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The photolysis of n-butyraldehyde in isooctane at 313 nm (1979)

Förgeteg, S. ; Bérces, T.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 11 (1979), S. 239-260

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The effects of aldehyde concentration, incident light intensity, and temperature on the quantum yields of reaction products were studied. Mechanisms for primary and secondary photochemical processes were suggested, and primary quantum yields as well as rate constant ratios were derived. Reversibility of intramolecular γ-hydrogen transfer and disproportionation of the radical pair formed in the reaction of an excited triplet and ground state molecule were shown to provide important pathways for radiationless decay of the triplet state.

Additional Material: 9 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550110303

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