ISSN:
0009-2940
Keywords:
Tripod ligand synthesis
;
Tripod nickel chloro complexes
;
Tripod iron tris(acetonitrile) complexes
;
Tripod cobalt acetate complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Synthesis and Complex Chemistry of Functionalised Tripod Ligands RC(CH2PPh2)3Malonic ester 1 is alkylated and converted into the triols RC(CH2OH)3 (5). These are easily converted into the corresponding functionalised tripodal ligands RC(CH2PPh2)3 (7) with R = Bzl (a), n-C12H25 (b), (CH3)2CH(CH2)2 (c). Crystals suitable for X-ray crystallography have been obtained of the ligand 7a. In addition, the tripod ligands 7a and 7c have been further characterized by the syntheses and X-ray analyses of the nickel complex [(7a)NiCl] (8a), the iron complex [(7c)Fe(NCCH3)3](BF4)2 [9 · (BF4)2], and the cobalt complex [(7c)Co{O(O)CCH3}](BPh4) (10 · BF4).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19951280109