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Computation of phase and chemical equilibrium: Part III. Electrolytic solutions (1979)

Gautam, Rajeev ; Seider, Warren D.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 25 (1979), S. 1006-1015

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ISSN: 0001-1541

Keywords: Chemistry ; Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: Methods for estimating the properties of electrolytic solutions are reviewed, with emphasis on molecule-molecule, molecule-ion, and ion-ion interactions. The algorithms of Parts I and II, to search for global minimum in Gibbs free energy, are extended to handle electrolytes and compared with an algorithm using k-values. Results are presented for SO2-H2O and H2S-NH3-H2O systems and agree with experimental values.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/aic.690250612

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