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  • 1
    Electronic Resource
    Electronic Resource
    Capillary-Type Viscometer (1947)
    s.l. : American Chemical Society
    Analytical chemistry 19 (1947), S. 131-132 
    Details
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ac60002a018
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    X-Ray Diffraction Patterns for Identification of Crystalline Constituents of Explosives (1947)
    s.l. : American Chemical Society
    Analytical chemistry 19 (1947), S. 442-444 
    Details
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ac60007a004
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Kinetics of Reactions in Solution (1956)
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Physical Chemistry 7 (1956), S. 185-206 
    Details
    ISSN: 0066-426X
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1146/annurev.pc.07.100156.001153
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  • 4
    Electronic Resource
    Electronic Resource
    Chemical oscillations during the uncatalyzed reaction of aromatic compounds with bromate. 2. A plausible skeleton mechanism (1979)
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 83 (1979), S. 3056-3057 
    Details
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/j100486a025
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    Paper (German National Licenses)
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  • 5
    Electronic Resource
    Electronic Resource
    Oscillatory Chemical Reactions (1974)
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Physical Chemistry 25 (1974), S. 95-119 
    Details
    ISSN: 0066-426X
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1146/annurev.pc.25.100174.000523
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    Paper (German National Licenses)
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  • 6
    Electronic Resource
    Electronic Resource
    Mechanistic details of the Belousov-Zhabotinskii oscillations (1975)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 7 (1975), S. 417-432 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A detailed chemical mechanism for the cerium catalyzed bromination and oxidation of malonic acid by bromate has been developed, and complete numerical solutions have been obtained for the temporal behavior of the concentrations of the intermediate species. The many points of similarity with the experimentally observed initial decay, long quiescence, and abrupt transition to sustained oscillation establish confidence in the essential validity of the proposed mechanism. Close examination of the time dependence of these species concentrations as well as the magnitude of the several reaction channels permits the clarification of the switching mechanism causing theoscillatory behavior of this system. The results appear to exhibit limit cycle behavior, in accordance with theoretical predictions.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550070309
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  • 7
    Electronic Resource
    Electronic Resource
    The oxidation of cerous ions by bromate ions comparison of experimental data with computer calculations (1977)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 9 (1977), S. 841-862 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The oxidation of cerous ions by bromate ions in sulfuric acid medium was followed spectrophotometrically under various experimental conditions. The results were compared to the calculated predictions on the basis of a mechanism suggested by R. M. Noyes and collaborators. The computations were done by solving the complete set of the kinetic differential equations. The results of the computations show that the proposed mechanism explains adequately most of our and previous experimental data. In particular, the mechanism predicts the main features of the reaction, namely, the induction and the fast and slow reaction periods which occur during the oxidation.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550090514
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  • 8
    Electronic Resource
    Electronic Resource
    On the oxidation of malonic acid by ceric ions (1978)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 10 (1978), S. 619-636 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The oxidation of malonic acid by ceric ions has been investigated in sulfuric acid solution under a variety of conditions. The initial rate at low ceric ion concentrations is first order in each of the two reactants and has an activation energy of 11.6 kcal/mol; the instantaneous rate constant increases somewhat with time during a single run. At higher concentrations of ceric ion, semilogarithmic plots are sigmoid with a reduced rate constant at long times. The rate decreases slightly with increasing sulfuric acid concentration. Rates of carbon dioxide evolution may be much less than rates of ceric ion reduction because of supersaturation effects. The observations can be explained if dissolved oxygen reacts with organic radicals to catalyze the rate of initial attack on malonic acid, but oxygen must also be consumed irreversibly during these reactions. Computations with plausible rate constants have simulated the experimental observations. These oxygen effects can rationalize peculiar almost discontinuous changes in rate when bromomalonic acid is oxidized by ceric ion. These effects may also explain the previously puzzling observation that some Belousov-Zhabotinsky solutions are oscillatory in bulk but become quiescent but excitable when spread in a thin film in contact with air.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550100608
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  • 9
    Electronic Resource
    Electronic Resource
    Mechanistic details of the Belousov-Zhabotinsky oscillations. II. The organic reaction subset (1979)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 11 (1979), S. 155-164 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Our previous mechanistic model for the Belousov-Zhabotinsky reaction has been revised to include a more realistic set of reactions for the oxidation pathways of the organic intermediates. A few other rate constants have also been modified to include new information. The revised mechanism reproduces the essential experimental observations, although the periods of oscillation are somewhat too long and oscillations cease at malonic acid concentrations about ten times greater than the observed lower limit. However, the essential features of the mechanism are clearly understood.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550110207
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  • 10
    Electronic Resource
    Electronic Resource
    A model for explosions during carbon monoxide oxidationPaper 32 in the Series Oscillations in Chemical Systems. For Paper 31 see [1]. (1979)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 11 (1979), S. 821-841 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: During the oxidation of carbon monoxide containing a trace of water, ten well-known atomic and molecular species can be identified as of potential significance. All conceivable reactions of these species in their ground electronic states were considered, and rate constants for all those that are of potential importance are either known or can be estimated with considerable confidence. For compositions and temperatures of experimental interest an isothermal system goes to a single steady state that is stable to perturbation and will neither explode nor oscillate. These steady-state computations also predict that as the temperature is raised above about 1000 K most of the water is converted to H, OH, and HO2 radicals. Under such conditions, exothermic reactions would be so rapid that strong thermal gradients would develop in any real system of plausible dimensions. A simple model based on these calculations predicts explosion limits consistent with those observed experimentally. Simultaneous behavior in time and in space must be calculated in detail before it is clear whether or not this model based on ground electronic states can model the oscillations that are sometimes observed in this system.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550110803
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