ZIB

Hits per page

hit 1 - 1 | 1 hit

Select All Export

Electronic Resource

Pyrolysis of [5-14C]-1-pentene-evidence for homoallylic rearrangements at 873 K (1986)

Kopinke, F.-D. ; Zimmermann, G. ; Bach, G. ; [et al.]

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 18 (1986), S. 159-163

add to mindlist on the mindlist

Details

ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: It was found that the pyrolysis of [5-14C]-1-pentene gives radioactive 1,3-butadiene. This result can be explained in terms of a sequence of free radical rearrangements of 1-penten-3-yl radicals. From this and additional information on isotope distribution in butadiene formed from different deuterated 1-pentenes, we conclude that homoallylic rearrangement of 1-penten-4-yl and 2-penten-5-yl radicals is the dominant route for their consumption.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550180203

Library	Location	Call Number	Volume/Issue/Year	Availability

Others were also interested in ...

Paper (German National Licenses)

Fulltext

hit 1 - 1 | 1 hit