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Digitale Medien

Synthesis of 2′-Deoxyisoinosine and Related 2′-Deoxyribonucleosides (1994)

Seela, Frank ; Chen, Yaoming ; Bindig, Uwe ; [weitere]

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 77 (1994), S. 194-202

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Details

ISSN: 0018-019X

Schlagwort(e): Chemistry ; Organic Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Various 2-substituted purine and pyrrolo[2,3-d]pyrimidine 2′-deoxyribonucleosides with methylthio (13a), chloro (13b), methoxy (9b), and oxo (2, 3) substituents at C(2) are prepared. They are obtained either via stereoselective nucleobase-anion glycosylation or by base transformation. A three-step synthesis of the unknown 2′-deoxyisoinosine (2) from 2′-deoxyguanosine (15) is described. Compound 2 as well as its 7-deazapurine derivative 3 exhibit strong fluorescence.

Zusätzliches Material: 4 Tab.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/hlca.19940770122

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