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Phosphorescence from nylon polymers: Effects of thermal and photochemical oxidation (1974)

Allen, N. S. ; McKellar, J. F. ; Phillips, G. O.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 12 (1974), S. 1233-1241

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Details

ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The phosphorescence from the nylon polymers 6, 66, 11, and 12 has been studied from the aspects of excitation and emission wavelength location and of emission lifetime. In contrast to the other nylons, the 66 polymer exhibits two distinct phosphorescence bands, both of which are sensitive to thermal and photochemical oxidation of the polymer. The species responsible for these emissions are concluded to be carbonyl in nature and their role in the complex reactions that occur during thermal and photochemical oxidation of the polymer is discussed.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1974.170120609

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