ISSN:
1573-4803
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract Various kinds of tungsten borides were synthesized by solid state reaction between tungsten and amorphous boron powders. The mixed powders with various compositions (B/W = 0.4 to 13.0) were treated at 800 to 1550° C for 0 to 120 min in a stream of argon. Four kinds of boride phases such as W2B, WB, W2B5 and WB4 were formed, although the boride phase having the composition of the highest boride, WB12, did not appear. The formation of W2B was initiated approximately at 1000° C in excess of tungsten content. On the other hand, in the excess boron content, the formation of WB, W2B5 and WB4 was initiated approximately at 800, 950 and 1200° C, respectively. The maximum formation amount and crystallinity of WB and W2B5 was found in nearly 10 at % excess boron content in their own stoichiometric compositions. The only crystalline phase of WB4 was prepared with a large excess boron content. However, the formation behaviour of WB4 showed that WB4 is metastable above 1400° C. The stability of WB4 phase could be increased by the presence of excess boron.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01086475
