ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The bimolecular reactions in the title were measured behind shock waves by monitoring the O-atom production in COS—O2—Ar and CS2—O2—Ar mixtures over the temperature range between 1400 and 2200 K. A value of the rate constant for S + O2 → SO + O was evaluated to be (3.8 ± 0.7) × 1012 cm3 mol-1 s-1 between 1900 and 2200 K. This was connected with the data at lower temperatures to give an expression k2 = 1010.85 T0.52 cm3 mol-1 s-1 between 250 and 2200 K. An expression of the rate constant for CS2 + O2 → CS + SO2 was obtained to be k21 = 1012.0 exp(-32 kcal mol-1/RT) cm3 mol-1 s-1 with an error factor of 2 between 1500 and 2100 K.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550180807
