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Rate constants for the termination of benzyl radicals in solution (1979)

Lehni, M. ; Schuh, H. ; Fischer, H.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 11 (1979), S. 705-713

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The rate constant for the bimolecular combination of benzyl radicals in cyclohexane and toluene is determined as a function of temperature. Further, it is studied in cyclohexane-toluene mixtures of different compositions. In the entire range covered, 9.8 × 108 ≤ 2kt ≤ 9.0 × 109M-1·sec-1, the data are very well described by the Smoluchowski equation for a diffusion-controlled reaction to ground-state products using a spin statistical factor of 1/4, a temperature- and solvent-independent reaction distance, and the known diffusion coefficient of toluene.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550110704

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