ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The stereoelective polymerization of racemic t-butyl thiirane was performed with chiral zinc glycolate. Monomers and polymers of high optical purities were isolated. A new kinetic scheme in which the ratio of the rates of consumption of both enantiomers obeys a second-order relationship is proposed. This behavior is different from that observed for other three-membered ring monomers.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1979.170170602