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Digitale Medien

Mechanistic details of the Belousov-Zhabotinsky oscillations. II. The organic reaction subset (1979)

Edelson, D. ; Noyes, R. M. ; Field, R. J.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 11 (1979), S. 155-164

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Details

ISSN: 0538-8066

Schlagwort(e): Chemistry ; Physical Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Our previous mechanistic model for the Belousov-Zhabotinsky reaction has been revised to include a more realistic set of reactions for the oxidation pathways of the organic intermediates. A few other rate constants have also been modified to include new information. The revised mechanism reproduces the essential experimental observations, although the periods of oscillation are somewhat too long and oscillations cease at malonic acid concentrations about ten times greater than the observed lower limit. However, the essential features of the mechanism are clearly understood.

Zusätzliches Material: 4 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/kin.550110207

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