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Raman, pre-resonance Raman and electronic spectra of iron(II) saccharinate (1992)

Jubert, A. H. ; Diez, R. Pis ; Etcheverry, S. B. ; [et al.]

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 23 (1992), S. 15-20

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ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The Raman spectrum of solid [Fe(Sac)2 (H2O4)] · 2H2O was recorded and assigned. Some comparisons with the spectra of the related copper(II) and nickel(II) complexes were also made. The excitation profiles of the vibrational modes that show pre-resonance on excitation with laser lines within the electronic bands are reported. On this basis, and with the aid of a semi-empirical extended Hückel MO calculation, the assignment of the metal - ligand vibrations and the interpretation of the electronic spectrum could be reinforced.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250230103

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