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The oxidation of cerous ions by bromate ions comparison of experimental data with computer calculations (1977)

Barkin, S. ; Bixon, M. ; Noyes, R. M. ; [weitere]

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 9 (1977), S. 841-862

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Details

ISSN: 0538-8066

Schlagwort(e): Chemistry ; Physical Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The oxidation of cerous ions by bromate ions in sulfuric acid medium was followed spectrophotometrically under various experimental conditions. The results were compared to the calculated predictions on the basis of a mechanism suggested by R. M. Noyes and collaborators. The computations were done by solving the complete set of the kinetic differential equations. The results of the computations show that the proposed mechanism explains adequately most of our and previous experimental data. In particular, the mechanism predicts the main features of the reaction, namely, the induction and the fast and slow reaction periods which occur during the oxidation.

Zusätzliches Material: 16 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/kin.550090514

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