ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Various N-cycloalkyl fumaramides having different characters of N-cycloalkyl groups such as piperidine, morpholine, or pyrrolidone were synthesized and homopolymerized or copolymerized with styrene by use of a radical initiator and ultraviolet irradiation, respectively. N,N′-Dipiperidinyl or -dimorpholyl fumaramides copolymerized with styrene to form a random copolymer, while N,N′-fumaroyl dipyrrolidone tended to form an alternating copolymer with styrene, indicating that the electron distribution of the N-cycloalkyl group affects the polymerizability of fumaramide derivatives. Photopolymerizability of these fumaramides was not as great as that of α,β-unsaturated esters.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1974.170120405
