ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The NH3/NO2 system has been investigated experimentally in an isothermal flow reactor in the temperature range 850-1350 K. The experimental data were interpreted in terms of a detailed reaction mechanism. The flow reactor results, supported by a theoretical analysis of the NH2—NO2 complex, suggest that the NH2 + NO2 reaction has two major product channels, both proceeding without activation barriers: Our findings indicate that the N2O + H2O channel is dominant at low temperatures while H2NO + NO dominates at high temperatures. The rate constant for reaction (R21) is estimated to be 3.5 · 1012 cm3/mol-s in the temperature range studied with an uncertainty of a factor of 3. © 1995 John Wiley & Sons, Inc.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550271207
