ISSN:
0020-7608
Keywords:
Computational Chemistry and Molecular Modeling
;
Atomic, Molecular and Optical Physics
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
An expression for electron transfer rate has been obtained through the solution of a time wave equation by the variational method by defining the wave function as a linear combination of functions corresponding to electron localization on the donor and on the acceptor. A dependence of electron transfer on temperature, on the electronic and vibrational characteristics of the system has been derived. An activation energy temperature-variation effect has been obtained. It has been proved that many-electron transfers are impossible.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/qua.560280103
