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The formation of the styryl ion in the mass spectra of cinnamyl compounds (1969)

Brittain, E. F. H. ; Kelly, J. P. ; Mead, W. L.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 2 (1969), S. 325-330

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The formation of the styryl ion \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm PhCH = }\mathop {\rm C}\limits^{\rm + } {\rm H} $\end{document} in the mass spectra of some cinnamic compounds is shown to occur via the intermediate formation of the cinnamoyl ion \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm Ph} - {\rm CH} = {\rm CH} - {\rm C} \equiv \mathop {\rm O}\limits^{\rm + } $\end{document} rather than by direct cleavage of the bond α to the double bond.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210020311

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