ISSN:
0887-6266
Keywords:
thermodynamics
;
phenolic
;
PEO
;
polymer blend
;
PCAM
;
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The thermodynamic properties of novolac type phenolic resin blended with poly(ethylene oxide) (PEO) were investigated by the Painter-Coleman association model (PCAM). Equilibrium constants and enthalpy corresponding to the interaction between phenolic and poly(ethylene oxide) were calculated from the Fourier transform infrared spectroscopy of low molecular weight analogues in dilute solutions. The association parameters of the model compounds are transferred to the corresponding polymers, to predict the Gibbs free energy, phase behavior, and the degree of hydrogen bonding in the polymer blend. The heat capacity (CP) and the excess heat capacity (ΔCP) are used to verify the validity of PCAM model on predicting the thermodynamics properties of phenolic/PEO blend. It is found that the hydrogen bonding interaction dominates at moderate temperatures, which is outweighed by the dispersion force at higher temperature or high PEO compositions. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 1647-1655, 1998
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
