especially in the transition flow region, could not be found. As a result, the system appears to consist of two distinct parts separated at the minimum packing density. A correlation was found only for the first, but from a practical point of view more important, region. Data may be corrected for bed voidage, but only for small variations in ball spacing, by the ratios of (1 - ε)/ε3 at the two voidages. No entrance and exit effects could be measured beyond the first seven ball layers.
    Additional Material: 7 Ill.
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  • 111
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1171-1174 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A relationship for the diffusion coefficient of a dilute species in a mixture of two solvents is developed. The result, based on the linear additivity of the frictional activation energy which is valid for completely miscible, nonassociated systems, predicts the diffusion coefficient of the solute in terms of the limiting values of the diffusion coefficient of the solute in each of the solvents, the limiting values of the solvent pair diffusion coefficient, and two thermodynamic factors. The equation is confirmed for some recent experimental data.
    Additional Material: 2 Ill.
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  • 112
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1175-1180 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effects of viscous dissipation on fully developed laminar forced convection with heat sources in various regular polygonal ducts under the thermal boundary conditions of uniform wall heat transfer per unit duct length and circumferentially uniform wall temperature are approached by the method of point matching. The method uses the exact solutions to the governing partial differential equations and satisfies the boundary conditions exactly only at selected points. This method complements the method of complex variables for various noncircular geometrical configurations where the velocity and temperature fields are not deducible directly from the boundary equations. The relationship between the average velocity and the average of (grad u)2 over the cross section is pointed out. Other useful relationships between heat transfer quantities based on analogy or the observation of the results from literature and present investigation are also pointed out. The numerical results presented can be used to evaluate the effects of viscous dissipation on mean temperature, overall heat transfer rate at the boundary, heat transfer coefficient and Nusselt number. Graphical results for the representative cases are also presented for the heat transfer rate and the Nusselt number.
    Additional Material: 8 Ill.
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  • 113
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 3-3 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 114
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 115
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 2-2 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 116
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 10-16 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method of analysis is presented for determining closed-form solutions for two-component stratified laminar flow in horizontal ducts of arbitrary cross section. It is demonstrated that the method is remarkably easy to apply and produces results of high accuracy. As an application, solutions are obtained for stratified flow in a circular tube. The results are compared with various limiting cases and excellent agreement is found to exist. Among the limiting cases, an exact solution was derived by Green's functions for the problem in which the interface between the flow components is situated at the horizontal diametral plane.
    Additional Material: 4 Ill.
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  • 117
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 17-20 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An optical technique for the quantitative determination of point velocities in rapidly developing laminar flows of transparent liquids is useful as an experimental tool in problems of complex geometries and fluids. The accuracy of the technique has been confirmed by comparison of experimental data with the numerical solution of the equation of motion for the entrance region problem. A distributor capable of generating a flat velocity profile has been developed for this purpose.
    Additional Material: 4 Ill.
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  • 118
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    AIChE Journal 13 (1967), S. 5-10 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new empirical model has been proposed to described crystallization systems where the growth rate increases with increasing crystal size in violation of McCabe's ΔL law. Experimental data for Glauber's salt have been presented to illustrate the fit of the new model to an actual system. Equations for steady state crystal size distributions with the use of the proposed model have been derived. Wider use of population density plots for analysis of crystallization systems along with the coefficient of variation to describe a distribution numerically is recommended.
    Additional Material: 6 Ill.
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  • 119
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 28-36 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Severe discrepancies exist between theoretical considerations and the carbon dioxide-monoethanolamine absorption data available in the literature. By desorbing the inert tracer propylene simultaneously with the absorption of carbon dioxide into monoethanolamine in a short wetted-wall column, it is shown that the physical mass transfer coefficient is increased substantially by the carbon dioxide-monoethanolamine chemical absorption process. This is presumably due to interfacial turbulence driven by surface tension gradients. The use of the actual physical mass transfer coefficient prevailing during carbon dioxide absorption into monoethanolamine results in a considerable improvement in the agreement between the penetration theory solution and the experimental data on the rate of absorption of carbon dioxide into monoethanolamine.
    Additional Material: 14 Ill.
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  • 120
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 45-51 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Circulating hydrogen-oxygen mixtures were reacted at atmospheric pressure in a single long porous catalyst cylinder which contained a thermocouple-micromanometer probe. Rate and temperature rise data were obtained at 20°, 30°, 50°, and 60°C. in the concentration range 0 to 5% oxygen in hydrogen.The data were used in connection with the transport equations to obtain effectiveness factors, rate constant, activation energy, and reaction order for oxygen concentration.The necessity of considering thermal effects is exhibited clearly by this system. The maximum temperature rise observed inside the catalyst (33°C.) is associated with a 60% increase in utilization factor over the isothermal value.
    Additional Material: 5 Ill.
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  • 121
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    AIChE Journal 13 (1967), S. 21-28 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A radioptracer technique was utilized to measure axial dispersion in both phases in spray towers operated at and near flooding. A new method that exhibits certain advantages over methods employed in the past is presented for reducing such data. It is demonstrated that axial dispersion in flooded and near-flooded spray towers is sufficiently severe to control completely their performance as heat exchangers.
    Additional Material: 5 Ill.
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  • 122
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    AIChE Journal 13 (1967), S. 37-41 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Inclination of a flat-plate thermal diffusion column from the vertical axis substantially increases the separation efficiency by reducing the remixing effect. Theoretical considerations show that when the column is at the best inclination, maximum separation, maximum production, or minimum column length may be obtained. A generalized graphical solution of the conditions for best performance is presented. Experimental results for the system benzene-n-heptane are in excellent agreement with the theory.
    Additional Material: 3 Ill.
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  • 123
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 52-60 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A unified theory of one-dimensional, adiabatic, separated, two-phase flow is presented. To describe the flow adequately, four mixture specific volumes are defined. They are based on area, momentum, kinetic energy, and velocity averages. Increasing relative velocity between the phases initially lowers all mixture specific volumes except the velocity average. The momentum average specific volume minimizes when the slip ratio equals (Vg/Vf)1/2, while the kinetic energy average specific volume reaches its minimum value at a slip ratio of (Vg/Vf)1/3. Area average specific value does not minimize with slip ratio.Because a higher slip ratio would decrease the entropy of a closed system, (Vg/Vf)1/3 is the maximum slip ratio attainable in two-phase critical flow. Based on the maximum slip ratio and isentropic flow, a new critical flow model was developed and compared with the steam-water critical flow data of four recent investigations. While the predicted flow rates followed well the pressure behavior of the experimental data, they were too low at high qualities and too high at low qualities. The average percentage difference between experimental and predicted critical flow rates was -8.5% (three hundred and seventy-six data points).Differences in the approach to critical flow between a gas and a vapor-liquid stream appear to be caused by the latter's increased frictional and gravitational pressure drops and relative velocity effects.
    Additional Material: 7 Ill.
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  • 124
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    AIChE Journal 13 (1967), S. 41-44 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new freezing process for the desalination of seawater is being developed which utilizes a unique way of upgrading heat energy where there is no gas phase involved. This method takes advantage of the abnormal melting point curve of water. Water melts at a lower temperature under a higher applied pressure (that is, (dp/dT) melting 〈 0), while an ordinary substance melts at a higher temperature under a higher applied pressure (that is, (dP/dT) melting 〉 0). Due to this differnce a substance which melts at a temperature lower than the freezing point of an aqueous solution may melt at a temperature higher than the melting point of water at a sufficiently high pressure.Thus, a suitably selected working medium can be used to form a cyclic auxiliary system which can be incorporated with the main system to: remove the heat of crystallization of water in the partial freezing of an aqueous solution by melting the working medium at a low pressure, and to supply the heat for melting the ice by solidifying the working medium at a sufficiently high pressure.
    Additional Material: 3 Ill.
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  • 125
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    AIChE Journal 13 (1967), S. 70-77 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the first part of this paper a theory for isothermal homogeneous two-phase, liquid-gas flow in horizontal pipes is established by introducing the concept of Mach number and by considering the medium to be a pseudo gas. The theory takes account of wall friction, compressibility and flow choking. A set of working formulas is obtained. In the second part, results of experiments on homogeneous bubbly flows of water-air mixtures in a 1-in. Pipe are reported. Criteria for the occurrence of bubbly flow are established and the occurrence of flow choking confirmed. It is shown that the mathematical model is adequate insofar as it explains, phenomenologically, real flow conditions.
    Additional Material: 9 Ill.
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  • 126
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    AIChE Journal 13 (1967), S. 77-85 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Finite-difference methods were used to compute hydrodynamic instability due to natural convection in an enclosed horizontal rectangular region heated from below. Critical Rayleigh numbers were determined for a series of Prandtl numbers and length-to-height ratios. For Prandtl numbers greater than unity excellent agreement was obtained between these calculations and the values predicted by Kurzweg on the basis of a linearized theory. However, for Prandtl numbers less than unity the critical Rayleigh numbers exhibited a dependence on NPr, which was not predicted by the linearized theory. For Rayleigh numbers greater than the critical, complete temperature and velocity fields were determined.The calculations assumed that the fluid motion is two dimensional. Experiments have indicated that the flow may be two or three dimensional depending on minor perturbations in the boundary conditions.Although a number of metastable two-dimensional circulations are possible for symmetrical initial conditions, the calculation always converged to a single, unique solution for any asymmetric initial condition.
    Additional Material: 9 Ill.
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  • 127
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    AIChE Journal 13 (1967), S. 60-69 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper presents vapor-liquid equilibrium data for the system hydrogen - benzene - cyclohexane - n-hexane over the pressure range of 500 to 2,000 lb./sq.in.abs. and the temperature range of 200° to 300°F. Experimental equipment was constructed that was capable of operating at pressures of 3,000 lb./sq.in.abs. and at temperatures of 400°F. A static equilibrium cell, which had a sample port for both the liquid and vapor phases, was employed. Separation of the hydrogen from the hydrocarbons by means of a liquid nitrogen cold trap was utilized before performing the hydrocarbon analyses on a mass spectrometer. Three hydrocarbon mixtures were charged to the equilibrium cell, and for each charge, isotherms of 200°, 250°, and 300°F. were run for equilibrium pressures of 500, 1,000, 1,500 and 2,000 lb./sq.in.abs. These thirty-six quaternary equilibrium runs resulted in a total of one hundred and forty-four equilibrium data points. In addition, four binary equilibrium runs were determined both for the hydrogen-benzene and hydrogen-cyclohexane systems. A modified version of the Chao-Seader correlation was used to predict the data. This correlation was able to predict all the quaternary equilibrium ratios with an average deviation of 4.86%.
    Additional Material: 9 Ill.
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  • 128
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    AIChE Journal 13 (1967), S. 97-101 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analytical solution based on a previously proposed entrance model is developed for the case of flow at low Reynolds numbers. Agreement between this solution and the published numerical solution at this Reynolds number limit supports the authenticity of the numerical solutions presented previously.
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  • 129
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    AIChE Journal 13 (1967), S. 91-96 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the measurement of the absorption of carbon dioxide gas by a series of oil drops moving down a vertical wire the variables studied are drop frequency, oil viscosity, wire size, and column length. A model is proposed which assumes that the gas is absorbed by almost stagnant liquid film between and covering the drops, that the film is subsequently mixed with a drop as it moves past, and that the dissolved gas is carried from the column in circulating loops of liquid within the drops. The model leads to an equation which correlates the data and gives a good approximation to the slope of the line.
    Additional Material: 5 Ill.
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  • 130
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    AIChE Journal 13 (1967), S. 108-113 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is shown that the first variation method can be used to provide an excellent starting condition for the second variation control of nonlinear systems. Numerical examples illustrate the basic features of the methods.
    Additional Material: 4 Ill.
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  • 131
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    AIChE Journal 13 (1967), S. 86-91 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The decomposition of nickel tetracarbonyl at pressures between 20 and 200 torrs was studied at temperatures from 100° to 225°C. In the cross-flow system, the rate in the absence of appreciable dilution was primarily limited by kinetic resistances at temperatures up to about 175°C. over an effective Reynolds number range of 5 to 100. Gas phase diffusional resistances were controlling at higher temperatures. Corrections for natural convection were employed in both the kinetic and diffusional regions of control.
    Additional Material: 8 Ill.
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  • 132
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    AIChE Journal 13 (1967), S. 101-108 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A straightforward and simple algorithm is presented for obtaining the optimal control of nonlinear systems. This algorithm has many of the advantages of dynamic programming but not the disadvantage of excessive computer storage. A number of numerical examples are presented to show the versatility of the method.
    Additional Material: 3 Ill.
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  • 133
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    AIChE Journal 13 (1967), S. 118-121 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The typical solubility boundaries of binary simple hydrocarbon-water systems are outlined for temperatures and pressures ranging into the neighborhood of the critical point for pure water. These systems are characterized by two unique states, a critical vaporization end point and a critical solution end point. The former defines the limit of mutual solubility of two liquid phases, and the latter defines a point of complete solubility at a minimum pressure. Experimental P-T-x data for cyclohexane-water and n-hexane-water mixtures are presented.
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  • 134
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    AIChE Journal 13 (1967), S. 114-118 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An iterative technique is proposed that solves the two-point boundary value problem formed from the variational equations for the optimal control of nonlinear systems. The computational algorithm utilizes invariant imbedding to provide a set of the unknown boundary conditions and quasilinearization to calculate the optimal control policy. A numerical example indicates that the method exhibits considerable promise.
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  • 135
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    AIChE Journal 13 (1967), S. 122-125 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The flow of molten polymer through porous media has been investigated at constant temperatures and flow rates. Temperatures of 375°, 400°, and 425°F., flow rates from 12 to 60 g./min. and particle sizes from 0.054 in. to 6 mm. in diameter were studied. A modified Darcy's law was developed using the Metzner-Reed modification of the Mooney-Rabinowitsch relation. This form was then used to develop a modified friction factor plot which correlated the data with an average error of 5.02%. Calculated superficial velocities from the Darcy's law equation checked experimental values generally to within 10%. A technique for estimating shear rates when curved rheological flow curves occurred was also developed.
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  • 136
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    AIChE Journal 13 (1967), S. 125-131 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model of dynamic distillation was verified experimentally for transients resulting from a sequence of upsets in operating conditions, that is, for upsets occurring in the unsteady state before the effects of previous upsets died out.The equations for feed-forward control of the top product composition by reflux ratio control action were derived and a computer program was written in FORTRAN for solution on a digital computer. This control model was employed in the feed-forward control of an experimental distillation column when subjected to an upset in feed composition.Experimental data were obtained from a twelve-plate, 10-in. diameter distillation column with a methanol-tertiary butyl alcohol system. The numerical technique employed is a completely general divided difference method which can be utilized in the solution of any system of first-order differential equations.
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  • 137
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    AIChE Journal 13 (1967), S. 132-140 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Steady state heat and mass transfer between a submerged evaporative interface in a porous medium and an external gas stream were analyzed theoretically. Local and average evaporation rates for laminar and turbulent flow over a flat plate as well as for fully developed laminar or turbulent flow near the thermal entry region of a duct were obtained as a function of the position of the evaporative interface. Calculated local evaporation rates are significantly lower than values computed by Luikov, who did not take into account the variation of evaporative surface temperature with recession, indicated both by the present analysis and by observations related to the drying of thick porous materials. Application to the analysis of the drying process is discussed.
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  • 138
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    AIChE Journal 13 (1967), S. 140-147 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The variable-property, laminar, boundary-layer equations, which describe simultaneous momentum, heat, and binary mass transfer with thermodynamic coupling,Thermodynamic coupling refers to the Soret (or thermaldiffusion)effect, which is the flow of mass caused hy a temperaturegradient, and the Dufour (or diffusion thermo) effect, which is theflow of heat caused by a concentration gradient. are analyzed for air flows over a flat plate with the injection of foreign gases through the solid surface. A simplified general treatment of thermodynamic coupling is developed and applied to yield approximate but accurate expressions for evaluating heat transfer rates and adiabatic wall temperatures for injection of hydrogen, helium, and carbon dioxide. This method explains why the driving force based on (Tω - Tω) can be used to correlate heat transfer results for situations where diffusion thermo is important. Furthermore, and perhaps most significant, the method provides a simple error estimate for the correlation obtained by using the adiabatic wall temperature.It is shown that the injection of lightweight gases can significantly reduce viscous dissipation in flows over slender bodies and that diffusion thermo and dissipation effects can be otion in flows over slender bodies and that diffusion thermo and dissipation effects can be of the same order of magnitude even for reasonably high-velocity flows. These effects are discussed in terms of convenient quantities, called σ functions.
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  • 139
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    AIChE Journal 13 (1967), S. 148-155 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method was devised to yield chemical reaction kinetic parameters from nonisothermal, nonisobaric flow experiments. The system studied was the pyrolysis of propane at high temperatures (800° to 1,000°C.). At these temperatures the rates of the various reactions are so high that a batch or even an isothermal flow experiment is impossible. To keep the conversions low so that the initial stages of decomposition could be studied, the feed gas was diluted with varying amounts of nitrogen. Residence times in the reactor were in the millisecond range. The reactor exit gas was analyzed by mass spectrometry. The method developed in this work is not limited to simple kinetic studies, but can be useful in complicated series and parallel reactions which often require nonisothermal conditions.
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  • 140
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    AIChE Journal 13 (1967), S. 155-159 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An isobaric calorimeter has been built for measuring the integral heat of vaporization at high pressures and low temperatures simultaneously with vapor-liquid equilibria data. The methane-ethylene system was studied at 20 and 40 atm., with data obtained on three mixtures and the two pure components. The experimental results are compared with three different calculation methods.
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  • 141
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    AIChE Journal 13 (1967), S. 160-164 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: With the use of the heat balance integral method, a formula for the depth of solidification in a stratified medium is derived that applies to Newton's cooling at the surface, where the temperature of the cooling medium is variable. The presence of a surface layer with zero latent heat is given a special consideration. Comparison of the proposed formula with the direct field measurements and the calculations carried out by others shows a satisfactory coincidence. For the simplified boundary conditions, the formular reduces to a known analytical solution.
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  • 142
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    AIChE Journal 13 (1967), S. 165-169 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A numerical method and graphs of generalized solutions are presented for a moving interface problem of freezing a saturated liquid inside a cylindrical or a spherical container with a constant heat transfer coefficient, as well as melting a saturated solid. The frozen solid phase has a constant heat capacity.
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  • 143
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    AIChE Journal 13 (1967), S. 169-173 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A generalized differentiation method for analyzing rheological data of time-independent fluids is presented. The method is demonstrated to be valid and useful in analyzing rheological data and comparing such data obtained on the same time-independent fluid in rheometers of the capillary, annular, coaxial cylinder rotational, and falling cylinder types.
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  • 144
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    AIChE Journal 13 (1967), S. 176-179 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 145
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    AIChE Journal 13 (1967), S. 174-175 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data on liquid phase-controlled gas absorption in the loading regime are presented. Carbon dioxide was desorbed from water by using a 6-in. Diameter tower and 1/2- and 3/4-in. Ceramic rings. Below the loading point, HL increases approximately as the 0.25 power of the liquid rate and is independent of gas rate. In the loading regime, however, it was found that at high gas rates HL increases less rapidly and may even decrease with increase in liquid rate. At intermediate gas rates, the effect of liquid rate on HL is intermediate. These effects are explained on the basis of the interaction of the gas and liquid flow rates and the effect of this interaction on KL and a. The results suggest that in some cases tower capacity may be increased without increasing HL.
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    AIChE Journal 13 (1967), S. 179-181 
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    Additional Material: 4 Ill.
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    AIChE Journal 13 (1967), S. 186-188 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 148
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    AIChE Journal 13 (1967), S. 182-186 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 149
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    AIChE Journal 13 (1967), S. 191-192 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 150
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    AIChE Journal 13 (1967), S. 189-191 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 151
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    AIChE Journal 13 (1967), S. 192-194 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 152
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    AIChE Journal 13 (1967), S. 194-199 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 153
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    AIChE Journal 13 (1967) 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 154
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  • 155
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    AIChE Journal 13 (1967), S. 211-211 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 156
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  • 157
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    AIChE Journal 13 (1967), S. 414-415 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 158
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    Notes: This study was undertaken to ascertain the accuracy of finite-difference solutions for flow around spherical particles in the intermediate Reynolds number range. Comparison of the results with experimental data on drag coefficients, frontal stagnation pressure, and wake geometry indicated good agreement. The approximate solutions, in which the Galerkin method and asymptotic analytical predictions were utilized, were evaluated by using the finite-difference solutions as a standard. These methods were used to calculate the effect of uniform and nonuniform mass efflux on the drag and flow characteristics around a sphere. Theoretical solutions indicated that nonuniform mass efflux can significantly reduce the drag on a submerged object. Ranges of applicability of the approximate methods were established.
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  • 159
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Steady state solutions of the Navier-Stokes equations for Reynolds numbers of 0.1, 1, 50, 100, and 200 have been obtained by using finite-difference methods. The effects of radial and angular step size and wall proximity have been investigated. Results were found in the form of stream function and vorticity distributions with pressure distributions and drag coefficients calculated from them. The results compare favorably with experimental data and show a steady trend from Hadamard-Rybczynski flow to boundary-layer flow after Levich-Chao-Moore. For a circulating sphere of low viscosity there is no flow separation indicated at Reynolds numbers equal to or less than 200.
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  • 160
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    AIChE Journal 13 (1967), S. 224-230 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The basic equations that describe the thermal diffusion column, including the forgotten effect, were solved numerically. When the density of the liquid in the column varies with concentration, the effect is important in transient batch operation of columns, increasingly so as the wall spacing decreases, but it has no influence at the steady state. Experimental work corroborated the theoretical results.According to the theory, the instances of concentration reversal reported in the literature cannot be the result of the forgotten effect; the fluids involved could not have had the necessary properties. Attempted duplications of these instances in careful experiments yielded normal behavior. However, theoretical and experimental work on a column with a deliberately nonconstant wall spacing indicated that concentration reversals could occur in the complete absence of any forgotten effect contribution.
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  • 161
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    AIChE Journal 13 (1967), S. 231-236 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An instrument based on the Burnett method for determining gas compressibility at high temperature and high pressure was constructed. An estimate of the accumulated measurement errors indicate the data should be accurate to eight parts in 10,000. The instrument was calibrated up to 1,000 lb./sq.in. with helium at 200° and 300°C. The average absolute difference between the experimental and the smoothed helium compressibility factor data was 4 and 6 parts/100,000 for the 200° and 300°C. isotherms, respectively. Compressibility factor data for methyl chloride from 200° to 350°C. at 25°C. intervals and at pressures to 5,000 lb./sq.in. are reported. Second virial coefficients for helium and methyl chloride were also obtained.
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  • 162
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    AIChE Journal 13 (1967), S. 236-240 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Feedback and feedforward inventory control systems are derived which give improved probability of holding all inventories between predetermined limits, even when there are fewer controllers than controlled variables. The concept of partial controllability is developed to describe systems with uncontrollable states. An example shows that four tank levels can be held within limits with high probability, with only one manipulated flow rate used.
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  • 163
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    AIChE Journal 13 (1967), S. 241-244 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Phase equilibria in the decane-urea-ethanol system were investigated between 15° and 40°C. Solubility limits for urea-decane adduct in ternary liquid solutions and for urea in ethanol were measured over the entire feasible range of compositions, thus defining the phase diagrams. Activity coefficients estimated for the saturated liquid solutions reflected strong positive deviations from ideality. The magnitudes were consistent with the results of independent vaporliquid equilibrium studies.
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  • 164
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    AIChE Journal 13 (1967), S. 245-249 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Supersaturated solutions with randomly distributed seed crystals were formed by jet mixing of saturated slurries of urea - decane adduct and decane - urea - ethanol solutions. The resulting crystal growth rates were measured quantitatively with a rapid-mixing, stopped-flow calorimeter. Nucleation of additional crystals was negligible. Times required for 90% adduction ranged between 0.375 and 25.5 sec., a 68-fold variation. A single dimensionless chronomal which adequately represented all the kinetic data was obtained. In all runs, liquid phase mass transfer appeared to control the rate of adduction, despite the fact that the rapid mixing greatly reduced mass transfer resistance. Whereas the data were consistent with several equations describing models based on diffusional rate control, the results did not support mechanisms involving surface phenomena.
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  • 165
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    AIChE Journal 13 (1967), S. 250-253 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The terminal velocity of bubbles in low viscosity liquids of infinite extent is known to undergo a marked transition in behavior at an equivalent radius in the order of 0.07 cm. This transition is apparently due to a change from viscous to inviscid flow. It is also known that the inviscid flow regime can be further subdivided into surface tension- (Weber number) and buoyancy- (Froude number) dominated regimes. This behavior of rising bubbles is strikingly similar to the behavior of surface waves propagated over deep water. The analogy is found to be in quantitative agreement when the wavelength is suitably interpreted in terms of bubble dimensions. The inference of this analogy is that bubbles may be thought of as interfacial disturbances whose rate of propagation is governed by the well-known laws of wave motion.
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  • 166
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    AIChE Journal 13 (1967), S. 260-266 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Eleven mixtures of the three isomers of xylene and ethylbenzene were isomerized over a silica-alumina catalyst in a differential tubular reactor at temperatures from 700° to 900°F. and pressures from 0 to 100 lb./sq. in. gauge. Analysis showed that meta-xylene isomerizes reversibly to ortho- and para-xylene, but the direct interconversion of ortho-xylene to meta-xylene does not occur. Further, it appears that the isomerization reactions are first order and, by the Hougen-Watson technique, follow a single-site reaction model.
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  • 167
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    AIChE Journal 13 (1967), S. 253-259 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The flow of viscoelastic fluids past a flat plate has been investigated. Experimental studies were performed with aqueous solutions of sodium carboxymethylcellulose used as viscoelastic fluids and corn syrup as a viscous Newtonian fluid. It was observed that the flow patterns of elastic and inelastic fluids are markedly different. Tracer particles placed in the approaching viscoelastic fluids to follow their motion were seen to first decelerate and then to accelerate until a nearly constant velocity was reached. On the other hand tracer particles in the Newtonian fluid were observed merely to decelerate smoothly to the constant velocity.The drag force measured for the viscoelastic fluids was found to be roughly twice that predicted by inelastic models of fluid behavior. Predicted and measured values of the drag force for the Newtonian fluid agreed well.A discussion of mathematical solutions to the problem of flow of viscoelastic fluids past a flat plate is given. Solutions are obtained for a prototype of flow past a flat plate, the suddenly accelerated flat plate (Stokes' problem) with linear viscoelastic models used. The results from Stokes' problem qualitatively explain the anomalous kinematical behavior and the large drag force.
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    AIChE Journal 13 (1967), S. 266-272 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The distribution across a pipe of turbulent intensities, shearing stress, and energy spectra are inferred from measured electrokinetic-potential fluctuations in a fully developed flow of distilled water in a 2.54-cm. diameter glass pipe. These quantities are shown to be in good agreement with those obtained by Laufer and Sandborn with hot-wire anemometers for air flows at the same mean Reynolds number. A tentative analytical model of the phenomenon is constructed and analyzed by Maxwell's electrodynamic field equations for a nonmagnetized medium moving with a velocity which is much smaller than the velocity of light. A set of equations governing the interrelation between the electrokinetic-potential fluctuations and the turbulent velocity-fluctuation components of the flow field in fully developed pipe flow is deduced. Fourier transforms are then introduced and simple relations between the electrokinetic-potential fluctuations and velocity fluctuations are obtained.
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  • 169
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    AIChE Journal 13 (1967), S. 273-279 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study of the motion of the interface in two-phase flow in two dimensions with gravity force parallel to the plane of motion is described. The experiments were run in a porous medium analog, the Hele-Shaw model. A modification of the Saffman-Taylor solution is compared with the experimental results. The arbitrary parameter in the solution, measured in the experiments, does not approach an asymptote but is a function of the ratio of plate spacing to channel height. In the course of the air-water experiments three forms of the interface were observed before turbulence, which indicate regime changes in the flow. Finally, the effects of heterogeneities (change in plate spacing) on the interface were observed.
    Additional Material: 10 Ill.
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  • 170
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    AIChE Journal 13 (1967), S. 1214-1216 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 171
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    AIChE Journal 13 (1967), S. 1219-1221 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 172
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    AIChE Journal 13 (1967), S. 1216-1219 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 173
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    AIChE Journal 13 (1967), S. 1221-1225 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 174
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    AIChE Journal 13 (1967), S. 1226-1229 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 175
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    AIChE Journal 13 (1967), S. 401-402 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 176
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    AIChE Journal 13 (1967), S. 403-404 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 177
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    AIChE Journal 13 (1967), S. 404-406 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 178
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    AIChE Journal 13 (1967), S. 497-503 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Reverse osmosis experimental data for some inorganic salts with the porous cellulose acetate membrane used were analyzed to obtain their diffusivity in the membrane. A parameter including the diffusivity was found constant for each film in the concentration range investigated for a particular solute at a particular pressure. This parameter was also independent of feed flow rate. The effect of operating pressure on the parameter was found to depend on the film shrinkage. Mass transfer coefficient between the membrane and the feed solution was also obtained by the analysis, and this value was independently checked by the diffusion current method. Coincidence of these coefficients shows that the ordinary mass transfer coefficient can be used in reverse osmosis with the appropriate driving force. These facts facilitate the prediction of solute separation and membrane throughput rate in reverse osmosis.
    Additional Material: 8 Ill.
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  • 179
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    AIChE Journal 13 (1967), S. 519-527 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical study of the transient state of a plug-flow tubular reactor with recycle is presenred for a model in which axial dispersion of heat and mass is negligible. A qualitative description of the temporal behavior near the steady state is obtained from an analysis of the linearized transient equations, and some large-scale transient characteristics are studied by means of numerical solution of the nonlinear transient equations. A cursory study of the application of the Liapunov's direct method to predict regions of asymptotic stability is also presented. Numerical examples illustrate sustained oscillatory behavior as well as the transient nature of systems with multiple steady states.
    Additional Material: 11 Ill.
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  • 180
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    AIChE Journal 13 (1967), S. 513-519 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Longitudinal turbulence intensities, autocorrelations, and energy spectra have been measured in the flow of toluene, benzene, and cyclohexane in smooth, round 1- and 2-in. I.D. tubes. These measurements were made with a constant-temperature hot-film anemometer and covered radial positions from the center to r/a = 0.85 in the 2-in. tube and to r/a = 0.75 in the 1-in. tube.The turbulence intensity data were found to be similar to those obtained for air in a 10-in. pipe by Laufer. A slight diameter effect was observed, the intensities in the 1-in. tube being slightly lower than those in the 2-in. tube at equal Reynolds numbers.The energy spectra were similar to the spectrum reported by Lee and Brodkey for water. The spectra reached higher frequencies at the lowest measurable energy levels for higher velocities. There was little effect of tube diameter or radial position on the spectra from the center to r/a = 0.85. A short inertial subrange with a log-log slope of -5/3 seemed evident in high velocity spectra, and the log-log slope of -7 was approached at high frequencies by the lowest velocity spectrum.The peak energy dissipation frequencies for all the energy spectra measured were approximately proportional to bulk mean velocity to the 1.4 power with little effect of tube diameter or radial position from the center to r/a = 0.85.Integral scales of the turbulence were proportional to bulk mean velocity to a power less than one for a given tube. These measurements indicated that the ratio of integral scale to pipe diameter is not a function of Reynolds number only.Microscale values were relatively independent of velocity and pipe diameter.
    Additional Material: 8 Ill.
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  • 181
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    AIChE Journal 13 (1967), S. 580-585 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A stochastic mixing model is developed for turbulent flow in homogeneous plug-flow reactors. The model is based on random coalescence and redispersion of fluid elements. Of special significance is its applicability when mixing and reaction rates are comparable, as well as when either rate dominates. The model's parameters may be determined by measuring conversion with instantaneous reactions. Experimental results reported by others are successfully simulated.
    Additional Material: 8 Ill.
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  • 182
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    AIChE Journal 13 (1967), S. 586-589 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Using a thermodynamically consistent form of equation of state proposed by Foulkes, one can determine the virial coefficients of the pressure expansion from Joule-Thomson coefficient data. A modification of the method has been applied for nitrogen and ethane within the temperature range from 50°C. to the normal boiling point. Mixture rules are proposed that allow reproduction of experimental data on μ for nitrogen-ethane mixtures at pressures below the critical pressure of ethane.
    Additional Material: 5 Tab.
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  • 183
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    AIChE Journal 13 (1967), S. 608-611 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 184
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    AIChE Journal 13 (1967), S. 611-612 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 185
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    AIChE Journal 13 (1967), S. 616-616 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 186
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    AIChE Journal 13 (1967), S. 621-622 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 187
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    AIChE Journal 13 (1967) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 188
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    AIChE Journal 13 (1967), S. 663-669 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A correlations has been developed from considerations of single-phase flow behavior to predict pressure drop across packed beds for two-phase cocurrent flow. The correlation does no require one of the assumptions made in previous correlations, and thus it was not necessary to relate empirically any dimensionless groups through the use of experimental two-phase flow data. The only empiricism involved in the use of this correlation is that required in correlating single-phase pressure drops through packed beds, an art well developed in the literature. The correlation as developed here is at least as accurate as previous correlations in this area and may be more reliable when used for two-phase systems not previously studied experimentally.
    Additional Material: 7 Ill.
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  • 189
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Enhanced rates of mass transfer in aqueous systems were studied with an electrochemical technique. Detached turbulence promoters (cylinders supported away from the surface) were shown to cause increases in mass transfer in aqueous systems in a manner similar to that observed in gaseous system. As in air studies, peaks in the local rate of mass transfer were observed directly beneath the cylinders and a wake effect was observed downstream from the cylinders.
    Additional Material: 3 Ill.
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  • 190
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    AIChE Journal 13 (1967), S. 682-688 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The stability of cylindrical jets in immiscible liquid systems is analyzed with the low velocity theory of Tomotika. For the first time the several limiting solutions in the literature are obtained from a general equation, so approximate restrictions on their applicability can be presented. These restrictions show that for many systems none of the limiting solutions is valid. Correlations applicable to all Newtonian liquid-liquid systems are presented for predicting the growth rate and wavelength of the most unstable disturbance.
    Additional Material: 9 Ill.
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  • 191
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The second virial coefficients of pure n-butane and of two mixtures of helium and n-butane were determined in the range 100° to 225°C. from isothermal compressibility measurements. Values of B11 (pure n-butane) agree closely with those of McGlashan and Potter (11) at low temperatures and of Hirschfelder et al. (7) at higher temperatures. Values of the mixed second virial coefficient B12 were computed from the mixture data. B12 shows little variation with temperature over this interval. The interpretation of the data as the behavior of a mixture composed of hard sphere (helium) in a real gas (n-butane) is discussed.
    Additional Material: 4 Ill.
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  • 192
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    AIChE Journal 13 (1967), S. 726-731 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The reaction between aluminum, in the form of flat plates, and chlorine was investigated in a flow system at temperatures from 500° to 650°F. Gaseous aluminum chloride was the reaction product at these temperatures. At 500°F. the reaction proceeded by pitting, and the rate appeared to be chemically controlled. The reaction mechanism changed at higher temperatures to give a smooth reacted surface, and the reaction rate was found to be dependent upon both mass transport and kinetic parameters. The method proposed by Rosner for calculating mass transport-dependent reaction rates was found to correlate both average and local rate data and was used to obtain estimates of the kinetic parameters for the heterogeneous surface reaction.
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  • 193
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    AIChE Journal 13 (1967), S. 810-813 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 194
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    AIChE Journal 13 (1967), S. 814-815 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 195
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    AIChE Journal 13 (1967), S. 815-816 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 196
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    AIChE Journal 13 (1967), S. 817-821 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 197
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    AIChE Journal 13 (1967), S. 821-823 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 198
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    AIChE Journal 13 (1967), S. 824-825 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 199
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    AIChE Journal 13 (1967) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 200
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    AIChE Journal 13 (1967), S. 834-834 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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